• 제목/요약/키워드: Stationary base

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고성능 액체크로마토그래피의 다당유도체를 기초로 한 키랄 고정상에서 이동상 첨가제가 키랄 아민의 광학분리에 미치는 영향 (Effect of Mobile Phase Additive on Enantiomer Resolution for Chiral Amines on Polysaccharide-derived Chiral Stationary Phases by High Performance Liquid Chromatography)

  • 백만정;윤혜란;이원재
    • KSBB Journal
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    • 제29권3호
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    • pp.205-209
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    • 2014
  • Chromatographic enantiomer resolution of chiral amines was performed on several covalently immobilized and coated chiral stationary phases (CSPs) based on polysaccharide derivatives under the mobile phase conditions containing base or acid or acid/base additive. The chromatographic parameters including separation factors and capacity factors were greatly influenced by the nature of the mobile phase containing base or acid or salt additive as well as the used CSPs. When 0.05% triethylamine/0.05% trifluoroacetic acid as an additive in the mobile phase was used on all CSPs in this study, the greatest enantiomer resolution was observed except for Chiralpak AD. Also, it was shown that the change of base additive into acid or salt in the mobile phase may directly affect chiral recognition mechanisms between the chiral selectors and analytes occurring during enantiomer separation, resulting in the change of elution orders.

Optimum parameters and performance of tuned mass damper-inerter for base-isolated structures

  • Jangid, Radhey Shyam
    • Smart Structures and Systems
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    • 제29권4호
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    • pp.549-560
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    • 2022
  • The optimum damping and tuning frequency ratio of the tuned mass damper-inerter (TMDI) for the base-isolated structure is obtained using the numerical searching technique under stationary white-noise and filtered white-noise earthquake excitation. The minimization of the isolated structure's mean-square relative displacement and absolute acceleration, as well as the maximization of the energy dissipation index, were chosen as the criteria for optimality. Using a curve-fitting technique, explicit formulae for TMDI damping and tuning frequency for white-noise excitation are then derived. The proposed empirical expressions for TMDI parameters are found to have a negligible error, making them useful for the effective design of base-isolated structures. The effectiveness of TMDI and its optimum parameters are influenced by the soil condition and isolation frequency, according to the comparison made of the optimized parameters and response with different soil profiles. The effectiveness of an optimally designed TMDI in controlling the displacement and acceleration response of the flexible isolated structure under real and pulse-type earthquakes is also observed and found to be increased as the inertance mass ratio increases.

강화학습 기반의 다단계 공급망 분배계획 (Reinforcement leaning based multi-echelon supply chain distribution planning)

  • 권익현
    • 대한안전경영과학회지
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    • 제16권4호
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    • pp.323-330
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    • 2014
  • Various inventory control theories have tried to modelling and analyzing supply chains by using quantitative methods and characterization of optimal control policies. However, despite of various efforts in this research filed, the existing models cannot afford to be applied to the realistic problems. The most unrealistic assumption for these models is customer demand. Most of previous researches assume that the customer demand is stationary with a known distribution, whereas, in reality, the customer demand is not known a priori and changes over time. In this paper, we propose a reinforcement learning based adaptive echelon base-stock inventory control policy for a multi-stage, serial supply chain with non-stationary customer demand under the service level constraint. Using various simulation experiments, we prove that the proposed inventory control policy can meet the target service level quite well under various experimental environments.

발전용 가스엔진의 개발 및 연소특성에 관한 연구 (A Study on the Development and the Combustion Characteristics of a Stationary Gas Engine)

  • 김현규;우석근;전충환;장영준
    • Journal of Advanced Marine Engineering and Technology
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    • 제24권6호
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    • pp.128-139
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    • 2000
  • Environmental concerns and shortage of petroleum have promoted considerable interest in the use of alternate fuels in stationary diesel engine. In this study, a heavy-duty, intercooler-turbocharged 6-cylinder stationary diesel engine was converted into stationary gas engine fueled with propane or natural gas for the cogeneration plants. One of the most important factors in the combustion features of a stationary gas engine is the fuel composition and operating parameters in terms of compression ratio, spark advance, and engine loads. Experiments with different fuel gas and load conditions were carried out with combustion pressure analysis and NOx measurement. Combustion analysis based on P-$\theta$ diagrams was also investigated by means of combustion duration and cycle variation. Compression ratio is 10.0 and ignition timing is set by using the gasoline setting as a base line and advanced toward BTDC. The results show that fuel composition and spark advance have dominant effects on combustion and NOx characteristics at operating conditions.

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Stationary Distribution for the Mobilities in Catastrophe Rescue Scenario

  • Wang, Yong;Peng, Wei;Dou, Qiang;Gong, Zhenghu
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제7권2호
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    • pp.308-326
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    • 2013
  • Mobility Model has drawn more and more attentions since its critical role in Mobile Wireless Networks performance evaluation. This paper analyzes the mobility patterns in the catastrophe rescue scenario, and proposes the Random Waypoint with Base Point mobility model to model these characteristics. We mathematically analyze the speed and spatial stationary distributions of the nodes and derive explicit expressions for the one dimensional case. In order to keep the stationary distribution through the entire simulation procedure, we provide strategies to initialize the speed, location and destination of the nodes at the beginning of the simulation. The simulation results verify the derivations and the proposed methods in this paper. This work gives a deep understanding of the properties of the Random Waypoint with Base Point mobility model and such understanding is necessary to avoid misinterpretation of the simulation results. The conclusions are of practical value for performance analysis of mobile wireless networks, especially for the catastrophe rescue scenario.

