• Structural Engineering and Mechanics
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• v.78 no.5
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• pp.557-572
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• 2021

The current study considers free vibration of the spherical panel with magnetorheological (MR) fluids core and magneto-electro-elastic face sheets. The panel is subjected to electro-magnetic loads and also is located on an orthotropic visco-Pasternak elastic foundation. To describe the displacement components of the structure, the first-order shear deformation theory (FSDT) is used and the motion equations are extracted by employing Hamilton's principle. To solve the motion differential equations, Navier's method is selected as an exact analytical solution for simply supported boundary conditions. Effect of the most important parameters such as magnetic field intensity, loss factor, multi-physical loads, types of an elastic medium, geometrical properties of the panel, and also different material types for the face sheets on the results is considered and discussed in details. The outcomes of the present work may be used to design more efficient smart structures such as sensors and actuators.

• Journal of the Korean Applied Science and Technology
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• v.22 no.4
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• pp.306-314
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• 2005

In this study, spherical $pre-BaTiO_3$ particles are prepared by gelation and aging process in autoclave without catalysts. The (Ba-Ti) gel used as a starting material was prepared by aging mixtures of titanyl acylate with barium acetate aqueous solution([glacial acetic acid (AcOH)]/[titanium isopropoxide (TIP)] 4, [barium acetate]/[TIP] 1) at $45^{\circ}C$ for 48hrs. XRD and SEM results for the (Ba-Ti) gel sample at aging process showed that the gel was formed via aggregation of the fine particles. It seems to be the primary particles of bulk (Ba-Ti) gel amorphous, but the spatial arrangement of barium and titanium in the (Ba-Ti) gel is similar to that in crystalline $BaTiO_3$ particles. From XRD and FT-IR. spectroscopy analysis it was found that the crystal structure of the prepared particles continuously transformed from amorphous to tetragonal as the calcination temperature increased, and crystallized spherical cubic and tetragonal $BaTiO_3$ powder obtained at the very low calcination temperature between $500^{\circ}C$ and $900^{\circ}C$ after 1hrs of heat treatment respectively. According to BET analysis result, final particle have pore structure of ink bottle shape which is produced by aggregation of fine spherical particles with surface area of $280m^2/g$ and average pore size of 130nm.

• Journal of the Korean Ceramic Society
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• v.48 no.5
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• pp.447-453
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• 2011

The monodisperse spherical $SiO_2$ particles were overcoated with $Y_2O_3:Eu^{3+}$ phosphor layers via a Pechini sol-gel process and the resulting $SiO_2@Y_2O_3:Eu^{3+}$ core-shell phosphors were subsequently annealed at $800^{\circ}C$ at an ambient atmosphere. The crystallographic structure, morphology, and luminescent property of core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and photoluminescence (PL). The spherical, nonagglomerated $SiO_2$ particles prepared by a Stober method exhibited a relatively narrow size distribution in the range of 260-300 nm. The thickness of phosphor shell layer in the core-shell particles can be facilely controlled by varying the coating number of $Y_2O_3:Eu^{3+}$ phosphors. The core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors showed a strong red emission, which was dominated by the $^5D_0-^7F_2$ transition (610 nm) of $Eu^{3+}$ ion under the ultraviolet excitation (263 nm). The PL emission properties of $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were also compared with pure $Y_2O_3:Eu^{3+}$ nanophosphors.

• Bulletin of the Korean Chemical Society
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• v.26 no.1
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• pp.107-114
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• 2005

Molecular aggregates of surfactant molecules consisting of one or more bilayers arranged in a hollow, closed, usually spherical geometry are termed “esicles”or “iposomes” In recent years it has been found that in certain systems the vesicular structure forms spontaneously and is long lived, and it has been suggested that these structures may in fact constitute the equilibrium state in these cases (as is true of micelles) This paper deals with the mixed CMC, vesicles, phase behavior, phase transition, geometrical structure, their formation and characterization in the aqueous solutions of mixed cationic/anionic surfactants systems. TEM micrographs revealed that the vesicles were of spherical shape and that their size was of around 180 nm. The zeta potentials are positive at CGS1-rich regions and negative at SLES-rich regions. In the region where SLES/CGS1 (6/4), the zeta potentials are very small, implying that the vesicles at this surfactant ratio may be less stable. At other surfactant ratios, the vesicles are thought to be stable, supported by large absolute values of zeta potentials and little change in UV absorbance for several months.

• Nuclear Engineering and Technology
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• v.54 no.4
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• pp.1161-1166
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• 2022

Green pitch coke with an average particle size of 2 mm was adopted as densifier and added to the raw materials of conventional A3-3 matrix graphite (MG) to prepare modified A3-3 matrix graphite (MMG) by the quasi-isostatic molding method. The structure, mechanical and thermal properties were assessed. Compared with MG, MMG had a more compact structure, and exhibited improved properties of higher mechanical strength, higher thermal conductivity and better molten salt barrier performance. Notably, under the same infiltration pressure of 5 atm, the fluoride salt occupation of MMG was only 0.26 wt%, whereas it was 15.82 wt% for MG. The densification effect of green pitch coke endowed MMG with improved properties for potential use in the spherical fuel elements of molten salt reactor.

