• Proceedings of the KIEE Conference
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• 2009.07a
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• pp.1473_1474
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• 2009

To develop electrically reliable high voltage apparatuses, the experimental study on the electrical breakdown field strength is needed, as well as theoretical approach. In this paper, lightning impulse breakdown characteristics considering utilization factors are investigated for the establishment of insulation design criteria of an high voltage apparatus. The utilization factors are represented as the ratio of mean electric field to maximum electric field. Dielectric experiments are performed by using five kinds of sphere-plane electrode systems made of stainless steel. As a result, it is found that dielectric characteristics are affected by not only gap length but also utilization factor of electrode systems. The results are expected to be applicable to the design of high voltage apparatuses.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.60 no.5
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• pp.1005-1010
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• 2011

The accidents caused by dielectric instability have been increasing in power grid. It is important to enhance the dielectric reliability of a high voltage apparatus to reduce the damage from electrical hazards. To develop an electrically reliable high voltage apparatus, the experimental study on the electrical breakdown field strength is indispensable, as well as theoretical approach. In this paper, the lightning impulse breakdown characteristics considering utilization factors are studied for the establishment of insulation design criteria of an high voltage apparatus. The utilization factors are represented as the ratio of mean electric field to maximum electric field. Dielectric experiments are performed by using several kinds of sphere-plane electrode systems made of stainless steel. As a result, it is found that dielectric characteristics are affected by not only maximum electric field intensity but also utilization factors of electrode systems. The results are expected to be applicable to designing the air-insulated high voltage apparatuses.

• Journal of Electrochemical Science and Technology
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• v.7 no.4
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• pp.316-326
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• 2016

Development and discovery of efficient, cost-effective, and robust electrocatalysts are imperative for practical and widespread implementation of water electrolysis and fuel cell techniques in the anticipated hydrogen economy. The electrochemical reactions involved in water electrolysis, i.e., hydrogen and oxygen evolution reactions, are complex inner-sphere reactions with slow multi-electron transfer kinetics. To develop active electrocatalysts for water electrolysis, the physicochemical properties of the electrode surfaces in electrolyte solutions should be investigated and understood in detail. When electrocatalysis is conducted using nanoparticles with large surface areas and active surface states, analytical techniques with sub-nanometer resolution are required, along with material development. Scanning electrochemical microscopy (SECM) is an electrochemical technique for studying the surface reactions and properties of various types of electrodes using a very small tip electrode. Recently, the morphological and chemical characteristics of single nanoparticles and bio-enzymes for catalytic reactions were studied with nanometer resolution by combining SECM with atomic force microscopy (AFM). Herein, SECM techniques are briefly reviewed, including the AFM-SECM technique, to facilitate further development and discovery of highly active, cost-effective, and robust electrode materials for efficient electrolysis and photolysis.

• Korean Journal of Materials Research
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• v.27 no.12
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• pp.658-663
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• 2017

Urchin-structured zinc oxide(ZnO) nanorod(NR) gas sensors were successfully demonstrated on a polyimide(PI) substrate, using single wall carbon nanotubes(SWCNTs) as the electrode. The ZnO NRs were grown with ZnO shells arranged at regular intervals to form a network structure with maximized surface area. The high surface area and numerous junctions of the NR network structure was the key to excellent gas sensing performance. Moreover, the SWCNTs formed a junction barrier with the ZnO which further improved sensor characteristics. The fabricated urchin-structured ZnO NR gas sensors exhibited superior performance upon $NO_2$ exposure with a stable response of 110, fast rise and decay times of 38 and 24 sec, respectively. Comparative analyses revealed that the high performance of the sensors was due to a combination of high surface area, numerous active junction points, and the use of the SWCNTs electrode. Furthermore, the urchin-structured ZnO NR gas sensors showed sustainable mechanical stability. Although degradation of the devices progressed during repeated flexibility tests, the sensors were still operational even after 10000 cycles of a bending test with a radius of curvature of 5 mm.

