• Title/Summary/Keyword: Stationary base

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Effect of Mobile Phase Additive on Enantiomer Resolution for Chiral Amines on Polysaccharide-derived Chiral Stationary Phases by High Performance Liquid Chromatography (고성능 액체크로마토그래피의 다당유도체를 기초로 한 키랄 고정상에서 이동상 첨가제가 키랄 아민의 광학분리에 미치는 영향)

  • Paik, Man-Jeong;Yoon, Hye-Ran;Lee, Wonjae
    • KSBB Journal
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    • v.29 no.3
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    • pp.205-209
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    • 2014
  • Chromatographic enantiomer resolution of chiral amines was performed on several covalently immobilized and coated chiral stationary phases (CSPs) based on polysaccharide derivatives under the mobile phase conditions containing base or acid or acid/base additive. The chromatographic parameters including separation factors and capacity factors were greatly influenced by the nature of the mobile phase containing base or acid or salt additive as well as the used CSPs. When 0.05% triethylamine/0.05% trifluoroacetic acid as an additive in the mobile phase was used on all CSPs in this study, the greatest enantiomer resolution was observed except for Chiralpak AD. Also, it was shown that the change of base additive into acid or salt in the mobile phase may directly affect chiral recognition mechanisms between the chiral selectors and analytes occurring during enantiomer separation, resulting in the change of elution orders.

Optimum parameters and performance of tuned mass damper-inerter for base-isolated structures

  • Jangid, Radhey Shyam
    • Smart Structures and Systems
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    • v.29 no.4
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    • pp.549-560
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    • 2022
  • The optimum damping and tuning frequency ratio of the tuned mass damper-inerter (TMDI) for the base-isolated structure is obtained using the numerical searching technique under stationary white-noise and filtered white-noise earthquake excitation. The minimization of the isolated structure's mean-square relative displacement and absolute acceleration, as well as the maximization of the energy dissipation index, were chosen as the criteria for optimality. Using a curve-fitting technique, explicit formulae for TMDI damping and tuning frequency for white-noise excitation are then derived. The proposed empirical expressions for TMDI parameters are found to have a negligible error, making them useful for the effective design of base-isolated structures. The effectiveness of TMDI and its optimum parameters are influenced by the soil condition and isolation frequency, according to the comparison made of the optimized parameters and response with different soil profiles. The effectiveness of an optimally designed TMDI in controlling the displacement and acceleration response of the flexible isolated structure under real and pulse-type earthquakes is also observed and found to be increased as the inertance mass ratio increases.

Reinforcement leaning based multi-echelon supply chain distribution planning (강화학습 기반의 다단계 공급망 분배계획)

  • Kwon, Ick-Hyun
    • Journal of the Korea Safety Management & Science
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    • v.16 no.4
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    • pp.323-330
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    • 2014
  • Various inventory control theories have tried to modelling and analyzing supply chains by using quantitative methods and characterization of optimal control policies. However, despite of various efforts in this research filed, the existing models cannot afford to be applied to the realistic problems. The most unrealistic assumption for these models is customer demand. Most of previous researches assume that the customer demand is stationary with a known distribution, whereas, in reality, the customer demand is not known a priori and changes over time. In this paper, we propose a reinforcement learning based adaptive echelon base-stock inventory control policy for a multi-stage, serial supply chain with non-stationary customer demand under the service level constraint. Using various simulation experiments, we prove that the proposed inventory control policy can meet the target service level quite well under various experimental environments.

A Study on the Development and the Combustion Characteristics of a Stationary Gas Engine (발전용 가스엔진의 개발 및 연소특성에 관한 연구)

  • 김현규;우석근;전충환;장영준
    • Journal of Advanced Marine Engineering and Technology
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    • v.24 no.6
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    • pp.128-139
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    • 2000
  • Environmental concerns and shortage of petroleum have promoted considerable interest in the use of alternate fuels in stationary diesel engine. In this study, a heavy-duty, intercooler-turbocharged 6-cylinder stationary diesel engine was converted into stationary gas engine fueled with propane or natural gas for the cogeneration plants. One of the most important factors in the combustion features of a stationary gas engine is the fuel composition and operating parameters in terms of compression ratio, spark advance, and engine loads. Experiments with different fuel gas and load conditions were carried out with combustion pressure analysis and NOx measurement. Combustion analysis based on P-$\theta$ diagrams was also investigated by means of combustion duration and cycle variation. Compression ratio is 10.0 and ignition timing is set by using the gasoline setting as a base line and advanced toward BTDC. The results show that fuel composition and spark advance have dominant effects on combustion and NOx characteristics at operating conditions.

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Stationary Distribution for the Mobilities in Catastrophe Rescue Scenario

  • Wang, Yong;Peng, Wei;Dou, Qiang;Gong, Zhenghu
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.7 no.2
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    • pp.308-326
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    • 2013
  • Mobility Model has drawn more and more attentions since its critical role in Mobile Wireless Networks performance evaluation. This paper analyzes the mobility patterns in the catastrophe rescue scenario, and proposes the Random Waypoint with Base Point mobility model to model these characteristics. We mathematically analyze the speed and spatial stationary distributions of the nodes and derive explicit expressions for the one dimensional case. In order to keep the stationary distribution through the entire simulation procedure, we provide strategies to initialize the speed, location and destination of the nodes at the beginning of the simulation. The simulation results verify the derivations and the proposed methods in this paper. This work gives a deep understanding of the properties of the Random Waypoint with Base Point mobility model and such understanding is necessary to avoid misinterpretation of the simulation results. The conclusions are of practical value for performance analysis of mobile wireless networks, especially for the catastrophe rescue scenario.