• Journal of Powder Materials
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• v.29 no.6
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• pp.485-491
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• 2022

Lithium lanthanum titanium oxide (LLTO) is a promising ceramic electrolyte because of its high ionic conductivity at room temperature, low electrical conductivity, and outstanding physical properties. Several routes for the synthesis of bulk LLTO are known, in particular, solid-state synthesis and sol-gel method. However, the extremely low ionic conductivity of LLTO at grain boundaries is one of the major problems for practical applications. To diminish the grain boundary effect, the structure of LLTO is tuned to nanoscale morphology with structures of different dimensionalities (0D spheres, and 1D tubes and wires); this strategy has great potential to enhance the ion conduction by intensifying Li diffusion and minimizing the grain boundary resistance. Therefore, in this work, 0D spherical LLTO is synthesized using ultrasonic spray pyrolysis (USP). The USP method primarily yields spherical particles from the droplets generated by ultrasonic waves passed through several heating zones. LLTO is synthesized using USP, and the effects of each precursor and their mechanisms as well as synthesis parameters are analyzed and discussed to optimize the synthesis. The phase structure of the obtained materials is analyzed using X-ray diffraction, and their morphology and particle size are analyzed using field-emission scanning electron microscopy.

• Steel and Composite Structures
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• v.50 no.4
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• pp.375-382
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• 2024

The network theory studies interconnection between discrete objects to find about the behavior of a collection of objects. Also, nanomaterials are a collection of discrete atoms interconnected together to perform a specific task of mechanical or/and electrical type. Therefore, it is reasonable to use the network theory in the study of behavior of super-molecule in nano-scale. In the current study, we aim to examine vibrational behavior of spherical nanostructured composite with different geometrical and materials properties. In this regard, a specific shear deformation displacement theory, classical elasticity theory and analytical solution to find the natural frequency of the spherical nano-composite structure. The analytical results are validated by comparison to finite element (FE). Further, a detail comprehensive results of frequency variations are presented in terms of different parameters. It is revealed that the current methodology provides accurate results in comparison to FE results. On the other hand, different geometrical and weight fraction have influential role in determining frequency of the structure.

• Journal of the Korean earth science society
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• v.37 no.2
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• pp.107-116
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• 2016

Stability of the barotropic Rossby-Haurwitz wave is investigated using the numerical models on the global domain. The Rossby-Haurwitz wave under investigation is composed of the basic zonal flow of super-rotation and a finite amplitude spherical harmonic wave. The Rossby-Haurwitz wave is given as either steady or unsteady wave by adjusting the strength of the super-rotating zonal flow. Stability as well as the growth rate of the wave in the numerical simulation is determined by comparing the perturbation amplitude at two different time stages. Unstable modes of the Rossby-Haurwitz wave exhibited a horizontal structure composing of various zonal-wavenumber components. The vorticity perturbation for some modes showed a discontinuity around the area of weak flow, which was found robust regardless of the horizontal resolution of the model. Fourier finite element model was shown to generate the unstable mode in earlier stage of the time integration due to less accuracy compared to the spherical harmonic spectral model. Taking the overall accuracy of the models into consideration, the time by which the unstable mode begin to dominate over the spherical harmonic wave was estimated.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.28 no.4
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• pp.261-268
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• 2017

In this paper, we propose an FSSH(Folded Slot Spherical Helix) magnetic dipole antenna with a form factor easy to build and study its radiation properties. The number of folded arms, the gap between them and the metal thickness are tuned to achieve relatively simple structure to realize whereas maintaining high radiation efficiency at an electrically small size. The proposed design shows wide radiation efficiency bandwidth and it is confirmed by circuit simulation that the non-Foster impedance matching techniques could be utilized for its practical use. The prototype of the proposed antenna is built with the aid of an SLS(Selective Laser Sintering) 3D printing technology. The measured result shows lower Q impedance characteristic due to high resistive loss of the copper tape joints.

• Korean Journal of Materials Research
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• v.25 no.11
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• pp.602-606
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• 2015

Porous W with spherical and directionally aligned pores was fabricated by the combination of sacrificial fugitives and a freeze-drying process. Camphene slurries with powder mixtures of $WO_3$ and spherical PMMA of 20 vol% were frozen at $-25^{\circ}C$ and dried for the sublimation of the camphene. The green bodies were heat-treated at $400^{\circ}C$ for 2 h to decompose the PMMA; then, sintering was carried out at $1200^{\circ}C$ in a hydrogen atmosphere for 2 h. TGA and XRD analysis showed that the PMMA decomposed at about $400^{\circ}C$, and $WO_3$ was reduced to metallic W at $800^{\circ}C$ without any reaction phases. The sintered bodies with $WO_3$-PMMA contents of 15 and 20 vol% showed large pores with aligned direction and small pores in the internal walls of the large pores. The pore formation was discussed in terms of the solidication behavior of liquid camphene with solid particles. Spherical pores, formed by decomposition of PMMA, were observed in the sintered specimens. Also, microstructural observation revealed that struts between the small pores consisted of very fine particles with size of about 300 nm.