• Journal of the Korean institute of surface engineering
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• v.54 no.5
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• pp.267-277
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• 2021

Nitriding layers developed during gaseous nitriding of AISI4115 steels for the application of steel bushing part were investigated. The compound layer thickness of about 10㎛, 0.3mm of case depth under the same conditions, and conventional nitriding, nitrocarburizing, and controlled nitriding were performed in three methods. In the controlled nitriding, K_N was controlled by measuring the hydrogen partial pressure. The nitrided samples were analyzed by micro Vickers hardness test, optical microscopy and scanning electron microscopy. The phases of compound layer were identified by X-ray diffraction and electron backscatter diffraction. The controlled nitriding specimen indicated the highest surface hardness of about 860 HV_0.1. The compound layer of the conventional nitriding and nitrocarburizing specimen was formed with about 46% porous layer and 𝜺 + 𝜸' phase, and about 13% porous layer and about 80% 𝜸' phase were formed on the controlled nitriding specimen. As a result of the Ball-on-disk wear test, the worn mass loss of ball performed on the surface of the controlled nitriding specimen was the largest. The controlled nitriding specimen had the highest surface hardness due to the lowest porous percentage of compound layer, which improved the wear resistance.

• Journal of Ocean Engineering and Technology
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• v.12 no.3 s.29
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• pp.49-59
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• 1998

The damage mechanism of $Cr_2O_3$ plasma coated soda-lime glass and uncoated glass by steel ball particle impact was analyzed in this study. And the shape variation of the cracks was investigated by stereo-microscope according to the impact velocity and steel ball diameter. In order to improve the damage reduction effect by $Cr_2O_3$ coating layer, crack size was measured and surface erosion state was observed for both of two kinds of specimen after impact experiment. And the results were compared with each other. The 4-point bending test was performed according to ASTM D790 testing method to evaluate the effect of coating layer for bending strength variation. As a result, it was found that the crack size of $Cr_2O_3$ coated specimen was smaller than that of uncoated one, because of the impact absorption by interior pores in the coating layer and the load dispersion by the structural characteristic of the coating layer. For the specimens subjected to the steel ball impact, the bending strength of coated specimen was higher than that of uncoated specimen.

• Transactions of Materials Processing
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• v.26 no.6
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• pp.365-371
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• 2017

During sling wear of a ferrous metal, a surface layer is formed. Its microstructure, constituting phases, and mechanical property are different from those of the original wearing material. Since wear occurs at the layer, it is important to characterize the layer and understand how wear rate changes with different layers. Various layers are formed depending on external wear conditions such as load, sliding speed, counterpart material, and environmental conditions. In this research, sliding wear tests of pure iron were carried out against two different counterparts (AISI 52100 bearing steel and $Al_2O_3$) in the air and in an inert Ar gas atmosphere. Pure iron was employed to exclude other effects from secondary phases in steel on the wear. Wear tests were performed at room temperature. Worn surfaces, wear debris, and cross-sections were analyzed after the test. It was found that these two different counterparts and environments produced diverse layers, resulting in significant changes in wear rate. Against the bearing steel, pure iron showed higher wear rate in an Ar atmosphere due to severe adhesion than that in the air. On the contrary, the iron showed much higher wear rate in the air against $Al_2O_3$. Different layers and wear rates were analyzed and discussed by oxidation, severe plastic deformation, and adhesion at wearing surfaces.

• Tunnel and Underground Space
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• v.25 no.4
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• pp.383-396
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• 2015

It is analyzed the risk of building damage due to ground surface subsidence occurred during constructing a tunnel below buildings in sand-gravel layer. The overburden and the thickness of sand-gravel layer is about 20m and the width and the height of the tunnel are 12m and 8.6m, respectively. The tunnel is pre-reinforced by umbrella method with three rows of long steel pipes and grouting. Surface subsidence is measured at 36 points surrounding buildings and measured data are used to calculate optimized three dimensional subsidence surface. Depending on the building location, deflection ratio and horizontal strain are calculated to evaluate the risk of building damage. No damage occurs at the buildings because of both the small deflection ratios involved 1~4mm subsidence and compressive horizontal strains.

• Journal of the Korean Society for Heat Treatment
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• v.34 no.6
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• pp.272-280
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• 2021

The influence of acetylene flow rates on the carburizing behavior of an AISI 4115 steel in 1 ton-class mass production-type vacuum carburizing furnace has been studied through microstructure, carbon concentration, hardness analyses. The AISI 4115 steels were carburized with various flow rates (20, 32.7, 60 l/min) and locations in the furnace (top, center, bottom) at 950℃. The acetylene flow rate played an important role in controlling the carburizing properties of carburized samples, such as effective case depth and uniformity carburizing according to location in the furnace. At an acetylene flow rate of 20 l/min, the carburized samples had a shallow average hardened layer (0.645 mm) compared to the target hardening depth (1 mm) due to low carbon flux and spatial uniformity of carburization (17.8%) in the furnace. At a flow rate of 60 l/min, the carburized samples showed an average hardened layer (1.449 mm) deeper than the target hardening depth and had the spatial uniformity of carburization (98.8%). In particular, at a flow rate of 32.7 l/min, the carburized samples had an average hardened layer (1.13 mm) close to the target hardening depth and had the highest carburizing uniformity (99.1%). As a result, an appropriate flow rate of 32.7 l/min was derived to satisfy the target hardening depth and to have spatial uniform hardened layer in the furnace.

