• Title/Summary/Keyword: Spectral Derivative

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Phase inversion of seismic data

  • Kim, Won-Sik;Shin, Chang-Soo;Park, Kun-Pil
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.459-463
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    • 2003
  • Waveform inversion requires extracting a reliable low frequency content of seismic data for estimating of the low wave number velocity model. The low frequency content of the seismic data is usually discarded or neglected because of the band-limited response of the source and the receivers. In this study, however small the spectral of the low frequency seismic data is, we assume that it is possible to extract a reliable phase information of the low frequency from the seismic data and use it in waveform inversion. To this end, we exploit the frequency domain finite element modeling and source-receiver reciprocity to calculate the $Frech\`{e}t$ derivative of the phase of the seismic data with respect to the earth model parameter such as velocity, and then apply a damped least squares method to invert the phase of the seismic data. Through numerical example, we will attempt to demonstrate the feasibility of our method in estimating the correct velocity model for prestack depth migration.

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POLYNOMIALLY DEMICOMPACT OPERATORS AND SPECTRAL THEORY FOR OPERATOR MATRICES INVOLVING DEMICOMPACTNESS CLASSES

  • Brahim, Fatma Ben;Jeribi, Aref;Krichen, Bilel
    • Bulletin of the Korean Mathematical Society
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    • v.55 no.5
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    • pp.1351-1370
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    • 2018
  • In the first part of this paper we show that, under some conditions, a polynomially demicompact operator can be demicompact. An example involving the Caputo fractional derivative of order ${\alpha}$ is provided. Furthermore, we give a refinement of the left and the right Weyl essential spectra of a closed linear operator involving the class of demicompact ones. In the second part of this work we provide some sufficient conditions on the inputs of a closable block operator matrix, with domain consisting of vectors which satisfy certain conditions, to ensure the demicompactness of its closure. Moreover, we apply the obtained results to determine the essential spectra of this operator.

Solvatochromic Fluorescence Behavior of 8-Aminoquinoline-Benzothiazole: A Sensitive Probe for Water Composition in Binary Aqueous Solutions

  • Kim, Young-Hee;Youk, Jin-Soo;Kim, So-Hee;Chang, Suk-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.26 no.1
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    • pp.47-50
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    • 2005
  • Solvatochromic fluorescence behavior of 8-aminoquinoline based benzothiazole derivative in varying solvent systems has been investigated. Benzothiazole appended 8-aminoquinoline 3 showed distinctive fluorescence color changes depending upon the solvent polarities and the fluorescence color changes occurred over relatively wide span in visible region from 486 nm to 598 nm which can be detected with naked eye. Compound 3 also exhibited significant spectral shifts in ${\lambda}_{em}$ as a function of water composition in binary aqueous solvent systems. The changes are due to the specific interaction of 3 by hydrogen bonding with water as well as general solvent effect. The observed solvatochromic fluorescence characteristics of 3 could be used as a new probe for the micro-environmental polarity changes as well as a sensitive sensor for the determination of water composition in binary aqueous solutions.

A New Naphthoquinone with Anti-inflammatory Activity from An Egyptian Collection of Echiochilon fruticosum

  • Fathy, Hoda M.;Aboushoer, Mohamed I.;Baraka, Azza;Abdel-Kader, Maged S.;Omar, Abdallah A.
    • Natural Product Sciences
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    • v.15 no.1
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    • pp.22-26
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    • 2009
  • Phytochemical investigation of the roots of Echiochilon fruticosum resulted in the isolation of two naphthoquinone derivatives. Compound 1 was identified as anhydroalkanin while compound 2 was identified as a new derivative 5-hydroxy 8-methoxy 2-(4-methylpent-1,3-dienyl) naphthalene-1,4-dione named as echiochiloquinone. In addition, caffeic acid 3, caffeic acid methyl ester 4 were isolated. The structures were determined by physical, chemical and spectral methods. The anti-inflammatory activity of the root extracts and compound 2 was evaluated utilizing both cotton pellet-induced and carragenin-induced rat paw edema. The ulcerogenic effect was also studied.