유체-구조물 상호작용을 고려한 면진구조물의 추계학적 응답해석 (Stochastic Analysis of Base-Isolated Pool Structure Considering Fluid-Structure Interaction Effects)

  • 고현무;김재관;박관순;하동호
    • 대한토목학회논문집
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    • 제14권3호
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    • pp.463-472
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    • 1994
  • Random 지반운동에 대한 면진수조구조물 응답의 추계학적 해석방법을 연구하였다. 유연한 벽체와 내부유체간의 유체구조물 상호작용은 유체운동의 유한요소 모델링에 의하여 얻어지는 부가질량행렬 형태로 고려되었다. 정상(定常)(Stationary)지반운동으로는 수정된 Clough-Penzien Spectral Model이 사용되었으며, 비정상(非定常)(Nonstationary)지반운동으로는 상기모델에 포락함수를 적용한 모델을 사용하였다. 운동을 지배하는 Lyapunov Covariance Matrix 미분방정식의 해를 구하여 두 종류 면진시스템의 정상응답 및 비정상응답을 해석하였다.

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선형 및 신경망 자기회귀모형을 이용한 주식시장 불안정성지수 개발 (Stock market stability index via linear and neural network autoregressive model)

  • 오경주;김태윤;정기웅;김치호
    • Journal of the Korean Data and Information Science Society
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    • 제22권2호
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    • pp.335-351
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    • 2011
  • 오경주와 김태윤 (2007) 등은 위기 관련 데이터의 희귀성 에서 발생하는 문제를 해결하기 위해 과거 금융시장이 안정적이었던 구간을 기준 구간으로 설정하고 기준 구간의 금융시장 움직임을 점 근 자기회귀 모형으로 적합한 후 현재의 금융시장 상황과 비교하여 불안정 지수를 도출할 것을 제안하였다. 그러나 비모수 기법인 신경망을 사용하여 도출된 불안정 지수가 기준 구간의 데이터에 지나치게 의존하는 관계로 불안정 지수가 종종 실제 경제상황을 제대로 반영하지 못하는 것으로 관찰되고 있다. 본 연구에서는 비모수 기법인 신경망과 모수 기법인 선형모형을 이용하여 기준구간에 대한 적합을 독립적으로 수행하여 두 종류의 불안정성 지수들을 도출한 후 이 둘을 결합한 통합 불안정성 지수를 사용할 것을 제안한다. 두 지수의 적절한 통합을 위해 신경망과 선형모형을 통해 도출된 두 지수의 최적 결합비율을 부여하는 방법을 제안하며 제안기법의 타당성을 국내 주식시장 대상으로 검증하였다.

고성능 액체 크로마토그래피에 의한 다당 유도체를 기초로 한 흡착되거나 공유결합된 키랄 고정상에서 키랄 아미노 알코올의 안트르알디민 유도체의 광학분리 (Enantiomer Separation of Chiral Amino Alcohols as 9-anthraldimine Derivatives on Coated and Covalently Bonded Chiral Stationary Phases Based on Polysaccharide Derivatives by High Performance Liquid Chromatography)

  • 서문준;김경옥;이원재
    • KSBB Journal
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    • 제26권4호
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    • pp.323-327
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    • 2011
  • The convenient derivatization method of chiral amino alcohols as 9-anthraldimine Schiff base derivatives for chiral resolution was developed and the liquid chromatographic enantiomer separation of chiral amino alcohols as 9-anthraldimine derivatives was investigated on several coated and covalently bonded polysaccharide-derived chiral stationary phases (CSPs). In general, the performance of Chiralcel OD-H (or Chiralcel OD) (${\alpha}$ = 1.24-2.89), the coated CSP derived from cellulose derivative was superior to the other CSPs for resolution of 9-anthraldimine derivatives of several amino alcohols. The results of enantioseparation depending on the structure of 9-anthraldimine analytes like the steric bulky group and the polar moiety etc were discussed. The analytical method was applied to measure the enantiomeric purity of commercially available chiral amino alcohols. It is expected that the convenient analytical method will be very efficient for determination of enantiomeric purity of amino alcohols as 9-anthraldimine Schiff base derivatives with strong UV absorption.

다이케스팅 머신의 구조 해석

  • 윤승원
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 1995년도 추계학술대회 논문집
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    • pp.813-817
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    • 1995
  • Structural analysis of horizontal cold chamber die casting machine is performed by the FEM. The analyzed model is made up of stationary die platen,movable die platen,link housing platen, C-frame, and tie bar which mainly undertake die locking force and injection force. In modeling, compression gap elements are used for to simulate contacting condition between tie bar and movable die platen, movable die platen and base frame, and link housing and base frame. Unbalanced die locking force imposed on four tie bars are considered. As the results, the deformed shape and the stresses of the die casting machine are given.

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면진 구조물의 최적설계에 관한 연구(I) (A Study on the Optimum Design of Base Isolated Structures (I))

  • 정정훈;김병현;양용진
    • 한국지진공학회:학술대회논문집
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    • 한국지진공학회 2001년도 추계 학술발표회 논문집 Proceedings of EESK Conference-Fall 2001
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    • pp.339-347
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    • 2001
  • A probabilistic optimum design method of the base isolation system consisting of linear spring, viscous damper and frictional element is presented. For the probabilistic approach, the base excitation is assumed to be a stationary Gaussian filtered random process. For optimum design, the objective function and constraints are derived based on the stochastic responses of the system. As a numerical example, the optimum design problem of a three-story base isolated shear type structure is formulated and solved by the sequential quadratic programming method. As a result, the effects of variation of design variables such as parameters of the base isolation system and the mass of base on the objective function and constraints are investigated and the optimum parameters of the base isolation system under study are derived.

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