• Title/Summary/Keyword: Stark broadening

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Measurement of electron temperature and density using Stark broadening of the coaxial focused plasma for extreme ultraviolet (EUV) lithography

  • Lee, Sung-Hee;Hong, Young-June;Choi, Eun-Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.475-475
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    • 2010
  • We have generated Ar plasma in dense plasma focus device with coaxial electrodes for extreme ultraviolet (EUV) lithography and investigated an emitted visible light for electro-optical plasma diagnostics. We have applied an input voltage 4.5 kV to the capacitor bank of 1.53 uF and the diode chamber has been filled with Ar gas of pressure 8 mTorr. The inner surface of the cylindrical cathode has been attatched by an acetal insulator. Also, the anode made of tin metal. If we assumed that the focused plasma regions satisfy the local thermodynamic equilibrium (LTE) conditions, the electron temperature and density of the coaxial plasma focus could be obtained by Stark broadening of optical emission spectroscopy (OES). The Lorentzian profile for emission lines of Ar I of 426.629 nm and Ar II of 487.99 nm were measured with a visible monochromator. And the electron density has been estimated by FWHM (Full Width Half Maximum) of its profile. To find the exact value of FWHM, we observed the instrument line broadening of the monochromator with a Hg-Ar reference lamp. The electron temperature has been calculated using the two relative electron density ratios of the Stark profiles. In case of electron density, it has been observed by the Stark broadening method. This experiment result shows the temporal behavior of the electron temperature and density characteristics for the focused plasma. The EUV emission signal whose wavelength is about 6 ~ 16 nm has been detected by using a photo-detector (AXUV-100 Zr/C, IRD). The result compared the electron temperature and density with the temporal EUV signal. The electron density and temperature were observed to be $10^{16}\;cm^{-3}$ and 20 ~ 30 eV, respectively.

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Laser Intensity Dependence in Resonant Multiphoton Ionization of Hg Atoms (수은 원자에서의 공명 다광자 이온화 과정의 레이저 강도 의존성)

  • 한재민;정도영;차형기;김철중;이종민
    • Korean Journal of Optics and Photonics
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    • v.1 no.1
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    • pp.7-11
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    • 1990
  • Resonant multi photon ionization (RMPD of Hg atoms is studied by focusing a high-power laser into the ionization cell. The intermediate resonant state is taken as $6d^1D_2$ with the 4-photon resonance wavelength of 560.7 nm. The ionization signal is measured as Hg vapor pressure (0.1-3.0 Torr), laser intensity $(10-120GW/\textrm{cm}^2)$, and laser wavelength (559-569 nm) vary. AC Stark shift and line broadening of the resonant state $(6d^1D_2)$ are observed and the shift factor is measured to be $-0.6(cm^{-1}/GW/\textrm{cm}^2$. It is also observed that the ionization signal increases as the Hg vapor pressure increases up to a certain value of pressure, however, if the pressure further increases, the signal decreases. The order of non-linearity, which discribes the laser intensity dependence of ionization rate, is measured to be 3 at the resonance, and compared with the theoretical results.esults.

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액체 속에서의 고전압 펄스 플라즈마 발생 및 분광학적 플라즈마 특성연구

  • Park, Ji-Hun;Kim, Yong-Hui;Jeon, Su-Nam;Park, Bong-Sang;Choe, Eun-Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.549-549
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    • 2013
  • 고전압 펄스 플라즈마를 액체 속에서 발생시켜 수소 스펙트럼의 광학적 특성을 연구하였다. 고전압 펄스 발생 장치인 막스 제네레이터는 용량이 $0.5{\mu}F$인 축전기 5개로 이루어져 있다. 각각의 축전기는 전원 장치를 이용하여 저항을 통해 병렬로 충전되며, 방전 시에는 불꽃 방전 스위치에 의해 동시에 직렬로 연결되어 고전압을 발생시킨다. 따라서, 출력 전압과 전류는 40kV, 3 kA이며 총 에너지는 약 125 J이다. 직육면체 모양의 폴리카보네이트 용기 내부의 양쪽면에는 탐침 모양의 전극이 구성되어 있으며 전극 사이에서 고전압을 가진 플라즈마가 형성된다. 실험에서 액체로는 증류수를 사용하였다. 액체 방전 시 발생하는 수소 스펙트럼을 관측하기 위해 초점거리 30 cm의 monochromator를 이용하였고, 수소 알파선의 656.3 nm와 수소 베타선의 434.1 nm를 관측하였다. 전자 밀도의 측정법으로는 Stark broadening법을 이용하여 측정하였으며, 전자 온도는 Stark profile의 상대적인 전자 밀도의 비를 이용하여 계산하였다. 전자밀도는 실험조건에서 약 $3{\times}10^{15}cm^{-3}$, 전자온도는 약 2.5 eV가 측정되었다.