Rapid Analysis of Melamine Content in Powdered and Liquid Milk Using Fourier Transform Infrared Spectroscopy

  • Wang, Jun;Jun, Soo-Jin;Li, Qing X.
    • Food Science and Biotechnology
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    • v.18 no.5
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    • pp.1199-1203
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    • 2009
  • Melamine is a chemical intermediate to manufacture amino resins and plastics, which cannot be used as food additive since it can cause kidney stones. A qualitative determination method of melamine residue in powdered and liquid milk was developed using Fourier transform infrared (FTIR) spectroscopic technique. The calibration sets consisted of 21 standard melamine solutions, in which 1% trichloroacetic acid aqueous solution and acetonitrile (3:1, v/v) were used as solvent. The model was validated using 10 standard melamine solutions which were unused to build up the calibration set. Infrared (IR) absorbance peaks specific to almost all chemical groups in melamine molecule were shown in the spectral range between 1,100 and 1,800/cm. Combined partial least squares (PLS)-$2^{nd}$ derivative calibration model coupled with mean centering (MC) mathematical enhancement showed the highest correlation coefficients ($R^2$>0.99). In brief, the FTIR technique can be used for quantitative analysis of melamine in milk samples.

A Study on the Preparation of 2,4-Diamino-7-Phenyl-6-Mehylthiopteridine (2,4-Diamino-7-phenyl-6-methythiopteridine 합성에 관한 연구)

  • Park, Nae-Joung;Kim, Myung-Woong;Lee, Jong-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.4 no.1
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    • pp.61-66
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    • 1987
  • 2,4,6-Triamino-5-nitrosopyrimidine was prepared using malononitrile and guanidine carbonate, and acetylated refluxing in acetic acid with acetic anhydride in order to activate the nitroso group for nucleophilic attack. Nucleophilic attack of phenylpyrimidium bromide on the nitroso group of 2,4,6-triacetamido-5-nitrosopyrimidine gave the intermediate, which lost pyrdidine to give the nitrone derivative. Addition of the methanethiol anion to nitrone gave 2,4-diacetamido-7-phenyl-6-methylthiopteridine which was hydrolyzed to give 2,4-diamino-7-phenyl-6-methylthiopteridine. Spectral data (IR, M.S, NMR) were provided to identify the reaction products during synthesis.

X-RAY PROPERTIES OF THE PULSAR PSR J0205+6449 IN 3C 58

  • Kim, Minjun;An, Hongjun
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.53.2-53.2
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    • 2020
  • We measure X-ray timing and spectral properties of the pulsar PSR J0205+6449. Pulsar's rotation frequency ν = 15.20102357(9) s-1 and its derivative ${\dot{\nu}}=-4.5(1){\times}10^{-11}s^{-2}$ are measured, and the pulsed spectrum of 2-30 keV is model of power law with photon index ��psr = 1.07(16) and F2-30 keV = 7.3(6) × 10-13 erg cm-2 s-1. We use thermal emission models and non-thermal model to fit the pulsar spectrum and measure the surface temperature and luminosity of the pulsar. The surface temperature T∞ = 0.5-0.8 MK and luminosity Lth = 1-5 × 1032 erg s-1 are measure, and this result verifies the previous results known to have low surface temperature and luminosity for the age range of

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Implementation of DS-UWB Impulse Generator with Suppression of Frequency Band for WLAN (WLAN 주파수 대역이 억제된 DS-UWB 임펄스 생성기 구현)

