• 제목/요약/키워드: SrCO$_3$

검색결과 550건 처리시간 0.032초

중온형 고체산화물 연료전지를 위한 YSZ 전해질에서의 고성능 공기극 연구 (Study on high performance cathode on YSZ electrolyte for intermediate-temperature solid oxide fuel cells(IT-SOFC))

  • 이창보;배중면
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.368-371
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    • 2006
  • [ $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ ] cathode as a high performance cathode on YSZ electrolyte was studied by analyzing impedance spectra. It was shown that cathode property of $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ is bet ter than that of$La_{0.8}Sr_{0.2}CoO_3$. At $700^{\circ}C$ in air environment, $La_{0.8}Sr_{0.2}Co_{0.4}Mn_{0.6}O_3$ cathode on CGO- layered YSZ electrolyte showed very low area specific resistance of $0.14{\Omega}cm^2$, which is low enough for intermediate-temperature sol id oxide fuel cells. This is because material properties of ionic conductivity and thermal expansion compatibility with electrolyte were optimized. Judging from activation energy and oxygen part i al pressure dependance of cathode property, it was noted that oxygen surface exchange kinetics is dominantly influential on cathode property in higher temperature region than $700^{\circ}C$ and oxygen self-diffusion in cathode material is more influential in lower temperature region.

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Effect of Strontium Carbonate Content on Flexural Strength of Clay-Based Membrane Supports

  • Eom, Jung-Hye;Kim, Young-Wook;Song, In-Hyuck
    • 한국세라믹학회지
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    • 제52권6호
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    • pp.467-472
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    • 2015
  • The effect of $SrCO_3$ content on the microstructure, porosity, flexural strength, and pore size distribution of clay-based membrane supports was investigated. Green compacts prepared from low cost materials such as kaolin, bentonite, talc, sodium borate, and strontium carbonate were sintered at $1000^{\circ}C$ for 8 h in air. It was possible to control the porosity of the clay-based membrane supports within the range of 33% to 37% by adjusting the $SrCO_3$ content. The flexural strength of the clay-based membrane supports was found to strongly depend on their porosity. In turn, the porosity was affected by the $SrCO_3$ content. The average pore size and flexural strength of the clay-based membrane supports containing 4 wt% $SrCO_3$ were $0.62{\mu}m$ and 33 MPa at 34% porosity.

5-Bromo-Ph4-BTPhen Ligand for Selective Removal of Strontium and Cobalt From Water

  • Jang, Jiseon;Harwood, Laurence M.;Cowell, Joe;Afsar, Ashfaq;Lee, Dae Sung
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2018년도 춘계학술논문요약집
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    • pp.183-183
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    • 2018
  • In this study, 5-bromo-2,9-bis(5,6-diphenyl-1,2,4-triazin-3-yl)-1,10-phenanthroline (5-bromo-Ph4-BTPhen) was synthesized and evaluated for its ability to remove major radionuclides ($Cs^+$, $Sr^{2+}$, and $Co^{2+}$). The synthesized ligand removed both $Sr^{2+}$ and $Co^{2+}$ from $1mg\;L^{-1}$ aqueous solutions with extraction efficiencies of up to 99% at neutral and alkaline pH. The $Sr^{2+}$ and $Co^{2+}$ removal efficiencies decreased as a consequence of the higher bonding strengths of competing metal ions to the N-donor atoms in the cavity of the ligand; competing divalent ions affected the $Sr^{2+}$ and $Co^{2+}$ removal efficiencies more than monovalent ions.

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Impedance spectroscopy analysis of the $Li_2CO3$ doped $(Ba,Sr)TiO_3$ thick films

  • 함용수;고중혁
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.27-28
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    • 2009
  • In this study, we have fabricated the 3 wt% $Li_2CO3$ doped $(Ba,Sr)TiO_3$ thick films on the Ag/Pd printed $Al_2O_3$ substrates for the LTCCs (Low Temperature Co-fired Ceramics) applications. From the X-ray diffraion analysis, 3 wt% $Li_2CO3$ doped BST thick films on the Ag/Pd printed $Al_2O_3$ substrates, which sintered at 900 $^{\circ}C$ have perovskite structure without any pyro phase. The dielectric properties of 3 wt% $Li_2CO3$ doped BST thick films were measured from 1 kHz to 1 MHz. To investigate the electrical properties of 3 wt% $Li_2CO3$ doped BST thick films, we employed the impedance spectroscopy. The complex impedance of 3 wt% $Li_2CO3$ doped BST thick films were measured from 20 Hz to 1 MHz at the various temperatures.

