• Title/Summary/Keyword: Spectral shift

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OBSERVATION OF SPECTRAL CHARACTERISTICS FOR SOIL CONTAMINANTS

  • Choe Eun-Young;Kim Kyoung-Woong;Lee Sung-Soon;Chi Kwang-Hoon
    • Proceedings of the KSRS Conference
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    • 2005.10a
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    • pp.422-425
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    • 2005
  • Spectral characteristics depending on soil constituents and their proportion in a soil were firstly studied for monitoring of soil contamination using hyperspectral remote sensing. The reflectance spectra of heavy metals in soils were investigated in the VIS-NIR-SWIR regions (400-2500 nm) to observe spectral variation as a function of constituents and concentrations. Commercial kaolinite soils mixed with lead, copper, arsenic, and cadmium were used as synthetic soil samples for spectral measurement. In case of copper, relatively spectrally active regions was observed with some band shift whereas other heavy metals had only simple spectral variations expected to be related to the sorption phase and the amount of metal onto kaolinite. The reflectance spectrum of each metal on kaolinite could be identified in VIS-NIR region.

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Q-factor Estimation of Seismic Trace Including Random Noise using Peak Frequency-Shift Method (무작위 잡음이 포함된 탄성파 트레이스로부터 Peak Frequency-Shift 방법을 이용한 Q-factor 추정)

  • Kwon, Junseok;Chung, Wookeen;Ha, Jiho;Shin, Sungryul
    • Geophysics and Geophysical Exploration
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    • v.21 no.1
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    • pp.54-60
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    • 2018
  • The data acquired from seismic exploration can be used to detect the existence of oil and gas resources through appropriate processing and interpretation. The seismic attributes indicating the existence of resources are extracted from amplitude information, where the Q-factor representing intrinsic attenuation plays an useful role of hydrocarbon indicator. So, the accuracy of Q-factor estimation is very important to investigate the existence of resources. In this study, we calculated the Q-factor and analyzed the error rate through a numerical example. To mimic real data, random noise was added to the synthetic data. With the noise-added data, the Q-factor was estimated and the error rate was analyzed by using the spectral ratio method (SRM) and peak frequency shift method (PFSM). Both methods provided a relatively accurate Q-factor when the signal-to-noise ratio was 90 dB. However, the peak frequency shift method (PFSM) produced better results than the spectral ratio method (SRM) as the level of random noise increased.

Static and dynamic spectral properties of the monophthong vowels in Seoul Korean: Implication on sound change (서울 방언 단모음의 소리 변화와 음향 단서 연구: 단일지점 포먼트와 궤적 양상)

  • Kang, Jieun;Kong, Eun Jong
    • Phonetics and Speech Sciences
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    • v.8 no.4
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    • pp.39-47
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    • 2016
  • While acoustic studies in the past decade documented a raised /o/ by showing their lowered first formants (F1) almost overlapped with those of high back vowel /u/, no consensus has been made in terms of how this /o/-raising affects the vowels as a system in Seoul Korean. The current study aimed to investigate the age- and gender-related differences of the relative distance among the vowels to better understand the influence of this on-going sound change on the vowel system. We measured the static and dynamic spectral characteristics (F1 and F2) of the seven Korean monophthong vowels /e a ʌ o u ɨ i/ in the spontaneous speech of Seoul Corpus, and depicted the patterns of 30 individual speakers (10 speakers in each group of teens, 20s and 40s) as a function of age and gender. The static spectral examination showed low F1 values of /o/ in the spontaneous speech corpus confirming the vowel /o/ raising, and also revealed greater F2 values of /u, ɨ/ suggesting their anterior articulations. The tendencies were stronger when the speakers were younger and female. The spectral trajectories further showed that the F1 and F2 between /o/ and /u/ were differentiated throughout the vowel mid-point although the trajectories gradually merged near the vowel mid point in the older male speakers' productions. The acoustic evidence of contrast among /o, u, ɨ/ supports that the raised /o/ is not indicative of a merger with /u/ but rather implying a chain-like vowel shift in the Seoul Korean.

High-Efficiency and Low-Complexity Spread Spectrum ALOHA for Machine-to-Machine Communications (사물지능 통신을 위한 고효율 저복잡도 대역 확산 알로하 기법)

  • Noh, Hong-jun;Park, Hyung-won;Lim, Jae-sung
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.41 no.12
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    • pp.1700-1706
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    • 2016
  • To improve the number of simultaneous transmissions of machine-to-machine traffic in a spread spectrum ALOHA channel, we propose a new spreading technique called doubly truncated cyclic code shift keying (DTCCSK). By truncating the codeset of cyclic code shift keying, DTCCSK freely adjusts the spreading factor and the symbol length. As a result, DTCCSK exhibits both a high spectral efficiency of M-ary signaling and low implementation complexity of a direct sequence.

Anti-correlated hard and soft X-ray lags in the Z source GX 5-1

  • Sriram, K.;Choi, C.S.;Rao, A.R.
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.149.2-149.2
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    • 2011
  • We performed the cross-correlation analysis on energy-dependent light curves of the Z-type source GX 5-1. We observed X-ray delays of a few hundred seconds between hard (16-30 keV) and soft (2-5 keV) X-ray light curves. During these phenomena, the centroid frequency of horizontal branch oscillation (HBO) was found to shift to lower or higher frequency indicating towards the dynamical movement of a Compton cloud or an inner disk front. Both eastern and western approaches were used to unfold the X-ray continuum and systematic changes were observed in soft and hard X-ray spectral components. Simultaneous energy spectral and power density spectral study shows that the production of HBOs is closely related to the Comptonizing region rather than the accretion disk. We discuss the results in the context of re-condensation of coronal material in the inner accretion disk region.

