• International Journal of Automotive Technology
• /
• 제3권3호
• /
• pp.95-99
• /
• 2002

The characteristics of soot vaporization induced by a high-energy Pulsed laser were studied in an ethylene-air laminar flame. A system consisting of two pulsed lasers was used for the experiments. The pulse from the first laser was used to vaporize the soot particles, and the delayed pulse from the second laser was used to measure the residual soot volume fraction. Laser-induced soot vaporization was characterized according to the initial particle size distribution. The results indicated that soot particles could not be completely vaporized simply by introducing a high intensity laser pulse. Residual soot volume fractions present after vaporization appeared to be insensitive to the initial soot particle size distribution. Since the soot vaporization effect is more pronounced in the region of high soot concentrations, this laser-induced soot vaporization technique may be a very useful tool for measuring major species in highly sooting flame.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
• /
• pp.129-132
• /
• 2012

Computation is performed to predict number density, volume fraction and size distribution of soot particles in typical operating conditions of a diesel engine. KIVA has been integrated with the CMC routine to consider turbulence/chemistry coupling and gas phase kinetics for heat release and soot precursors. The compositions of soot precursors are estimated by tracking Lagrangian particles to consider spatial inhomogeneity and differential diffusion in KIVA. The soot simulator SWEEP is employed as a postprocessing step to calculate conditional and integral quantities of soot particles.

• 대한기계학회논문집B
• /
• 제28권9호
• /
• pp.1117-1123
• /
• 2004

The characteristics of soot near the soot inception point for an ethene-air flame was carried out in a WSR (well-stirred reactor). The new sampling tool like the temperature controlled filter system was introduced to minimize the condensation during sampling. The new analysis tools applied include the real time size distribution analysis with the Nano-DMA, particle size by transmission electron microscopy, C/H analysis, g filter analysis, and thermogravimetric analysis using both non-oxidative and oxidative pyrolysis. The WSR can generate young soot particles that can be collected and examined to gain insight into inception. For the current conditions, soot does not form for ${\Phi}$=1.9, inception occurs at or before ${\Phi}$=2.0, and inception combined with soot surface growth and/or coagulation occurs for ${\Phi}$=2.1. The filter samples for ${\Phi}$=1.9 are composed of volatile compounds that evolve at relatively low temperatures when heated in the presence or absence of O$_2$. The samples collected from the WSR at ${\Phi}$=2.0 and ${\Phi}$=2.1 are precursor-like in morphology and size. They have higher C/H ratios and lower organic percentages than precursor particles, but they are clearly not fully carbonized soot. The WSR PAH distribution is similar to that in young soot from inverse flames.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2004년도 춘계학술대회
• /
• pp.1298-1303
• /
• 2004

The characteristics of soot near the soot inception point for an ethene-air flame was carried out in a WSR (well-stirred reactor). The new sampling tool like the temperature controlled filter system was introduced to minimize the condensation during sampling. The new analysis tools applied include the real time size distribution analysis with the Nano-DMA, particle size by transmission electron microscopy, C/H analysis, g filter analysis, and thermogravimetric analysis using both non-oxidative and oxidative pyrolysis. The WSR can generate young soot particles that can be collected and examined to gain insight into inception. For the current conditions, soot does not form for ${\Phi}=1.9$, inception occurs at or before ${\Phi}=2.0$, and inception combined with soot surface growth and/or coagulation occurs for ${\Phi=2.1}$. The filter samples for ${\Phi}$=1.9 are composed of volatile compounds that evolve at relatively low temperatures when heated in the presence or absence of $O_2$. The samples collected from the WSR at ${\Phi}=2.0$ and ${\Phi}=2.1$ are precursor-like in morphology and size. They have higher C/H ratios and lower organic percentages than precursor particles, but they are clearly not fully carbonized soot. The WSR PAH distribution is similar to that in young soot from inverse flames.

