• 한국연소학회지
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• 제1권1호
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• pp.75-82
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• 1996

Laser induced incandescence, LII, recently developed technique for measuring soot concentration in flames, can overcome most of limitations of conventional laser extinction measurement. In this study, experiments were performed to investigate the effect of laser intensity, detection wavelength, and also laser beam quality on both LII signal at a particular position and peak-to-centerline LII signal ratio. The results of LII signal with increasing laser intensity shows its near-independence of laser intensity once threshold level of laser intensity has been reached. However, this near-independence depends on laser beam quality and the incident optical setup. The peak-to-centerline LII signal ratio slowly but continuously increases with laser power. This fact is due to the dependence of LII signal on particle mean diameter. LII signal is attenuated during it passes through the flame containing soot particles. The attenuation rate is inversely proportional to detection wavelength. In this study, LII signal at 680 nm band is 10% greater than the signal at 400 nm band.

• 한국안전학회지
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• 제31권3호
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• pp.22-27
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• 2016

The use of electromagnetic wave has been interested in various energy industry because it enhances a flame stability and provides higher safety environments. However it might increase the pollutant emissions such as NOx and soot, and have harmful influence on human and environments. Therefore, it is very important to understand interaction mechanism between flame and electromagnetic wave from environmental point of view. In this study, an experiment was performed with jet diffusion flames induced by electromagnetic wave. Microwave was used as representative electromagnetic wave and a flickering flame was introduced to simulate the more similar combustion condition to industry. The results show that the induced microwave enhances the flame stability and blowout limit. The unstable lifted flickering flames under low fuel/oxidizer velocity is changed to stable attached flames or lift-off flames when microwave applied to the flames, which results from the abundance of radical pool. However, NOx emission was increased monotonically with increasing the microwave power as microwave power increased up to 1.0 kW. The effects might be attributed to the heating of combustion field and thermal NOx mechanism will be prevailed. Soot particle was examined at the post flame region by TEM grid. The morphology of soot particle sampled in the microwave induced flames was similar to the incipient soot that is not agglomerated and contain a lots of liquid phase hydrocarbon such as PAH, which soot particle formed near reaction zone is oxidized on the extended yellow flame region and hence only unburned young particles are emitted on the post flame region.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2002년도 추계학술대회 논문집
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• pp.341-342
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• 2002

미세탄소입자는 원소탄소(elemental carbon)와 유기탄소(organic carbon)로 분류할 수 있다. 원소탄소는 불완전연소 과정에 발생하는 검댕(black soot), 원유의 정제과정에 발생하는 흑연(graphite), 자연상태에서 만들어진 다이아몬드의 3가지 형태로 존재한다. 이들 중 대기환경에 영향을 미치는 요소는 검댕입자로서 입경은 l$\mu\textrm{m}$이하이며, 일정한 형태를 지니고 있지 않다. (중략)

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2004년도 춘계학술대회 논문집
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• pp.237-238
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• 2004

• 대한기계학회논문집B
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• 제29권9호
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• pp.1022-1031
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• 2005

Temporal behavior of the laser induced incandescence (LII) signal is often used for soot particle sizing, which is possible because the cooling behavior of a laser heated particle is dependent on the particle size. In present study, LII signals of soot particles are modeled using two non-linear coupled differential equations deduced from the energy- and mass-balance of the process. The objective of this study is to obtain an appropriate calibration curve for determining primary particle size by comparing the gated signal ratio and double-exponential curve fitting methods. Not only the effects of laser fluence and gas temperature on the cooling behavior but also heat transfer mechanisms of heated soot particle have been investigated. The second-order exponential curve fitting showed better agreements with the LII signals than the gated signal ratio method which was based on the lust-order exponential curve fit. And the temporal decay rate of the LII signal and primary particle size showed nearly linear relationship, which was little dependent on the laser fluence. And it also could be reconfirmed that vaporization was dominant process of heat loss during first loons after laser pulse, then heat conduction played most important role while thermal radiation had little influence all the time.

