• Title/Summary/Keyword: Spin coating.

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Organic Light Emitting Diodes (OLED) with Electrostatic spray deposition (ESD)

  • Hwang, Won-Tae;Kim, Nam-Hun;Xin, Guoqing;Jang, Hae-Gyu;Chae, Hee-Yeop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.432-432
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    • 2010
  • Organic light emitting diodes (OLED) thin films were fabricated by Electrostatic spray deposition (ESD). In this study, we reported the thickness, morphology, current efficiency, luminescence of OLED fabricated by ESD. These results were compared with the spin coating method, and showed that also ESD is a good fabrication method for OLED because of its characteristics similar with the results using spin coating. The active layer consists of organic blends with Poly(N-vinylcarbazole) (PVK), 2-(4-Biphenyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole (PBD), N,N'-Bis(3-methylphenyl) -N,N'-bis(phenyl)-benzidine (TPD), Tris(2-phenylpyridine)iridium(III) (Ir(ppy)3), and the structure of OLED consists of aluminum (Al), lithium fluoride (LiF), organic blends, PEDOT:PSS and Indium-tin-oxide (ITO), which was used as the top cathode, cathode interfacial layer, emitting layer and bottom anode, respectively. The results suggest that Electrostatic spray deposition is a promising method for the next generation of OLED fabrication since it has a probability fabricating large-area thin films.

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Photoluminescence Studies of ZnO Nanostructures Fabricated by Using Combination of Hydrothermal Method and Plasma-Assisted Molecular Beam Epitaxy Regrowth

  • Nam, Giwoong;Kim, Byunggu;Park, Youngbin;Kim, Soaram;Lee, Sang-Heon;Kim, Jong Su;Leem, Jae-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.202.1-202.1
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    • 2013
  • ZnO nanostructure was fabricated on a Si substrate using two-step growth. The seed layer was grown on the Si substrate by a sol-gel spin-coating. In the first step, ZnO nanorods were grown by a hydrothermal method at $140^{\circ}C$ for 5 min. In the second step, a ZnO thin film was grown on the ZnO nanorods by spin-coating. After growth, these films were annealed at $800^{\circ}C$ for 10 min. Electrical and optical properties of ZnO nanostructures have modified by plasma-assisted molecular beam epitaxy (PA-MBE) regrowth. The carrier concentration and resistivity increased by PA-MBE regrowth. In the photoluminescence, the full width at half maximum and intensity were decreased and increased, respectively, by PA-MBE regrowth.

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Low Temperature Annealing Effect of PFO-Poss Emission Layer on the Properties of Polymer Light Emitting Diodes

  • Gong, Su-Cheol;Chang, Ho-Jung
    • Korean Journal of Materials Research
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    • v.19 no.6
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    • pp.313-318
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    • 2009
  • Polymer Light Emitting Diodes (PLEDs) with an ITO/PEDOT:PSS/PVK/PFO-poss/LiF/Al structure were prepared on plasma-treated ITO/glass substrates using spin-coating and thermal evaporation methods. The annealing effects of the PFO-poss film when it acts as the emission layer were investigated by using electrical and optical property measurements. The annealing conditions of the PFO-poss emission film were 100 and $200^{\circ}C$ for 1, 2 and 3 hours, respectively. The luminance increased and the turn-on voltage decreased when the annealing temperature and treatment time increased. After examining the Luminance-Voltage (L-V) properties of the PLED, the maximum luminance was found to be 1497 cd/$m^2$ at 11 V for the device when it was annealed at $200^{\circ}C$ for 3 hours. The peak intensity of the PLED emission spectra at approximately 525 nm in wavelength increased when the annealing temperature and time of the PFO-poss film increased. These results suggest that the light emission color shifted from blue to green.

