• Bulletin of the Korean Chemical Society
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• 제28권2호
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• pp.263-270
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• 2007

New mono- and bis-Cu(II)-triazacyclononane(tacn) complex that conjugated with 9-aminoacridine were synthesized, and their binding modes and DNA cleavage activity were investigated in this study. When the classic intercalator, 9-aminoacridine, was conjugated to mono- and bis-Cu(II)-tacn complexes, a significant red-shift and hypochromism in absorption spectrum was apparent in the acridine absorption region upon binding to DNA. Furthermore, the magnitude of the negative reduced linear dichroism signal in the substrate absorption region appeared to be larger than that in the DNA absorption region. These spectral observations indicated that the acridine moiety intercalated when the Cu(II)-tacn complex was conjugated. In contrast, from a close analysis of the circular and linear dichroism spectrum, the aminoacridine-free bis-Cu(II)-tacn complex was concluded to bind at the phosphate groups of DNA. The 9-aminoacridine-free-bis-Cu(II)-tacn complex produces the nicked and linear DNA. On the other hand, 9-aminoacridine conjugated mono-and bis-Cu(II)-tacn complexes showed unspecific binding with negligible DNA cleavage.

• 제어로봇시스템학회논문지
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• 제16권2호
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• pp.202-205
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• 2010

When we render 3D sound images using headphones or speakers, the main key of this technology is the Head-related transfer function (HRTF) database. Even though there are various HRTF databases, they have some drawbacks such as detrimental effects caused by imperfect measuring environment and insufficient measurement points. Moreover there is no database with Korean subjects. We are planning to develop the HRTF database for Korean. As a first step to establish the HRTF database aimed at Korean, the new HRTF measurement system with minimized aforementioned drawbacks is designed. In this paper, the newly designed HRTF measurement system is introduced and the overall effects caused by the diffraction of the apparatus, especially the headrest and backrest of the chair, are analyzed. The backrest of the chair does not distort the HRTFs significantly while the headrest makes significant distortion on the HRTFs and it could have significant effects on directional perception. We determined acceptable head rotation angle and head position of the subject for accurate HRTF measurement based on the experiments with B&K HATS. We conclude that the 3 degrees of the head rotation and the 1.5cm front/back/left/right shift of the head do not distort the HRTFs significantly.

• Archives of Pharmacal Research
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• 제19권6호
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• pp.551-553
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• 1996

A genuine dammarane glycoside, named ginsenoside $Rg_{5}$, has been isolated by repeated column chromatography and preparative HPLC from the MeOH extract of Korean red ginseng (Panax ginseng C.A. Meyer). The chemical structure of ginsenoside$ Rg_{5}$ was determined as $3-O-[{\beta}-D-glucopyranosyl (1{\rightarrow}2)-{\beta}-D-glucopyranosyl]$ dammar-20(22), $24-diene-3{\beta},12{\beta}-diol$ by spectral and chemical methods. The stereostructure of a double bond at C-20(22) of ginsenoside $Rg_{5}$ was characterized as (E) from the chemical shift of C-21 in the $^{13}C-NMR $and a NOESY experiment in the $^{1}H-NMR$.

• 한국전자파학회논문지
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• 제23권8호
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• pp.853-860
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• 2012

본고에서는 미국의 전파 정책 및 이용 전략을 분석하고, 이를 토대로 시사점을 제시한다. 먼저 전파기술의 발전과 함께 시장기반의 전파 정책과 주파수 공동사용 정책의 탄생 등 전파 정책의 패러다임 변화를 살펴본다. 또한, 전파자원에 대한 수요가 급증하는 정보화 사회에서 미국의 전파 이용 전략을 분석하고, 이의 시사점을 도출한다. 특히, 주파수 이용 효율을 향상시키기 위하여 dynamic spectrum access 기술의 적극 개발 및 테스트베드 구축을 통하여 이의 실현 가능성을 실험하는 중장기 이용전략을 중점적으로 검토한다. 끝으로 모바일 중심의 wireless broadband 사회를 맞이하여 National Broadband Plan에 따른 주파수 재배치에 대한 검토와 시사점을 다룬다.

