• Title/Summary/Keyword: Solute

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Characteristics of Absorption and Heat Transfer for Film Falling along a Vertical Inner Tube (2nd. Report, Characteristics of Heat Transfer) (수직관내(垂直管內)를 흘러내리는 액막식(液膜式) 흡수기(吸收器)의 흡수(吸收) 및 열전달특성(熱傳達特性)(제(第)2보(報) 열전달특성(熱傳達特性)))

  • Ohm, K.C.;Rie, D.H.;Choi, G.G.;Kasiwagi, Takao;Seo, J.Y.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.4
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    • pp.257-264
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    • 1993
  • This is the second report of a three part study on the absorption and heat transfer characteristics of absorber, the correlation of refrigerating capacity and heating capacity. The 2nd report deals with the heat transfer characteristics of a vertical falling film type absorber of inner copper tube. The solute is LiBr-Water solution(60wt%) and the solvent is water vapor. The film Reynoles numbers are varied in the range of 35~130. The states of LiBr solution at the top of absorber are supercooled liquid and superheated liquid. The results are summarized as follows ; Heat transfer results reveal that for the absorption of falling film, the state of LiBr solution appears to be influential in determining the heat transfer. Thus, for the state of supercooled liquid, heat transfer coefficient decreases with increasing the film Reynolds number, but in the condition of superheated liquid, it increases conversely. The mass transfer coefficients that were presented in the 1st.report and heat transfer coefficients of this paper are presented as the dimensionless correlation. The optimum water flowrate which brings about maximum value of heat flux in the film exists, and that increases with increasing the cooling water temperature.

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Solidification Cracking Behavior in Austenitic Stainless Steel Laser Welds (Part 2) -Effects of δ-ferrite Crystallization and Solidification Segregation Behavior on Solidification Cracking Susceptibility- (오스테나이트계 스테인리스강 레이저 용접부의 응고균열 거동 (Part 2) - δ 페라이트 정출 및 응고편석 거동에 따른 응고균열 민감도 변화 -)

  • Chun, Eun-Joon;Lee, Su-Jin;Suh, Jeong;Kang, Namhyun;Saida, Kazuyoshi
    • Journal of Welding and Joining
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    • v.34 no.5
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    • pp.61-69
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    • 2016
  • A numerical simulation of the solid/liquid coexistence temperature range, using solidification segregation model linked with the Kurz-Giovanola-Trivedi model, explained the mechanism of the BTR shrinkage (with an increase in welding speed) in type 310 stainless steel welds by reduction of the solid/liquid coexistence temperature range of the weld metal due to the inhibited solidification segregation of solute elements and promoted dendrite tip supercooling attributed to rapid solidification of laser beam welding. The reason why the BTR enlarged in type 316 series stainless welds could be clarified by the enhanced solidification segregation of impurity elements (S and P), corresponding to the decrement in ${\delta}-ferrite$ crystallization amount at the solidification completion stage in the laser welds. Furthermore, the greater increase in BTR with type 316-B steel was determined to be due to a larger decrease in ${\delta}-ferrite$ amount during welding solidification than with type 316-A steel. This, in turn, greatly increases the segregation of impurities, which is responsible for the greater temperature range of solid/liquid coexistence when using type 316-B steel.

A Study on Logconductivity-Head Cross Covariance in Two-Dimensional Nonstationary Porous Formations (비정체형 2차원 다공성 매질의 대수투수계수-수두 교차공분산에 관한 연구)

  • 성관제
    • Water for future
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    • v.29 no.5
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    • pp.215-222
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    • 1996
  • An expression for the cross covariance of the logconductivity and the head in nonstationary porous formation is obtained. This cross covariance plays a key role in the inverse problem, i.e., in inferring the statistical characteristics of the conductivity field from head data. The nonstationary logconductivity is modeled as superposition of definite linear trend and stationary fluctuation and the hydraulic head in saturated aquifers is found through stochastic analysis of a steady, two-dimensional flow. The cross covariance with a Gaussian correlation function is investigated for two particular cases where the trend is either parallel or normal to the head gradient. The results show that cross covariances are stationary except along separation distances parallel to the mean flow direction for the case where the trend is parallel to head gradient. Also, unlike the stationary model, the cross covariance along distances normal to flow direction is non-zero. From these observations we conclude that when a trend in the conductivity field is suspected, this information must be incorporated in the analysis of groundwater flow and solute transjport.