Comparison Study of Compact Titanium Oxide (c-TiO2) Powder Electron Transport Layer Fabrication for Carbon Electrode-based Perovskite Solar Cells (탄소전극 기반 페로브스카이트 태양전지 적용을 위한 조밀 이산화티타늄 분말 전자수송층 제작 비교 연구)

  • Woo, Chae Young;Lee, Hyung Woo
    • Journal of Powder Materials
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    • v.29 no.4
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    • pp.297-302
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    • 2022
  • This study compares the characteristics of a compact TiO2 (c-TiO2) powdery film, which is used as the electron transport layer (ETL) of perovskite solar cells, based on the manufacturing method. Additionally, its efficiency is measured by applying it to a carbon electrode solar cell. Spin-coating and spray methods are compared, and spray-based c-TiO2 exhibits superior optical properties. Furthermore, surface analysis by scanning electron microscopy (SEM) and atomic force microscopy (AFM) exhibits the excellent surface properties of spray-based TiO2. The photoelectric conversion efficiency (PCE) is 14.31% when applied to planar perovskite solar cells based on metal electrodes. Finally, carbon nanotube (CNT) film electrode-based solar cells exhibits a 76% PCE compared with that of metal electrode-based solar cells, providing the possibility of commercialization.

Effect of Nanomesh Structure Variation on the Friction and Wear Characteristics of Carbon Nanotube Coatings (탄소나노튜브 코팅의 마찰/마모 특성에 대한 나노메쉬 구조의 영향)

  • Kim, Hae-Jin;Kim, Chang-Lae
    • Tribology and Lubricants
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    • v.36 no.6
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    • pp.315-319
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    • 2020
  • In various fields, several studies based on carbon nanotubes (CNTs) have been conducted. The results of previous studies, wherein CNT coatings have been incorporated as solid lubricants, demonstrate that the friction and wear characteristics of CNT coatings can be improved through the absorption/dispersion of the contact pressure by controlling the stiffness of the nanomesh structure comprising CNT strands. In this study, the friction and wear characteristics of the following are compared: CNT coating formed by spin coating of CNT solution, compressed CNT coating, and compressed/heated CNT coating (wherein CNT strands are squeezed through compression and/or heating). It is observed that the friction coefficient of the CNT coating having the largest number of voids between the CNT strands is significantly lower than those of the compressed CNT coating and the compressed/heated CNT coating. The wear tracks of the compressed CNT coating and the compressed/heated CNT coating indicate that some parts become torn or adhere into a lump. However, in the case of the CNT coating, a smooth wear surface is formed by rubbing. Furthermore, as the void space between the squeezed and adhered CNT strands decreases, the resistance to structural deformation increases, thereby resulting in an increased frictional force and a wear pattern that becomes torn or forms a lump. Hence, the results obtained from this study corroborate that the friction and wear characteristics of CNT coatings can be enhanced through the absorption/dispersion of the contact pressure by controlling the stiffness of the nanomesh structure of CNT coatings.

A Study on Properties of PVA/$SiO_2$ Organic-inorganic Hybrid Materials Barrier Layer Coated on Flexible Substrate (PEN)

  • Koo, Tae-Wook;Farva, Umme;Yu, Eric S.H.;Kim, Yun-Su;Park, Chin-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.657-659
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    • 2008
  • Barrier coating properties of PVA/$SiO_2$ on the flexible substrates (PEN) have been investigated. Thin layer of PVA/$SiO_2$ organic-inorganic hybrid materials were deposited on PEN substrate by the spin-coating. The optical properties and surface roughness of barrier layer on flexible substrate were characterized by AFM, UV-Vis and WVTR/ OTR.

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Chemically Modified Superhydrophobic Zinc Oxide nanoparticle surface

  • Lee, Mi-Gyeong;Gwak, Geun-Jae;Yong, Gi-Jung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.448-448
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    • 2011
  • We investigated the fabrication method of superhydrophobic nanocoating prepared by a simple spin-coating and the chemisorption of fatty acid. The resulting coating showed a tremendous water repellency (static water contact angle = $154^{\circ}$) and the water contact angle can be modulated by changing the number of deposition cycles of ZnO and the carbon length of Self-Assembled Monolayers (SAM). Varying the number of deposition cycles of ZnO controlled the surface roughness, and affected to the superhydrophobicity. This simple coating method can be universally applicable to any substrates including flexible surfaces, papers and cotton fabrics, which can effectively be used in various potential applications. We also observed the thermal and dynamic stabilities of SAM on ZnO nanoparticles. The superhydrophobicic surface maintained its superhydrophobic properties below $250^{\circ}C$ and under dynamic conditions.