• Bulletin of the Korean Chemical Society
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• 제7권4호
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• pp.267-271
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• 1986

The ionomeric blend and the ionic aggregation studies by using a Fourier-transform infrared spectroscopy(FT-IR) are presented. Two ionomers were prepared, one is barium polyacrylate and the other is barium polystyrenesulfonate. The blend of the two ionomers of the barium salts shows intermolecular ionic interaction between the carboxylated ionomer and the sulfonated ionomer. This interaction leads to considerable differences between the spectrum of the blend and the sum of the spectra of the pure ionomers. From our results, it is shown that ionic interactions must play an important role in the compatibility of the two ionomers. In the ionic aggregation study, the bands due to asymmetric stretching mode of carboxylate anion(COO-) in the carboxylated ionomer and the ionomer blend increase in intensity with increasing the divalent barium cations. These results indicate the formation of ion pairs. The doublet due to the asymmetric stretching modes of the carboxylate anion(COO-) is concerned with a sort of local structure found in the ion aggregation. By considering a possible structure for multiplets in the blend, the spectral splitting and the frequency shift are well explained.

• Journal of Positioning, Navigation, and Timing
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• 제9권4호
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• pp.293-304
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• 2020

In this paper, various modulation techniques, including the legacy Global Navigation Satellite System (GNSS) signal modulation techniques, are introduced and the spectral characteristics and correlation characteristics of signals with various modulation techniques are analyzed based on numerical simulation. With the development of various GNSS services, the limited frequency band has become increasingly saturated, and issues of interoperability and compatibility have emerged in the new GNSS design. Since the efficient allocation of frequency resources is closely related to spectrum design, modulation techniques are one of the important signal design parameters of new signal design. Signal modulation techniques are closely related to various figure of merits (FoMs) as well as spectrum characteristic, and in some cases there is a complicated trade-off between FoMs. Thus, the FoMs associated with modulation technology should be analyzed and the best signal candidates should be chosen carefully via the trade-off analysis for FoMs. In this paper, we define the modulation technique based on Phase Shift Keying (PSK), Binary Offset Carrier (BOC) and Continuous Phase Modulation (CPM) for the design of KPS signals, and the FoMs of signals in terms of spectrum and correlation function are evaluated. Signals with various modulation techniques are implemented through a numerical simulation, and the relevant FoMs are analyzed.

• 천문학회보
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• 제46권2호
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• pp.71.2-71.2
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• 2021

Using multi-epoch spectra of active galactic nuclei (AGN) obtained from the Sloan Digital Sky Survey, we identify 16 spectrally variable sources, for which the spectral shapes of broad emission lines significantly vary with a time scale of yrs. Out of them, 3 AGNs are already known as changing-look (CL) AGNs by previous studies. 6 AGNs are newly identified as CL AGNs from our study. A majority of these AGNs are relatively faint and their variability in the continuum is small, which may explain their non-detection in the previous studies. 7 sources are known as binary AGN candidates based on the systematic velocity offset between broad emission lines and narrow emission lines. For those sources and 3 CL AGNs, we find that the peak of broad emission lines had been shifted up to a few thousands km/s for ~10 years, implying that those can be promising candidates for pc-scale binary AGNs or recoiling black holes. We plan to conduct multiwavelength follow-up studies to nail down the physical origin of the velocity shift.

• Bulletin of the Korean Chemical Society
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• 제24권4호
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• pp.446-452
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• 2003