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Spatially and Time Resolved Optical Diagnostics for High Pressure Microdischarges

  • Pu, Yi-Kang;Zhu, Xi-Ming;Huang, Bang-Dou;Takashima, Keisuke
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.140-140
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    • 2013
  • This presentation will describe recent developement in spatially and time resolved optical diagnostics for two kinds of the high pressure microdischarges. The first kind is a nanosecond pulsed discharge with two pin electrodes while the second kind is a microwave split ring resonator developed by Jeff Hopwood. Both spatially and time resolved optical emissions are collected for these two discharges and some interesting phenomena are observed. By using either the Stark broadening or a collisional radiative model for high pressure discharges, the evolution of electron density can be obtained. We will compare these different techniques for obtaining the electron density and discuss their limitations.

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Intermodulation Distortion in Multiple Quantum-Well Electroabsorption Modulator (다중 양자 우물 구조의 전계 흡수 변조기의 혼변조 왜곡 특성)

  • Yun Youngseol;Choi Young-Wan
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.6
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    • pp.293-297
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    • 2005
  • Linearity is an important property of optical devices for analog communications. In this paper, we study the 3rd-order interrnodulation distortion (IMD3) of an Inp/InGaAsP multiple-quantum-well (MQW) traveling-wave type electroabsorption modulator (TW-EAM). We observe abnormal notches in the IMD3 results those were different from notches by general transfer curve of electroabsorption modulators (EAMs). We analyze the phenomena through absorption coefficients according to wavelengths and bias voltages to verify appearance of the abnormal notchs, where it can be known to result from Stark-shift and broadening. We propose the method to enhance linearity of MQW-EAMs by using these effects.

Laser-induced plasma emission spectra of halogens in the helium gas flow and pulsed jet (헬륨 가스 플로우와 가스 펄스 젯에서 할로겐족 원소들의 레이저유도 플라즈마 방출 스펙트럼)

  • Lee, Yonghoon;Choi, Daewoong;Gong, Yongdeuk;Nam, Sang-Ho;Nah, Changwoon
    • Analytical Science and Technology
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    • v.26 no.4
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    • pp.235-244
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    • 2013
  • Detection of halogens using laser-induced breakdown spectroscopy (LIBS) in open air is very difficult since their strong atomic emission lines are located in VUV region. In NIR region, there are other emission lines of halogens through electronic transitions between excited states. However, these lines undergo Stark broadening severely. We report the observation of the emission lines of halogens in laser-induced plasma (LIP) spectra in NIR region using a helium gas flow. Particularly, the emission lines of iodine at 804.374 and 905.833 nm from LIPs have been observed for the first time. In the helium ambient gas, Stark broadening of the emission lines and background continuum emission could be suppressed significantly. Variations of the line intensity, plasma temperature, and electron density with the helium flow rate was investigated. Detection of chlorine and bromine in flame retardant of rubbers was demonstrated using this method. Finally, we suggest a pulsed helium gas jet as a practical and ecomonical helium gas source for the LIBS analysis of halogens in open air.

