Nuclear Engineering and Technology

Korean Nuclear Society (한국원자력학회)
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Effect of octadecylamine concentration on adsorption on carbon steel surface

  • Liu, Canshuai (Suzhou Nuclear Power Research Institute Co., Ltd.) ;
  • Lin, Genxian (Suzhou Nuclear Power Research Institute Co., Ltd.) ;
  • Sun, Yun (Suzhou Nuclear Power Research Institute Co., Ltd.) ;
  • Lu, Jundong (Suzhou Nuclear Power Research Institute Co., Ltd.) ;
  • Fang, Jun (Suzhou Nuclear Power Research Institute Co., Ltd.) ;
  • Yu, Chun (Fujian Key Laboratory of Fuel and Materials in Clean Nuclear Energy System, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences) ;
  • Chi, Lisheng (Fujian Key Laboratory of Fuel and Materials in Clean Nuclear Energy System, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences) ;
  • Sun, Ke (Daya Bay Nuclear Power Operation and Management Co., Ltd)
  • Received : 2020.02.04
  • Accepted : 2020.03.25
  • Published : 2020.10.25
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Abstract

Octadecylamine is an effective film-forming amine that protects carbon steel from corrosion. In the present study, the effect of octadecylamine concentration on adsorption on a carbon steel surface was investigated in anaerobic alkaline solution by using SEM/EDS, TEM and the Materials Studio simulation techniques. TEM morphology observation and EDS elemental detection determine the thicknesses of octadecylamine film on a carbon steel surface, which are confirmed by the in-situ electrochemical impedance spectroscopy measurement and resistance calculation. The Materials Studio simulation reveals the number of octadecylamine film layers at different concentrations. Results obtained in this study indicate that adsorption of octadecylamine film on carbon steel proceeds with the multi-layer adsorption mechanism.

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References

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