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InP-Based Polarization-Insensitive Planar Waveguide Concave Grating Demultiplexer with Flattened Spectral Response

  • Kwon, Oh-Kee;Lee, Chul-Wook;Lee, Dong-Hun;Sim, Eun-Deok;Kim, Jong-Hoi;Baek, Yong-Soon
    • ETRI Journal
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    • v.31 no.2
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    • pp.228-230
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    • 2009
  • InP-based planar waveguide 48-channel concave grating demultiplexers with a channel spacing of 0.8 nm (100 GHz) are described and demonstrated. Polarization insensitivity and flattened spectral response are successfully achieved by the introduction of a polarization compensator and a two-focus grating, respectively. The fabricated device shows a polarization-dependent wavelength shift of less than 20 pm and a -3 dB spectral width of about 0.55 nm (68.75 GHz) over all channels.

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Highly Angle-tolerant Spectral Filter Based on an Etalon Resonator Incorporating a High Index Cavity

  • Noh, Tae-Hui;Yoon, Yeo-Taek;Lee, Sang-Shin;Choi, Duk-Yong;Lim, Seung-Chan
    • Journal of the Optical Society of Korea
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    • v.16 no.3
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    • pp.299-304
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    • 2012
  • A high angular tolerance spectral filter was realized incorporating an etalon, which consists of a $TiO_2$ cavity sandwiched between a pair of Ag/Ge mirrors. The effective angle was substantially extended thanks to the cavity's high refractive index. The device was created by embedding a 313-nm thick $TiO_2$ film in 16-nm thick Ag/Ge films through sputtering, with the Ge layer alleviating the roughness and adhesion of the Ag layer. For normal incidence, the observed center wavelength and transmission were ~900 nm and ~60%, respectively; throughout the range of $50^{\circ}$, the relative wavelength shift and transmission variation amounted to only ~0.06 and ~4%, respectively.

Algorithm to Improve Mass Spectral Resolution of Gas Chromatography Mass Spectrometer (가스크로마토그래피 질량분석기의 질량 스펙트럼 해상도 개선 알고리즘)

  • Choi, Hun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.9
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    • pp.1232-1238
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    • 2018
  • This paper proposes methods for improving mass spectral resolution for a gas chromatograph mass spectrometer. The slope signs of the 1st and 2nd fitting functions for the ion signal block of each mass index are obtained, and the unnecessary element signals in the ion signal block are removed. The spectrum can be obtained by obtaining the second-order fitting function of the reconstructed ion signal block using only the effective ion signals. In addition, the resolution of the mass spectrum can be improved by correcting the error caused by the shift of the spectral peak position. To verify the performance of the proposed methods, computer simulations were performed using the actual ion signals obtained from the GC-MS system under development. Simulation results show that the proposed method is valid.

Large Solvent and Noise Peak Suppression by Combined SVD-Harr Wavelet Transform

  • Kim, Dae-Sung;Kim, Dai-Gyoung;Lee, Yong-Woo;Won, Ho-Shik
    • Bulletin of the Korean Chemical Society
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    • v.24 no.7
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    • pp.971-974
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    • 2003
  • By utilizing singular value decomposition (SVD) and shift averaged Harr wavelet transform (WT) with a set of Daubechies wavelet coefficients (1/2, -1/2), a method that can simultaneously eliminate an unwanted large solvent peak and noise peaks from NMR data has been developed. Noise elimination was accomplished by shift-averaging the time domain NMR data after a large solvent peak was suppressed by SVD. The algorithms took advantage of the WT, giving excellent results for the noise elimination in the Gaussian type NMR spectral lines of NMR data pretreated with SVD, providing superb results in the adjustment of phase and magnitude of the spectrum. SVD and shift averaged Haar wavelet methods were quantitatively evaluated in terms of threshold values and signal to noise (S/N) ratio values.

Spectrophotometric Analysis of Behavior to Tyrosine Residue in the Yellow Fluorescent Cocoon of Bombyx mori (황색 형광견 중 Tyrosine잔기 거동의 분광학적 분석)

  • Yeo, Ju-Hong;Lee, In-Jeon
    • Journal of Sericultural and Entomological Science
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    • v.39 no.2
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    • pp.169-173
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    • 1997
  • The behavior of tyrosine(Tyr.) residue of Bombyx mori silk fiber from yellow fluorescent cocoon has been examined for the dependence of pH in aqueous silk solution under the presence of orange II salt. Through the peak separation of angular dependence of spectral pattern of 15N-Tyr. and [1-13C]-Tyr. between the fiber axis and the molecular bond direction, N-H bond in fiber as well as the orientation distribution around the fiber axis were analyzed. Also, and sericin component was obtained from these angular dependence of oriented spectral pattern. The pH dependence of the 13C NMR chemical shift of B. mori silk fibroin was examined in aqueous solution in the presince of orange II are broad at pH$\geq$7.0. However, these become sharper at pH$\geq$8.0 and remain sharp at higher pH. In these higher pH range, a chemical shift change occurs due to the deprotonation of the Tyr. side group of fibroin. At higher pH. such a hydrophobic cluster is destroyed because of the electrostatic interaction according to the deprotonation of the Tyr-OH group.

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