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A Preparation of Copper Phthalocyanine Photoreceptor by an Aqueous Coating Method and Study of Dark Decay and Photoinjection Efficiency (신규 제작법을 이용한 Copper Phthalocyanine 전자사진 감광체의 개발과 Dark Decay와 Photoinjection Efficiency에 관한 연구)

  • 이상남
    • Journal of the Korean Graphic Arts Communication Society
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    • v.11 no.1
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    • pp.103-122
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    • 1993
  • A cause and counterplan of the increase in dark decay rate of$\varepsilon$-CuPc/PVCz photoreceptor which is consist of the carrier generation layer (CGL) of$\varepsilon$type copper phthalocyanine ($\varepsilon$-CuPc) thin film by an aqueous coating method and the carrier transport layer (CTL) of polyvinylcarbazol (PVCz) by spin coating, are studied in this paper. Electrochemical deposition of CGL was accompanied by an increase in work function of the aluminium substrate during the processes and the enhanced work function 5.3 eV rose above the ionization potential 5.16 eV of $\varepsilon$-CuPc. This resulted in the increased injection of holes from substrate into CGL and a fast dark decay rate. Improved photoreceptor, an electron-transport $\varepsilon$-CuPc/TNF photoreceptor, led to lowing of dark decay rate and increasing of photosensitivity. The carrier generation efficiency (ηg), carrier injection efficiency (ηi) and xerographic gain (G) of the $\varepsilon$-CuPc/TNF photoreceptor were obtained by XTOF method and PIDC.

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Synthesis and Dispersion Stabilization of Indium Tin Oxide Nanopowders by Coprecipitation and Sol-Gel Method for Transparent and Conductive Films

  • Cho, Young-Sang;Hong, Jeong-Jin;Kim, Young Kuk;Chung, Kook Chae;Choi, Chul Jin
    • Korean Journal of Metals and Materials
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    • v.48 no.9
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    • pp.831-841
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    • 2010
  • Indium tin oxide (ITO) nanopowders were synthesized by coprecipitation and the sol-gel method to prepare a stable dispersion of ITO nano-colloid for antistatic coating of a display panel. The colloidal dispersions were prepared by attrition process with a vibratory milling apparatus using a suitable dispersant in organic solvent. The ITO coating solution was spin-coated on a glass panel followed by the deposition of partially hydrolyzed alkyl silicate as an over-coat layer. The double-layered coating films were characterized by measuring the sheet resistance and reflectance spectrum for antistatic and antireflective properties.

Photochromic Properties of Spiropyran in Hard Coating Films Made by Sol-Gel Method (Sol-Gel 하드 코팅 막에서의 Spiropyran의 광 변색 특성)

  • Jeong, Sang Hyeok;Cho, Kyung In;Park, Jeong Yong;Song, Ki Chang
    • Korean Chemical Engineering Research
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    • v.46 no.2
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    • pp.310-315
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    • 2008
  • Organic-inorganic hybrid solutions were made using glycidoxypropyl trimethoxysilane (GPTMS) and vinyltriethoxysilane (VTES) as starting materials by sol-gel method. Photochromic coating solutions were prepared by mixing the solution of photochromic dye (spiropyran) dissolved in ethylacetate with the organic-inorganic hybrid solutions. Photochromic films were prepared on polycarbonate sheets by spin coating and cured for 2 h at $100^{\circ}C$. The resulting films exhibited a reversible color change upon irradiation with UV light from transparent to blue. The color-fading speed and pencil hardness of the coating films increased with increasing the GPTMS content in the coating solutions.