• 대한기계학회논문집B
• /
• 제26권8호
• /
• pp.1062-1068
• /
• 2002

In our previous study, it was proven that the mean size and the total number concentration of carbon soot particles emitted from a $C_2$H$_4$ normal diffusion flame decreased when a DC corona was discharged to pin-pin electrodes. In this work the effect of AC corona discharge on soot emission was investigated and compared with that of DC corona discharge. For the pin-pin electrodes the size of soot particles and the number concentration decreased by the AC voltage. There were only slight changes in size distribution with frequencies, while the magnitude of applied voltage was constant. When the electric field was applied to plate-plate electrodes, the size and the number concentration also decreased with the applied AC voltages. For applied voltages above 2kV the effect of frequency increase on the soot emission was effective.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
• /
• pp.261-264
• /
• 2015

Soot particles of diesel and bunker-A with different sulfur contents were generated by pyrolysis with varying conditions of fuel flow rate and residence time in the ceramic tube at $1300^{\circ}C$. TEM and particle size analyzer were used for analysing the primary and the secondary particle size distributions. The results showed that the sulfur content in fuel influences soot inception while the fuel concentration and residence time affects the growth of incepted soot particles.

• 대한기계학회논문집B
• /
• 제20권8호
• /
• pp.2626-2636
• /
• 1996

A study of soot deposition and reentrainment was carried out both theoretically and experimentally to understand behavior of soot formed by incomplete combustion in a diesel engine. Theoretically, soot deposition on engine cylinder wall and/or piston head was studied with a stagnation point flow approximation. Soot reentrainment occurred upon exhaust gas blowdown was also studied by assuming a long-normal shear velocity distribution. Experimentally, a LPG$O_2/N_2$ flame impinging on a disk, produced by a concentric tubular burner, was chosen as deposition configuration and a shear flow unit with compressed air was installed for the study of reentrainment. For selected flame configuration, soot deposition measurements were conducted and showed that the dominant deposition mechanism was thermophoresis. Distributions of gas temperature and soot number density were estimated by combining data obtained by a B-type thermocouple with a thermophoretic transport theory. Disk temperature distributions were directly measured using a K-type thermocouple. Soot size and morphology were estimated from a TEM photograph. Ratios of soot deposit to reentrained amount were measured for a wide range of shear flow velocities, which showed that the reentrainment model was reasonable.

• 한국연소학회지
• /
• 제15권4호
• /
• pp.22-28
• /
• 2010

The Direct Quadrature Method of Moments (DQMOM) has been presented for the solution of population balance equation in the wide range of the multi-phase flows. This method has the inherently interesting features which can be easily applied to the multi-inner variable equation. In addition, DQMOM is capable of easily coupling the gas phase with the discrete phases while it requires the relatively low computational cost. Soot inception, subsequent aggregation, surface growth and oxidation are described through a population balance model solved with the DQMOM for soot formation. This approach is also able to represent the evolution of the soot particle size distribution. The turbulence-chemistry interaction is represented by the laminar flamelet model together with the presumed PDF approach and the spherical harmonic P-1 approximation is adopted to account for the radiative heat transfer.

• 대한기계학회논문집B
• /
• 제26권3호
• /
• pp.402-409
• /
• 2002

Experiments were performed with double-concentric diffusion flame(DDF) in order to investigate the characteristics of soot formation and temperature distributions. The flame size and shape of the DDF are similar to those of the well-known normal co-flow diffusion flame(WF), except the formation of a tiny inverse flame near the central tube exit. A laser light extinction technique was used to measure the soot volume fractions. The temperature distributions in the flame were measured by rapid insertion of a R-type thermocouple. Soot concentrations along the flame axis of the DDF were higher than those of the NDF. However, the maximum soot volume fraction of the DDF along the periphery of the flame was lower than that of the NDF. It is mainly due to the effect of nitrogen-dilution from the inner air. Measured temperature distribution explains these trends of soot concentration. The temperature along the flame axis was also higher in DDF than that of the NDF. However, the flame temperatures at the flame front of the two flames were almost same regardless of the inner flame. This phenomenon means that the inverse flame inside the DDF did not affect on the flame structure including the temperature and soot concentration, except the region around the flame axis.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2004년도 추계학술대회
• /
• pp.1158-1161
• /
• 2004

Shell shaped hollow carbon nanoparticles are synthesized in the oxygen-hydrogen diffusion flame with $C_{2}H_{2}$ as precursor when it is irradiated with $CO_{2}$ laser of certain power. Below this power of laser, we couldn't get any other but amorphous soot. This shell shaped hollow carbon nanoparticles shows outer wall of high degree of crystallinity with void space inside of itself. And size distribution of these nanoparticles is measured with TEM image analysis. Also the structural comparison between this carbon nanoparticle and soot is done by Raman and XRD measurement. These results show this carbon nanoparticles are of grapheme structure, which means it has good crystallinity when compared with soot.