Stochastic Analysis of Base-Isolated Pool Structure Considering Fluid-Structure Interaction Effects (유체-구조물 상호작용을 고려한 면진구조물의 추계학적 응답해석)

  • Koh, Hyun Moo;Kim, Jae Kwan;Park, Kwan Soon;Ha, Dong Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.3
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    • pp.463-472
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    • 1994
  • A method of stochastic response analysis of base-isolated fluid-filled pool structures subject to random ground excitations is studied. Fluid-structure interaction effects between the flexible walls and contained fluid are taken into account in the form of added mass matrix derived by FEM modeling of the contained fluid motion. The stationary ground excitation is represented by Modified Clough-Penzien spectral model and the nonstationary one is obtained by imposing an envelope function on the stationary one. The stationary and nonstationary response statistics of the two different isolation systems are obtained by solving the governing Lyapunov covariance matrix differential equations.

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Stock market stability index via linear and neural network autoregressive model (선형 및 신경망 자기회귀모형을 이용한 주식시장 불안정성지수 개발)

  • Oh, Kyung-Joo;Kim, Tae-Yoon;Jung, Ki-Woong;Kim, Chi-Ho
    • Journal of the Korean Data and Information Science Society
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    • v.22 no.2
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    • pp.335-351
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    • 2011
  • In order to resolve data scarcity problem related to crisis, Oh and Kim (2007) proposed to use stability oriented approach which focuses a base period of financial market, fits asymptotic stationary autoregressive model to the base period and then compares the fitted model with the current market situation. Based on such approach, they developed financial market instability index. However, since neural network, their major tool, depends on the base period too heavily, their instability index tends to suffer from inaccuracy. In this study, we consider linear asymptotic stationary autoregressive model and neural network to fit the base period and produce two instability indexes independently. Then the two indexes are combined into one integrated instability index via newly proposed combining method. It turns out that the combined instability performs reliably well.

Enantiomer Separation of Chiral Amino Alcohols as 9-anthraldimine Derivatives on Coated and Covalently Bonded Chiral Stationary Phases Based on Polysaccharide Derivatives by High Performance Liquid Chromatography (고성능 액체 크로마토그래피에 의한 다당 유도체를 기초로 한 흡착되거나 공유결합된 키랄 고정상에서 키랄 아미노 알코올의 안트르알디민 유도체의 광학분리)

  • Xu, Wen Jun;Jin, Jing Yu;Lee, Won-Jae
    • KSBB Journal
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    • v.26 no.4
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    • pp.323-327
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    • 2011
  • The convenient derivatization method of chiral amino alcohols as 9-anthraldimine Schiff base derivatives for chiral resolution was developed and the liquid chromatographic enantiomer separation of chiral amino alcohols as 9-anthraldimine derivatives was investigated on several coated and covalently bonded polysaccharide-derived chiral stationary phases (CSPs). In general, the performance of Chiralcel OD-H (or Chiralcel OD) (${\alpha}$ = 1.24-2.89), the coated CSP derived from cellulose derivative was superior to the other CSPs for resolution of 9-anthraldimine derivatives of several amino alcohols. The results of enantioseparation depending on the structure of 9-anthraldimine analytes like the steric bulky group and the polar moiety etc were discussed. The analytical method was applied to measure the enantiomeric purity of commercially available chiral amino alcohols. It is expected that the convenient analytical method will be very efficient for determination of enantiomeric purity of amino alcohols as 9-anthraldimine Schiff base derivatives with strong UV absorption.

다이케스팅 머신의 구조 해석

  • 윤승원
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1995.10a
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    • pp.813-817
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    • 1995
  • Structural analysis of horizontal cold chamber die casting machine is performed by the FEM. The analyzed model is made up of stationary die platen,movable die platen,link housing platen, C-frame, and tie bar which mainly undertake die locking force and injection force. In modeling, compression gap elements are used for to simulate contacting condition between tie bar and movable die platen, movable die platen and base frame, and link housing and base frame. Unbalanced die locking force imposed on four tie bars are considered. As the results, the deformed shape and the stresses of the die casting machine are given.

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A Study on the Optimum Design of Base Isolated Structures (I) (면진 구조물의 최적설계에 관한 연구(I))

  • 정정훈;김병현;양용진
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2001.09a
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    • pp.339-347
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    • 2001
  • A probabilistic optimum design method of the base isolation system consisting of linear spring, viscous damper and frictional element is presented. For the probabilistic approach, the base excitation is assumed to be a stationary Gaussian filtered random process. For optimum design, the objective function and constraints are derived based on the stochastic responses of the system. As a numerical example, the optimum design problem of a three-story base isolated shear type structure is formulated and solved by the sequential quadratic programming method. As a result, the effects of variation of design variables such as parameters of the base isolation system and the mass of base on the objective function and constraints are investigated and the optimum parameters of the base isolation system under study are derived.

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