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0.96K0.5Na0.5NbO3-0.04SrTiO3 세라믹스의 상전이와 압전 특성에 대한 Li2CO3 도핑 효과 (Effect of Li2CO3 Doping on Phase Transition and Piezoelectric Properties of 0.96K0.5Na0.5NbO3-0.04SrTiO3 Ceramics)

  • 박재영;즈엉 짱 안;이상섭;안창원;김병우;한형수;이재신
    • 한국전기전자재료학회논문지
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    • 제36권5호
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    • pp.513-519
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    • 2023
  • It was reported that a tetragonal phase can be stabilized with maintaining good piezoelectric properties when Na0.5K0.5NbO3 (KNN) is modified with 0.06 mol SrTiO3. However, such a high amount of SrTiO3 leads not only to poor sinterability but low Curie temperature (TC). To maintain high TC with good piezoelectric properties in KNN-based lead-free piezoelectric ceramics, this study investigates the effect of Li-doping on the dielectric and piezoelectric properties of 0.96Na0.5K0.5NbO3-0.04SrTiO3 (KNN-4ST) ceramics. As a result, the orthorhombic-tetragonal phase transition was observed at 2 mol% Li2CO3 modified KNN-4ST ceramics, whose TC, d33 and kp values are 328℃, 165pC/N and 0.33, respectively.

Electrosorption and Separation of $Co^{2+}$ and $Sr^{2+}$ Ions from Decontaminated Liquid Wastes

  • Kim, Jun-Soo;Jung, Chong-Hun;Oh, Won-Zin;Ryu, Seung-Kon
    • Carbon letters
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    • 제3권1호
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    • pp.6-12
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    • 2002
  • A study on the electrosorption of $Co^{2+}$ and $Sr^{2+}$ ions onto a porous activated carbon fiber (ACF) was performed to treat radioactive liquid wastes resulting from chemical or electrochemical decontamination and to regenerate the spent carbon electrode. The result of batch electrosorption experiments showed that applied negative potential increased adsorption kinetics and capacity in comparison with open-circuit potential (OCP) adsorption for $Co^{2+}$ and $Sr^{2+}$ ions. The adsorbed $Co^{2+}$ and $Sr^{2+}$ ions are released from the carbon fiber by applying a positive potential on the electrode, showing the reversibility of the sorption process. The possibility of application of the electrosorption technique to the separation of radionuclides was examined. The result of a selective removal experiments of a single component from a mixed solution showed that perfect separation of $Co^{2+}$ and $Sr^{2+}$ ions was possible by the electrosorption process.

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Catalytic Activity of $Nd_{1-x}Sr_xCoO_{3-y}$ on the Oxidation of Carbon Monoxide

  • Kim, Keu-Hong;Kim, Seong-Han;Lee, Dong-Hoon;Kim, Yoo-Young;Choi, Jae-Shi
    • Bulletin of the Korean Chemical Society
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    • 제12권1호
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    • pp.35-39
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    • 1991
  • The catalytic activity of $Nd_{1-x}Sr_xCoO_{3-y}$, $0{\leq}x{\leq}0.75$ and $0.001{\leq}y{\leq}0.103$, on the oxidation of carbon monoxide has been investigated from the structure analyses of the catalysts by X-ray diffraction and infrared spectroscopy and the measurements of the oxidation and adsorption rates of carbon monoxide. The catalytic activity is found to be correlated with Sr substitution (x) and nonstoichiometry (y). The oxidation power of carbon monoxide increases continuously with increasing Sr substitution without oxygen, but increases with Sr substitution up to x = 0.25 and then is almost constant at larger x values up to x = 0.75 with oxygen. This change of catalytic activity is explained by the oxidation-reduction properties of the catalyst due to the variation of nonstoichiometry.