• Fire Science and Engineering
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• v.17 no.2
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• pp.25-34
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• 2003

In this paper, characteristics of the DC flashover voltage in the horizontal air gap of sphere-sphere/needle-needle electrode system were investigated when the combustion flame of paraffin oil was present between the two electrodes. The reduction characteristic of DC flashover voltage was discussed with the thermal ionization process, the relative air density and the deflection phenomena in the shape of flames that caused by the corona wind and Coulomb's force. As the results of an experimental investigation, It was found that the reduction characteristics of DC flashover voltages with flames were affected strongly by the flame deflection and the change of relative air density. It was also found that the thermal ionization phenomena were not important in the range of combustion flame temperature.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.65 no.9
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• pp.1511-1517
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• 2016

The aim of this study is to improve of properties for electrical AC insulation breakdown strength using epoxy/micro-nano alumina composites with adding glycerol diglycidyl ether (GDE:1,3,5g). This paper deals with the effects of GDE addition for epoxy/micro alumina contents (40,50,60wt%)+surface modified nano alumina(1_phr) composites. 14 kinds specimen were prepared with containing epoxy resins, epoxy micro composites and epoxy nano-micro alumina mixture composites. Average particle size of nano and micro alumina used were 30nm and $1{\sim}2{\mu}m$, respectively. The micro alumina used were alpha phase with Heterogeneous and nano alumina were gamma phase particles of spherical shape. The electrical AC insulation breakdown strength was evaluated by sphere to sphere electrode system and raising velocity 1kV/s. The AC breakdown strength decreased insulation properties of multi-composites according to increasing micro alumina and GDE addition contents.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.99-99
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• 2010

Polymer nanocomposite has been attracting much attention as a new insulation material, since homogeneous dispersion of nm-sized inorganic fillers can improve various properties significantly. In this paper, various kinds of epoxy based nanocomposites were made and AC breakdown strength of Nano-TiO2 and micro-silica filler mixture of epoxy based composites were studied by sphere to sphere electrode. Moreover, nano- and micro-filler combinations were adopted as an approach toward practical application of nanocomposite insulation materials. Nano-TiO2 particle size is about 10nm and composites ratio was resin (100) : hardener (82) : accelerator (1.5). AC breakdown test was performed at room temperature (25 [$^{\circ}C$], 80 [$^{\circ}C$] and 100 [$^{\circ}C$] in the vicinity of Tg (90[$^{\circ}C$]). And thermal conductivity were measured by ASTM-D5470.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.227-228
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• 2007

Although many studies have been carried out about binary gas mixtures with $SF_6$, few studies were presented about breakdown characteristics of $SF_6/CF_4$ mixtures. At present study the breakdown characteristics of SFJCF4 mixtures in uniform field was performed. The experiments were carried out under AC and standard lightning impulse (SLI) voltages. The sphere-sphere electrode whose gap distance was 1 mm was used in a test chamber. $SF_6/CF_4$ mixtures contained from 0 to 100% $SF_6$ and the experimental gas pressure ranged from 0.1 to 0.4 MPa. The results show that addition of $SF_6$ to $CF_4$ increase AC and SLI breakdown voltages. Under AC voltages the breakdown voltages of each mixture were linearly increased according to the quantity of $SF_6$. However under SLI voltages the breakdown voltages of each mixture were similar.

• Analytical Science and Technology
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• v.26 no.1
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• pp.42-50
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• 2013

This paper describes the electrocatalytic activity for the oxidation of small biomolecules on the surface of Pt-Ru nanoparticles supported by $TiO_2$-hollow sphere prepared for use in sensor applications or fuel cells. The $TiO_2$-hollow sphere supports were first prepared by sol-gel reaction of titanium tetraisopropoxide with poly(styrene-co-vinylphenylboronic acid), PSB used as a template. Pt-Ru nanoparticles were then deposited by chemical reduction of the $Pt^{4+}$ and $Ru^{3+}$ ions onto $TiO_2$-hollow sphere ($Pt-Ru@TiO_2-H$). The prepared $Pt-Ru@TiO_2-H$ nanocomposites were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), and elemental analysis. The electrocatalytic efficiency of Pt-Ru nanoparticles was evaluated via ethanol, methanol, dopamine, ascorbic acid, formalin, and glucose oxidation. The cyclic voltammograms (CV) obtained during the oxidation studies revealed that the $Pt-Ru@TiO_2-H$ nanocomposites showed high electrocatalytic activity for the oxidation of biomolecules. As a result, the prepared Pt-Ru catalysts doped onto $TiO_2$-H sphere nanocomposites supports can be used for non-enzymatic biosensor or fuel cell anode electrode.

• Applied Chemistry for Engineering
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• v.20 no.4
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• pp.396-401
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• 2009

A micro-spherical activated carbon with meso-pore structure of 52~64% and particle diameter of $2{\sim}10{\mu}m$ was prepared for the improvement electrochemical performance of activated carbon as electrode material for electric double layer capacitor. Resorcinol-formaldehyde resin was used as a carbon source in this preparation. According to electrochemical analysis of EDLC using this activated a carbon with showing effects to reduce charge transfer resistance and to increase rate capability, it was found out that micro-spherical activated carbon could be a good method as well as a material for enhancing the performance of electric double layer capacitor.