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Prediction of Solute Transport in Natural River Using RAM4 (RAM4모형을 이용한 자연하천에서의 확산거동 예측)

  • Jung, Sung-Tae;Lyu, Si-Wan;Kim, Young-Do;Seo, Il-Won
    • Proceedings of the Korea Water Resources Association Conference
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    • 2008.05a
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    • pp.2046-2050
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    • 2008
  • 현재까지 우리나라에서 주로 사용되고 있는 2차원 흐름 해석 모형은 미연방 도로국(U.S. Federal Highway Administration)과 연계하여 Brigham Young University에서 개발된 SMS(Surface-Water Modeling System)모형이다. SMS모형 중 이송 확산 모형으로는 RMA-4가 포함되나 이 모형은 최신 수치기법을 반영하지 못하는 등의 문제점들로 인해 실제 물리적 현상을 모의에 있어서 한계를 가지고 있다. 따라서 물리적 현상에 대한 적절한 모의를 위해 여러 개선과정을 거쳐 RAM4가 개발되었다. 본 연구를 위해 점적분 유사량 측정기(P-61)와 대하천 유속계를 사용하여 대상구간의 SS자료 및 유속의 2차원적 분포를 취득하였고, SMS의 Pre-processing 기능을 이용하여 유한요소망을 구성하였다. 구성된 유한요소망과 흐름모형인 RMA-2를 사용하여 대상구간의 유속장을 모의하였다. 이때 모의된 유속장과 현장에서 취득한 유속분포를 비교하여 RMA-2를 검증하였고, SS자료와 RAM4로 모의된 농도장을 비교하여 RAM4를 검증하였다. 검증된 두 모형을 바탕으로 대상 구간에서 다량의 점오염원이 투입되는 가상의 시나리오를 선정 및 적용하여 오염물 이송 및 확산 거동에 대해 살펴보았다. 본 연구의 대상 하천은 형산강으로써, 유역 내에 경주시와 포항시가 위치하고 이 두 도시를 잇는 산업도로가 형산강 본류 위를 지나고, 또한 두 도시를 관류하고 있어 다른 국가하천과 마찬가지로 지속적이고 안정적인 수질관리가 필요한 하천이다, 모의구간은 형산강 본류 중 No. 68(안강 수위관측소 상류 약 350 m)에서 No. 48(부조 수위관측소 하류 약 200 m)까지로서, 약 4.3 km 구간을 모의 하였다. 모의구간 시점에서 약 0.35 km 지점에 산업도로의 일부분인 강동대교, 0.98 km 지점에 왕신천 유입, 1.35 km 지점에 수중보, 1.8 km 지점에 국당1교, 3.2 km 지점에 국당2교가 위치하며 구간 내에는 만곡 및 사행, 특히 수중보 전 후로 사주가 발달해있어 2차원 흐름 및 이송확산 모의에 적합하다고 판단되었다.

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Breakthrough Curves and Miscible Displacement of Cadmium Through Double-Layered Reclaimed Soils Amended with Macroporous Granule