Sr1-xBaxAl2O4:Eu2+, Dy3+계 축광성 형광체의 합성과 그의 발광특성 (Synthesis and Photoluminescence of the Sr1-xBaxAl2O4:Eu2+, Dy3+ Long Phosphorescence Phosphor)

  • 박진우;김정식
    • 한국세라믹학회지
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    • 제43권6호
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    • pp.333-337
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    • 2006
  • In this study, the $Sr_{1-x}Ba_{x}Al_{2}O_{4}:Eu^{2+},Dy^{3+}$ phosphor were prepared by the solid-state reaction method and its photoluminescence properties were investigated. Starting powders of $SrCO_3,\;BaCO_3,\;and\;Al_{2}O_3$ were mixed with $Eu_{2}O_3$ as activator, $Dy_{2}O_3$ as co-activator and $B_{2}O_3$ as flux. Then, the mixed powders were heated at the temperature of $1100{\sim}1400^{\circ}C$ for 3 h under the reducing ambient atmosphere of $95%Ar+5%H_2$. The effect of Ba addition from 0.0 to 1.0 mol on photoluminescence was investigated. As the amount of Ba increased, the intensity of emission increased and the optimum long phosphorescence occurred at the amount of 0.1 mol Ba. The optimum sintering condition for long phosphorescent phosphor of $Sr_{1-x}Ba_{x}Al_{2}O_{4}:Eu^{2+},Dy^{3+}$($x=0{\sim}1.0mol$) was found at $1400^{\circ}C$. The excitation spectra showed a broad band of $250{\sim}450nm$ with maximum peak at 360 nm. The maximum peak intensity of emission spectra occurred at the range of $480{\sim}520nm$, depending on Ba content.

고체산화물 연료전지용 La0.7Sr0.3Ga0.6Fe0.4O3-δ계의 메탄부분산화반응 (Partial Oxidation of CH4 Using {0.7}Sr0.3Ga0.6Fe0.4O3-δ for Soild Oxide Fuel Cell)

  • 이승영;이기성;이시우;김종원;우상국
    • 전기화학회지
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    • 제6권1호
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    • pp.59-64
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    • 2003
  • 고상 반응법을 이용하여 $La_{0.7}Sr_{0.3}Ga_{0.6}Fe_{0.4}O_{3-\delta}$ 분말을 합성하고 소결하여 혼합전도성 분리막을 제조하였다. 제조된 분리막들은 페롭스카이트 단일상 결정구조를 나타내었으며, $95\%$, 이상의 상대밀도를 나타내었다. 산소이온 변환 능력을 향상시키기 위해 $La_{0.7}Sr_{0.3}Ga_{0.6}Fe_{0.4}O_{3-\delta}$의 양 표면에 $La_{0.6}Sr_{0.4}CoO_{3-\delta}$ paste를 스크린 프린팅 방법으로 코팅한 결과, 코팅되지 않은 분리막에 비해 산소투과 유속이 크게 증가하여 $950^{\circ}C,\; {\Delta}P_{o_2}=0.21 atm$에서 약 $0.5ml/min{\cdot}cm^2$의 값을 나타내었다. 이러한 산소투과 유속은 표면 코팅층이 다공성일수록, $La_{0.7}Sr_{0.3}Ga_{0.6}Fe_{0.4}O_{3-\delta}$의 결정립 크기가 증가할수록 증가하는 경향을 나타내었다. 제조된 디스크 형상의 소결체를 이용하여 $950^{\circ}C$에서 메탄부분산화반응을 행한 결과 $40\%$ 이상의 메탄전환율과 합성가스의 수율을 얻을 수 있었으며, CO의 선택도는 $100\%$를 나타내었다 또한, $950^{\circ}C$의 메탄분위기에서 600시간의 장기부분산화반응을 통해 상의 안정성을 확인하였다.

1,2차 첨가제가 이방성 $SrO-5.7Fe_2O_3$의 자기적 특성에 미치는 효과 (A Study on the Effects of first and second additives Magnetic Characteristics of Anisotropic $SrO-5.7Fe_2O_3$.)

  • 송준태;신용덕;정인영;진홍범
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1990년도 하계학술대회 논문집
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    • pp.239-242
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    • 1990
  • The effect of $CaCo_3$, $SrCo_3$, $SiO_2$ and $H_3BO_3$ in the range of 0.1-1.0 wt% on strontium ferrites consisting of the magnetoplumbite phase $SrO-5.7Fe_2O_3$ were investigated. The hysteresis loop, density, demagnetization curve and the intrinsic coercive force were measured on anisotropic ferrite. The particle diameter and 0.5(wt%) of second additive $CaCo_3$ is particularly important for the properties of anisotropic ferrite. When the particle diameter is decreased from 1.98(${\mu}m$) to 1.07(${\mu}m$), the remance is increased from 2900 to 4010(G) and the coercive force from 2150 to 2850(Oe) at a sintering temperature 1230 ($^{\circ}C$). Remance Br(G), coercleve force(Oe) and maximum energy product of sample A-16 are87(%), 56(%), 67(%) of S-W model theoretical value.

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