Measurement of Electron Temperature and Number Density and Their Effects on Reactive Species Formation in a DC Underwater Capillary Discharge

  • Ahmed, Muhammad Waqar;Rahman, Md. Shahinur;Choi, Sooseok;Shaislamov, Ulugbek;Yang, Jong-Keun;Suresh, Rai;Lee, Heon-Ju
    • Applied Science and Convergence Technology
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    • v.26 no.5
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    • pp.118-128
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    • 2017
  • The scope of this work is to determine and compare the effect of electron temperature ($T_e$) and number density ($N_e$) on the yield rate and concentration of reactive chemical species ($^{\bullet}OH$, $H_2O_2$ and $O_3$) in an argon, air and oxygen injected negative DC (0-4 kV) capillary discharge with water flow(0.1 L/min). The discharge was created between tungsten pin-to pin electrodes (${\Phi}=0.5mm$) separated by a variable distance (1-2 mm) in a quartz capillary tube (2 mm inner diameter, 4 mm outer diameter), with various gas injection rates (100-800 sccm). Optical emission spectroscopy (OES) of the hydrogen Balmer lines was carried out to investigate the line shapes and intensities as functions of the discharge parameters such as the type of gas, gas injection rate and inter electrode gap distances. The intensity ratio method was used to calculate $T_e$ and Stark broadening of Balmer ${\beta}$ lines was adopted to determine $N_e$. The effects of $T_e$ and $N_e$ on the reactive chemical species formation were evaluated and presented. The enhancement in yield rate of reactive chemical species was revealed at the higher electron temperature, higher gas injection rates, higher discharge power and larger inter-electrode gap. The discharge with oxygen injection was the most effective one for increasing the reactive chemical species concentration. The formation of reactive chemical species was shown more directly related to $T_e$ than $N_e$ in a flowing water gas injected negative DC capillary discharge.

Emission Plasma Spectroscopy of High-pressure Microdischarges

  • Lee, Byeong-Jun;Ju, Yeong-Do;Kim, Seung-Hwan;Ha, Tae-Gyun;Gong, Hyeong-Seop;Park, Yong-Jeong;Park, Jong-Do;Nam, Sang-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.253.2-253.2
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    • 2014
  • Micro hollow cathode discharges (MHCDs) are high-pressure, non-equilibrium discharges. Those MHCDs are useful to produce an excimer radiation. A major advantage of excimer sources is their high internal efficiency which may reach values up to 40% when operated under optimum conditions. To produce strong excimer radiation, the optimisation of the discharge conditions however needs a detailed knowledge of the properties of the discharge plasma itself. The electron density and temperature influence the excitation as well as plasma chemistry reactions and the gas temperature plays a major role as a significant energy loss process limiting efficiency of excimer radiation. Most of the recent spectroscopic investigations are focusing on the ultraviolet or vacuum ultraviolet range for direct detection of the excimer. In our experiments we have concentrated on investigating the micro hollow cathodes from the near UV to the near infrared (300~850 nm) to measure the basic plasma parameters using standard plasma diagnostic techniques such as stark broadening for electron density and the relative line intensity method for electron temperature. Finally, the neutral gas temperature was measured by means of the vibrational rotational structures of the second positive system of nitrogen.

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Characteristics of Nonthermal Plasma Source in Various Liquids

  • Lim, Seung-Ju;Min, Boo-Ki;Taylor, Nathan;Kim, Tae-Gyu;Kim, Hyeong-Seok;Yang, Seon-Pil;Jung, Jin-Yong;Han, Jin-Hyun;Lee, Jong-Yong;Kang, Seung-Oun;Choi, Eun Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.259.1-259.1
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    • 2014
  • Recently non-thermal plasma has been frequently applied to various research fields. The liquid plasma have received much attention lately because of interests in surgical and nanomaterial synthesis applications. Especially, intensive researches have been carried out for non-thermal plasma in liquid by using various electrode configurations and power supplies. We have developed a bioplasma source which could be used in a liquid, in which outer insulator has been covered onto the outer electrode. Also we have also put an insulator between the inner and outer electrode. Based on the surface discharge mode, the nonthermal bioplasma has been generated inside a liquid by using an alternating current voltage generator with peak voltage of 12 kV under driving frequency of 22 KHz. Here the discharge voltage and current have been measured for electrical characteristics. Especially, We have measured discharge and optical characteristics under various liquids of deionized (DI) water, tap water, and saline by using monochromator. We have also observed nitric oxide (NO), hydrogen peroxide (H2O2), and hydroxyl (OH) radical species by optical emission spectroscopy during the operation of bioplasma discharge inside various kinds of DI water, tap water, and saline. Here the temperature has been kept to be $40^{\circ}C$ or less when discharge in liquid has been operated in this experiment. Also we have measured plasma temperature by high speed camera image and density by using either H-alpha or H-beta Stark broadening method.

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