  • Kim, Hye-Jin;Ryu, Jin-Hee;Kim, Si-Ju;Park, Mi-Suk;Chung, Doug-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.1
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    • pp.15-21
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    • 2011
  • Transport of heavy metals such as Cd is affected by several rate-limiting processes including adsorption and desorption by exchange reactions in soils. In this study, column transport and batch kinetic experiments were performed to assess Cd mobility in a double-layered soil with a reclaimed saline and sodic soil (SSS) as top soil and macroporous granule (MPG) as a bottom layer. For individual soil layer having different physical and chemical properties, Cd was considered to be nonlinear reactivity with the soil matrix in layered soils. The dispersive equation for reactive solutes was solved with three types of boundary conditions for the interface between soil layers. The adsorption of Cd with respect to the saline-sodic sandy loam and the MPG indicated that the nature of the sites or the mechanisms involved in the sorption process of Cd was different and the amounts of Cd for both of samples increases with increasing amounts of equilibrium concentration whereas the amount of Cd adsorbed in saline-sodic sandy loam soil was higher than that in MPG. The results of breakthrough curve indicating relative Cd retardation accompanied by layer material and sequence during leaching showed that the number of pore volumes to reach the maximum relative concentration of 1 increased in the order of MPG, SSS, and double layer of SSS-MPG. Breakthrough curves (BTCs) from column experiments were well predicted with our double-layered model where independently derived solute physical and retention parameters were implemented.

Effects of Natural Convection on Macrosegregation of Directionally Solidified Off-Eutectic Composites (공정복합재료의 일방향응고시 용질편석에 미치는 자연대류의 영향)

  • Kim, Gi-Bae;Yun, Ui-Park
    • Korean Journal of Materials Research
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    • v.5 no.1
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    • pp.123-131
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    • 1995
  • Natural convection in bridgman growth and it's effect on macrosegregation in unidirectionally solidified off-eutectic alloys were examined in this study. AlCu off-eutectic alloys(27.5wt% ~35. 6wt% ) were solidified upward or downward for producing a different natural convection and then Cu concentrations of off-eutectic composites were measured as a function of solidified fraction. Solutal and temperature distributions ahead of the solid/liquid interface were measured on quenched specimen. When hypo-utectic AlCu alloys are directionally solidified with downward growth, considerable macrosegregation occurs due to flow induced by thermal and solutal convection in melt. Soultal convection affects the macrosegregation of hyper-eutectic AlCu alloys more severely than thermal convection. Solute composition at solid/liquid interface of offkutectic composites was eutectic and also temperature was near eutectic point without large undercooling.

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ORTHROGNATHIC SURGERY IN SEVERE CHRONIC RENAL FAILURE PATIENT (중증의 만성신부전 환자에서의 악교정 수술)

  • Shin, Sang-Hun;Kim, Ki-Hyun;Jeung, Suck-Young;Park, Sung-Hwan;Kim, Cheol-Hun
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.26 no.6
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    • pp.652-657
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    • 2000
  • The kidneys play a vital role in the maintenance of normal body fluid volumes and in the composition of the extracellular fluid compartments. There are normally more than 2 million functioning glomeruli that regulate total body water and solute concentrations. As renal failure progresses, there is a decrease in the number of functioning nephrons. Chronic renal failure(CRF) is the consequence of a multitude of diseases that cause permanent destruction of the nephron. Azotemia is an elevation in blood urea nitrogen(BUN) and serum creatinine levels subsequent to a decreased glomerular filtration rate(GFR), which results in uremia. This loss of renal function can cause functional and metabolic abnomalities of body. For this problem, oral & maxillofacial surgeons have demanded to routinely treat patients with CRF. However, there has not been a reported case of orthognathic surgery by bilateral sagittal split ramus osteotomy(BSSRO) in patients with CRF, which can cause multiple complications in healthy patients. We report developmental mechanism of complication associated with CRF and preop. and postop. care of orthognathic surgery by BSSRO in Cl III patient with severe chronic renal failure.