  • Park, Chong-Dae;Kim, Bum-Joo;Kim, Dong-Ho
    • Journal of Advanced Navigation Technology
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    • v.10 no.1
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    • pp.13-19
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    • 2006
  • In this paper, Gaussian impulse generator for DS-UWB was proposed and fabricated so that the frequency band allocated to WLAN, around 5 GHz, was suppressed in accordance with the regulation of radiation spectrum limitation defined by FCC. In order to transform an unipolar rectangular signal to a Gaussian impulse, the proposed impulse generator consists of two stage impulse generation parts; the first stage using dual SRD and the second stage using gain switching of semiconductor laser diode. The result shows a gaussian impulse as narrow as 180 psec in width. In addition, high order derivative Gaussian filter with a structure of 4 stage ring resonators was designed and fabricated so that DS-UWB impulse generator could reduce the frequency spectrum of WLAN by 25 dB compared to the spectral power of th adjacent UWB band.

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New metabolites from the biotransformation of ginsenoside Rb1 by Paecilomyces bainier sp.229 and activities in inducing osteogenic differentiation by Wnt/β-catenin signaling activation

  • Zhou, Wei;Huang, Hai;Zhu, Haiyan;Zhou, Pei;Shi, Xunlong
    • Journal of Ginseng Research
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    • v.42 no.2
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    • pp.199-207
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    • 2018
  • Background: Ginseng is a well-known traditional Chinese medicine that has been widely used in a range of therapeutic and healthcare applications in East Asian countries. Microbial transformation is regarded as an effective and useful technology in modification of nature products for finding new chemical derivatives with potent bioactivities. In this study, three minor derivatives of ginsenoside compound K were isolated and the inducing effects in the Wingless-type MMTV integration site (Wnt) signaling pathway were also investigated. Methods: New compounds were purified from scale-up fermentation of ginsenoside Rb1 by Paecilomyces bainier sp. 229 through repeated silica gel column chromatography and high pressure liquid chromatography. Their structures were determined based on spectral data and X-ray diffraction. The inductive activities of these compounds on the Wnt signaling pathway were conducted on MC3T3-E1 cells by quantitative real-time polymerase chain reaction analysis. Results: The structures of a known 3-keto derivative and two new dehydrogenated metabolites were elucidated. The crystal structure of the 3-keto derivative was reported for the first time and its conformation was compared with that of ginsenoside compound K. The inductive effects of these compounds on osteogenic differentiation by activating the Wnt/b-catenin signaling pathway were explained for the first time. Conclusion: This study may provide a new insight into the metabolic pathway of ginsenoside by microbial transformation. In addition, the results might provide a reasonable explanation for the activity of ginseng in treating osteoporosis and supply good monomer ginsenoside resources for nutraceutical or pharmaceutical development.

Hyperspectral Imaging and Partial Least Square Discriminant Analysis for Geographical Origin Discrimination of White Rice

  • Mo, Changyeun;Lim, Jongguk;Kwon, Sung Won;Lim, Dong Kyu;Kim, Moon S.;Kim, Giyoung;Kang, Jungsook;Kwon, Kyung-Do;Cho, Byoung-Kwan
    • Journal of Biosystems Engineering
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    • v.42 no.4
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    • pp.293-300
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    • 2017
  • Purpose: This study aims to propose a method for fast geographical origin discrimination between domestic and imported rice using a visible/near-infrared (VNIR) hyperspectral imaging technique. Methods: Hyperspectral reflectance images of South Korean and Chinese rice samples were obtained in the range of 400 nm to 1000 nm. Partial least square discriminant analysis (PLS-DA) models were developed and applied to the acquired images to determine the geographical origin of the rice samples. Results: The optimal pixel dimensions and spectral pretreatment conditions for the hyperspectral images were identified to improve the discrimination accuracy. The results revealed that the highest accuracy was achieved when the hyperspectral image's pixel dimension was $3.0mm{\times}3.0mm$. Furthermore, the geographical origin discrimination models achieved a discrimination accuracy of over 99.99% upon application of a first-order derivative, second-order derivative, maximum normalization, or baseline pretreatment. Conclusions: The results demonstrated that the VNIR hyperspectral imaging technique can be used to discriminate geographical origins of rice.