Some new nanohybrid materials have been synthesized by intercalating the oxotitanium(IV) meso-tetrakis(4- sulfonatophenyl) porphyrin$(O=Ti^{(IV)} TSPP)$ into the Zn/Al layered double hydroxides (LDHs), and their structures and photophysical properties have been investigated by various laser spectroscopic techniques. According to the XRD pattern of the synthesized nanohybrid materials, the macrocycle plane of $O=Ti^{(IV)}$ TSPP are grafted perpendicular to the LDH layers. The $O=Ti^{(IV)}$ TSPP-intercalated LDH exhibits band broadening of the absorption spectrum and a blue shift of Q-band as compared to that observed in solution. Resonance Raman spectral measurements demonstrate that the positively charged LDHs give rise to a slight decrease of the electronic density of the porphyrin ring accompanying a small change of the electronic distribution of the $O=Ti^{(IV)}$ TSPP. Consequently the LDH environment affects the energies of the two highest occupied molecular orbitals (HOMOs) of the $O=Ti^{(IV)}$) TSPP, $a_{1u}$ and $a_{2u}$, producing a mixed orbital character. Being consistent with these electronic structural changes of $O=Ti^{(IV)}$ TSPP in LDH, both the fluorescence spectral change and the fsdiffuse reflectance transient measurements imply that the photoexcitation of the $O=Ti^{(IV)}$ TSPP intercalated into LDH undergoes fast relaxation to the O=Ti(IV) $TSPP^+-LDH^- $charge transfer (CT) state within a few picoseconds, followed by a photoinduced electron transfer between the O=Ti(IV) TSPP and LDHs with a rate constant greater than %1×10^{10}S^{-1}$. No evidence is found for back electron transfer. In conclusion, the $O=Ti^{(IV)}$ TSPP intercalated LDH seems to be a possible candidate for an artificial reaction center for an efficient solar energy conversion system.

• Applied Biological Chemistry
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• 제39권1호
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• pp.89-94
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• 1996

한방에서 종기, 치질, 위암 및 염증의 치료목적으로 사용되어온 당느릅나무 (Ulmus davidiana Planch) 근피의 메탄을 추출물로부터 sesquiterpene o-naphthoquinone류 화합물 세가지를 분리 정제하였다. 이들의 구조를 UV-vis, IR, EIMS, HR-EIMS 및 여러 가지 NMR 스펙트럼, 특히 새로운 기법인 pulse field gradient (PFG)-HMQC 및 HMBC 스펙트럼의 분석에 의하여 결정하였다. 그 결과 이들은 2,3-dihydro-3,6,9-trimethylnaphtho(1,8-b,c)pyran-7,8-dione, 3,6,9-trimethylnaphtho(1,8-b,c)pyran-7,8-dione 및 2,3-dihydro-4-hydroxy-3,6,9-trimethylnaphtho(1,8-b,c)pyran-7,8-dione으로 동정 되었으며, 각각 mansonone E, F 및 H로 밝혀졌다. 이 화합물들은 당느릅나무에서는 처음 분리되었으며, 특히 mansonone H는 아프리카 열대식물인 Mansonia altissima Chev 및 Helicters angustifolia에서 분리된 후 자연계에서 처음으로 분리되었다. 문헌에 잘못 보고된 mansonone E 와 F의 C-3a, C-6a 및 C-9b의 세 사급탄소의 chemical shift를 최신 PFG-NMR기법에 의하여 동정하여 교정하였다.

• 한국광학회지
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• 제19권2호
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• pp.127-131
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• 2008

본 논문에서는 굴절률 감지 방식의 수직 결합형 폴리머 마이크로링 공진기 기반 글루코스 바이오 센서를 제안하고 구현하였다. 이 센서에서 상부 클래딩 역할을 하는 글루코스 분석 대상물의 농도 변화는 링 공진기의 공진파장 이동을 측정함으로써 얻어진다. 특히, 센서의 감도를 향상시키기 위해 다음과 같은 방법을 사용하였다. 첫째로, 분석 대상물에 근접한 유효굴절률을 갖는 폴리머 도파로 구조를 공진기 센서에 도입하였다. 둘째로, 분석 물질의 접촉면적을 확대하기 위해 측면 클래딩층이 충분히 식각된 pedestal 링 도파로 구조를 사용하였다. 제안된 공진기 센서는 빔전파 방법을 사용하여 설계하고 분석하였다. 사용된 코어 및 클래딩용 폴리머의 굴절률은 각각 1.430과 1.375였으며, 링 반경은 $400\;{\mu}m$였다. 이 때 얻어진 도파로의 유효굴절률은 ${\sim}1.390$였으며 글루코스 수용액의 굴절률 1.333와 매우 근접하였다. 제작된 소자의 기본적인 전달특성은 FSR(free spectral range) 0.66 nm, 대역폭 ${\sim}0.15\;nm$, Q 값 10,000 이었다. 1550 nm 광파장 대역에서 얻어진 측정 결과를 살펴보면, 센서 감도는 ${\sim}0.28\;pm$/(mg/dL)였으며, 이에 따른 굴절률 변화 감도는 ${\sim}200\;nm/RIU$였다.