• Journal of the Korean Society for Heat Treatment
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• v.12 no.2
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• pp.166-173
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• 1999

Commercial carbon steels containing 0.2~0.55 wt.----C were plasma-nitrided or plasma nitrocarburized at $550^{\circ}C$ for 21.6Ks using $H_2-N_2$ or $H_2-N_2$-CO mixed gas respectively. The characteristics of hardening and wear-resistance of each treatment were studied and compared. And also microstructure of nitrided layer and nitrides formed in compound layer near surface were studied. All plasma-nitrided steels investigated showed remarkable increase of surface hardness with the increase of carbon content. But nitrocarburized steels resulted in higher surface-hardness than plasma-nitrided steels, which means that nitrocarburized has higher surface-hardening effect. Plasma-nitrided steels showed hardness increase in through-thickness direction near surface. And also nitrocarburized steels showed similar hardness distribution in through-thickness direction to that of plasma-nitrided steel. However, nitrocarburized steels had higher cross-sectional maximum-hardness than plasma-nitrided steels as much as 100Hv. Wear test showed that the amount of specific wear was reduced by both plasma-nitriding and nitrocarburized, showing that the amount of specific wear was not related to the hardness. But non-treated specimen showed that the amount of specific wear was related to the hardness.

• Advances in concrete construction
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• v.3 no.4
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• pp.283-293
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• 2015

This paper presents the effects of elevated temperatures of $400^{\circ}C$ and $800^{\circ}C$ on the residual compressive strength and failure behaviour of fibre reinforced concretes and comparison is made with that of unreinforced control concrete. Two types of short fibres are used in this study e.g., steel and basalt fibres. The results show that the residual compressive strength capacity of steel fibre reinforced concrete is higher than unreinforced concrete at both elevated temperatures. The basalt fibre reinforced concrete, on the other hand, showed lower strength retention capacity than the control unreinforced concrete. However, the use of hybrid steel-basalt fibre reinforcement recovered the deficiency of basalt fibre reinforced concrete, but still slightly lower than the control and steel fibres reinforced concretes. The use of fibres reduces the spalling and explosive failure of steel, basalt and hybrid steel-basalt fibres reinforced concretes oppose to spalling in deeper regions of ordinary control concrete after exposure to above elevated temperatures. Microscopic observation of steel and basalt fibres surfaces after exposure to above elevated temperatures shows peeling of thin layer from steel surface at $800^{\circ}C$, whereas in the case of basalt fibre formation of Plagioclase mineral crystals on the surface are observed at elevated temperatures.

• Nuclear Engineering and Technology
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• v.52 no.10
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• pp.2394-2401
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• 2020

Octadecylamine is an effective film-forming amine that protects carbon steel from corrosion. In the present study, the effect of octadecylamine concentration on adsorption on a carbon steel surface was investigated in anaerobic alkaline solution by using SEM/EDS, TEM and the Materials Studio simulation techniques. TEM morphology observation and EDS elemental detection determine the thicknesses of octadecylamine film on a carbon steel surface, which are confirmed by the in-situ electrochemical impedance spectroscopy measurement and resistance calculation. The Materials Studio simulation reveals the number of octadecylamine film layers at different concentrations. Results obtained in this study indicate that adsorption of octadecylamine film on carbon steel proceeds with the multi-layer adsorption mechanism.

• Membrane Journal
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• v.24 no.3
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• pp.177-184
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• 2014

Silica membranes with high permeability were prepared using colloidal and polymeric silica sols on a porous stainless steel-tube support by a DRFF and SRFF method. Silica sols were derived with tetraethylorthosilicate (TEOS) by sol-gel method and analyzed with DLS, FE-SEM, and $N_2$ adsorption. The coating of the intermediate layer with colloidal silica sol on the stainless steel-tube support led to a denser surface morphology of the membrane along with a considerable reduction in the number of surface defect. As the polymeric silica sol enclosed the colloidal silica sol with spherical particles during the SRFF method, the separation-layer-coated silica membrane showed a denser surface than the intermediate layer. Moreover, the silica membranes showed high hydrogen gas permeability of $(6.63-9.21){\times}10^{-5}mol{\cdot}m^{-2}{\cdot}s^{-1}{\cdot}Pa^{-1}$ with low $H_2/N_2$ perm-selectivity (2.9-3.1) at room temperatures.

• Journal of the Korean institute of surface engineering
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• v.47 no.4
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• pp.186-191
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• 2014

Double layer films which consisted of aluminum(Al) and magnesium(Mg) have been prepared by e-beam deposition. The structure, alloy phase, and corrosion resistance of the prepared films were investigated before and after heat treatment. The first (bottom) layer fixed with Al, and the thickness ratio between Al and Mg layers has been changed from 1 : 1 to 5 : 1, respectively. Total thickness of Al-Mg film was fixed at $3{\mu}m$. The cold-rolled steel sheet was used as a substrate. Heat treatment was fulfilled in an nitrogen atmosphere at the temperature of $400^{\circ}C$ for 2, 3 and 10 min. Surface morphology of as-deposited Al-Mg film having Mg top layer showed plate-like structure. The morphology was not changed even after heat treatment. However, cross-sectional morphology of Al-Mg films was drastically changed after heat treatment, especially for the samples heat treated for 10 min. The morphology of as-deposited films showed columnar structure, while featureless structure of the films appeared after heat treatment. The x-ray diffraction data for as-deposited Al-Mg films showed only pure Al and Mg peaks. However, Al-Mg alloy peaks such as $Al_3Mg_2$ and $Al_{12}Mg_{17}$ appeared after heat treatment of the films. It is believed that the formation of Al-Mg alloy phase affected the structure change of Al-Mg film. It was found that the corrosion resistance of Al-Mg film was increased after heat treatment.