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Structural Studies on Conjugated Oximes (II). Nuclear Magnetic Resonance spectral Analysis on the Configuration and Hydrogen Bond of cis-2-Butenedialdioxime in Solutions (Conjugated Oxime의 立體構造에 關한 硏究 (第2報). NMR에 依한 cis-2-Butenedialdioxime의 Configuration 및 水素結合에 對한 考察)

  • Hong Young-Suek;Lee Hak-Ki
    • Journal of the Korean Chemical Society
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    • v.19 no.4
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    • pp.233-239
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    • 1975
  • The configuration of two oxime groups in cis-2-butenedialdioxime, unsymmetrical compound conjugated by three double bonds, is determined by a NMR study on the effects of the solvent, temperature and concentration; it is certain that, in solutions of usual conditions, the configuration exists as only "syn-syn". And the relative strengths of the hydrogen bond between these oxime groups and several solvents are compared and somc effects of the temperature and concentration are also considered. The several models of hydrogen bond between oxime and solvents are proposed; especially it is to be noted here that the hydrogen bond in pyridine solvent is not resulted from the interaction between a lone electron pair on nitrogen atom of pyridine and the hydroxyl proton of oxime, but the result of $\pi$-complex formed between the $\pi$-orbital of pyridine and the hydroxyl proton of the solute.

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A Study on the Internet Domain's Name Dispute Sdution Methods at EC times (EC시대(時代) 인터넷 도메인명(名) 분쟁(紛爭) 해결(解決) 방안(方案)에 관한 연구(硏究))

  • Park, Jong Sam;Park, Young Tae
    • Journal of Arbitration Studies
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    • v.9 no.1
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    • pp.291-322
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    • 1999
  • The world of today faces a radical change, a new revolution, by the spread of the Internet. It is used not only for advertising but also for the exclusive rights in the field of information and communication, in add to the way of developing everyday our lives with world news, home-shopping, on-line education and so on. Actually, since the Internet Domain's Name(IDN) is unique over the world, the individual and the companies which provide information through the Internet have a keen competition to make a good IDN to memorize and organize all available information provided them. As a result, there are an increasing number of the cases where one company files suit against another for the validity of it's IDN so the policy to arbitrate and solute the cases is required. This paper is going to introduce the structure and the system of management for IDN. It will also discuss the efficient management of IDN, various case analysis of the dispute restraint and solutions, and the movement of improving the management procedure of IDN in WIPO. So we suggest to examine common disputes among IDN uses and solution methods for future problem at EC times. Therefore we have to establish the dispute solution system. Here are the two methods : one is that to establish a dispute solution organization. This organization which can conduct the new dispute solution procedure differs from the existing legislation system. The other is that to establish a dispute solution procedure i.e. the various dispute solution procedure for efficient dispute solution : council, inspection, mediation and arbitration. This procedure is conducted on-line due to features of the IDN disputes, also along with the current legislation system and the International dispute solution procedure. Because there is possibility the IDN disputes usually are connected with other countries. As there is no specific disputes solution procedure so far, we have to wait while development occurs that also striving to be coherent with and between the domestic and International solution procedure by helping to establish the International dispute solution procedure.

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Preparation of Cucurbituril Anchored Silica Gel by Cross Polymerization and Its Chromatographic Applications

  • Cheong, Won-Jo;Go, Joung-Ho;Baik, Yoon-Suk;Kim, Sung-Soon;Nagarajan, Erumaipatty R;Selvapalam, Narayanan;Ko, Young-Ho;Kim, Ki-Moon
    • Bulletin of the Korean Chemical Society
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    • v.29 no.10
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    • pp.1941-1945
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    • 2008
  • A new chromatographic stationary phase has been prepared by cross polymerization between allylsilica and perallyloxycucurbit[6]uril and characterized by elemental analysis and FT-IR spectroscopy. The double endcapping has been proven to improve the separation efficiency of the cucurbituril-based stationary phase material. The first end-capping was carried out when allylsilica was made. The second end-capping was done as the final step of the whole process, and the use of a mixture of hexamethyldisilazane (HMDS) and trimethylchlorosilane (TMCS) as an end-capping reagent was found better than the use of only HMDS or TMCS. Our stationary phase has shown generally good results in separation of nonpolar and polar analytes. This phase showed even better separation performance than the commercial C18 phase for the case where hostguest chemistry was properly incorporated in solute retention.