• 설비공학논문집
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• 제7권4호
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• pp.694-702
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• 1995

When a small absorbing particle is exposed to a strong thermal radiation incidence, it moves towards or away from the radiation source due to the nonuniform internal absorption of the radiation. It is called the photophoretic phenomena and governed by the asymmetry factor. An asymmetry factor for the total wavelength range is calculated to estimate the photophoretic phenomena of a particle in a combustor or in the atmosphere and compared to that for a single wavelength. The samples are soot particulates, water droplets, ice particles, silicon particles, $SiO_2$ particles, aluminium oxide particles, whose spectral complex refractive index are available. Although differences between total and monochromatic asymmertry factors are not much for relatively uniform distribution of the spectral refractive index, they are great in general. Therefore the use of the monochromatic factor will considerably deteriorate the accuracy of the calculation of the photophoresis.

• Korean Chemical Engineering Research
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• 제57권4호
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• pp.584-588
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• 2019

디젤엔진 시스템은 미세먼지 배출의 엄격해진 저감/제어 기준을 충족하기 위해서 산화촉매는 매우 중요한 기술 중에 하나이다. 본 연구에서는 효율적인 soot산화의 촉매로 Ag 나노입자가 loading된 $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$ 섬유상 web 촉매를 제시하였다. 제조된 촉매는 FE-SEM, EDS mapping, XRD, XPS 분석을 통해 특성을 평가하였다. Soot 산화성능측정결과 Ag의 효율적인 촉매특성과 증가된 soot입자와 표면의 접촉면적으로 인하여 50% 산화온도 평가($T_{50}=490^{\circ}C$)에서 자연적인 산화보다 $151^{\circ}C$ 가속화된 것을 확인하였다. 따라서 Ag가 loading된 촉매와 3차원적인 web 구조는 soot 산화에 효율적인 촉매후보군으로 확인하였다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1999년도 제19회 KOSCO SYMPOSIUM 논문집
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• pp.231-240
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• 1999

The temperature distribution in double-concentric diffusion flames have been investigated experimentally by rapid insertion technique. Using a fine thermocouple and rapid insertion mechanism, the temperature has been measured before soot particles attach the thermocouple junction which can affect the temperature signal by changing the radiation heat loss. For double-concentric diffusion flames, the temperature at the axis is higher than that of normal coflow diffusion flames because of the inverse diffusion flame at the center of the flame. However, it is almost same at the periphery on which the inverse flame does not have an effect.

• 한국분무공학회지
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• 제22권4호
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• pp.197-202
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• 2017

The objective of this study is to investigate the effects of low-temperature combustion (LTC) on the correlations of combustion characteristics and reduction of exhaust emissions in a small DI diesel engine with biodiesel fuel. In order to analyze the combustion, exhaust emission characteristics and distribution of nano size particles for biodiesel were investigated. In addition, to evaluate the effect of LTC on the combustion and emission characteristics, 30 and 50% of cooled-EGR rates were investigated. From these results, it revealed that the influence of LTC on the combustion characteristics showed that the ignition delay significantly increased and reduces peak heat release rate of premixed combustion by lowering reaction rate. With 50% EGR and advanced injection timing, soot and $NO_x$ emissions were simultaneously reduced.

• 한국대기환경학회지
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• 제31권3호
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• pp.255-268
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• 2015

Single particle soot photometer (SP2) is an advanced instrument capable of real-time measurement of concentration, coating thickness, and size distribution of individual BC particle using laser-induced incandescence. So far, there have been insufficient studies examining the real-time characteristics of BC in Korea. In this study, we examined temporal variations in BC concentration and mass size distribution of BC in volume equivalence diameter at a background site of Aewol, Jeju in May. Average concentration and mass median diameter (MMD) of BC particles measured during the study period (06~ 16 May 2013) were $0.69{\pm}0.48{\mu}g/m^3$ and $196{\pm}17nm$, respectively. The BC concentration measured in Aewol was very similar to that observed in the spring of 2012 in Baengnyeong island, and showed diurnal profiles similar to those in other background areas. MMD of BC ranged from 172 to 222 nm. It was found that the mass size distribution of BC varied depending on the location (ground-based), season, types of air masses, and altitude (aircraft-based).