• 제목/요약/키워드: Soluble salt

검색결과 410건 처리시간 0.022초

알루미늄 재활용 소재를 이용한 내화재용 Mayenite 합성 연구 (A Study on Synthesis of Mayenite by Using Recycled Aluminium Resource for Application in Insulating Material)

  • 임병용;강유빈;주소영;김대근
    • 자원리싸이클링
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    • 제29권6호
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    • pp.65-72
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    • 2020
  • 블랙 드로스는 알루미늄을 재활용하는 과정 중에 플럭스 사용에 의해 발생되는 짙은 회색의 드로스로서, NaCl, KCl, Al2O3, MgO 등이 포함되어 있다. 블랙 드로스는 용해(dissolution) 공정을 통하여 용해성 물질(NaCl, KCl)과 불용해성 물질(Al2O4, MgO)로 분리가 가능하다. 이중 용해성 물질의 경우 Salt flux로 재활용이 가능하며, Al2O3, MgO의 경우 합성 공정을 통하여 다양한 세라믹 소재로 업사이클링이 가능하다. 본 연구에서는 블랙 드로스로부터 회수한 Al2O3, MgO를 이용하여 Mayenite를 합성 하였으며, 배합 비율 및 반응 온도 조건에 따른 합성을 실시하였다. 블랙 드로스(spinel)와 CaCO3를 이용하여 Mayenite를 합성할 시 700 ℃에서 Mg0.4Al2.4O4, CaO로 변하며, 800 ℃ 이후부터 Ca12Al14O33(Mayenite)으로 변하는 것을 확인하였다. 배합 조건에는 CaCO3 함량이 증가함에 따라 Mayenite XRD 피크가 증가하며, Mg0.4Al2.4O4 XRD 피크는 감소하는 것을 확인하였다. 합성된 분말의 BET 분석 결과 Mayenite가 생성되는 과정에서 미세한 입자가 성장되고 응집됨에 따라 비표면적은 감소하는 거동을 보였다.

Lactobacillus acidophilus의 복합담즙산염 분해 (Deconjugation of Bile Salts by Lactobacillus acidophilus)

  • 임광세;백영진;임정현;김현욱;안영태
    • Journal of Dairy Science and Biotechnology
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    • 제22권1호
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    • pp.13-25
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    • 2004
  • 담즙산은 cholesterol의 대사산물로 체내에서 cholesterol을 제거하는 주경로로서, 체내 cholesterol 대사를 조절하는 중요한 수단이다. 최근에 복합담즙산 분해활력이 높은 L. acidophilus에 의한 혈중 cholesterol 저하효과에 관한 많은 연구들이 보고되고 있으며, 이것은 복합담즙산의 분해로 생성되는 유리 담즙산의 분 배출 증가와 장내 cholesterol 흡수에 필요한 복합 micelle 형성의 방해에 의한 것으로 알려져 있다. 즉, 유리 담즙산은 장내에서 복합담즙산보다 용해성이 낮아서 흡수되지 않고 분으로 배출되기 쉬워, 간에서는 분으로 배출된 양만큼의 부족한 복합담즙산을 보충하기 위해 cholesterol을 이용하여 새로운 복합담즙산을 생성하기 때문에 결국은 체내의 혈중 cholesterol 수준을 감소시키는 것으로 생각된다. 또한 담즙으로 분비되는 복합담즙산은 소장내에서 cholesterol의 용해 흡수에 도움을 주지만 유리 담즙산은 cholesterol 용해성이 낮기 때문에, 장내 cholesterol 흡수에 영향을 미치는 것으로 생각된다.

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Growth and solute pattern of Suaeda maritima and Suaeda asparagoides in an abandoned salt field

  • Choi, Sung-Chul;Lim, Sung-Hwan;Kim, Sang-Hun;Choi, Deok-Gyun;Kim, Jong-Guk;Choo, Yeon-Sik
    • Journal of Ecology and Environment
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    • 제35권4호
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    • pp.351-358
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    • 2012
  • To investigate the environmental adaptation and ecophysiological characteristics of Suaeda maritima and S. asparagoides under saline conditions, plant growth and density were analyzed according to environmental changes of habitats. The total ion content of soil decreased with time, which was caused by the predominance of exchangeable $Na^+$ and $Cl^-$ in the upper layers. The population of S. maritima was more densely distributed in the region with higher ion contents of $Cl^-$, $Mg^{2+}$, $K^+$ and $Na^+$ than the population of S. asparagoides. Both species were showed a decreased population density according to increases in plant growth. Under the conditions of a salt field, S. maritima and S. asparagoides contained high inorganic ions to maintain low water potential, but low water soluble carbohydrate contents. In the case of free amino acid, S. maritima showed an especially high proline content, and contained rather large amounts of free amino acids, whereas S. asparagoides did not. Both species showed high inorganic ion contents in the leaves, which might be a mechanism of avoiding the ionic toxicity by diluting the accumulated ionic concentration with a high ratio of water content to dry weight. This result suggests that S. maritima seems to adapt to saline conditions by accumulating proline in addition to inorganic ions. S. asparagoides seems to adapt by osmoregulation processes, using inorganic ions rather than free amino acids.

염스트레스가 담배식물의 Protein, ATPase 및 Peroxidase 활성에 미치는 영향 (Effects of Salt Stress on Protein Content, ATPase and Peroxidase Activities in Tobacco.)

  • 이상각;강병화;이학수;배길관
    • 한국환경농학회지
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    • 제17권4호
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    • pp.296-300
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    • 1998
  • 본 실험은 담배에서 염스트레스에 따른 생리적 반응의 연구결과(제1보)를 기초로, NaCl를 농도별로 처리하여 생체내에서 일어나는 생화학적인 변화의 구명을 통해 염해기작의 기초자료로 얻고자 수행한 결과를 요약하면 다음과 같다. 총단백질과 가용성단백질은 염농도가 높아질수록 감소하였으며 처리간에는 120mM까지는 완만히 감소하였고, 150mM에서는 급격한 감소를 나타냈다. 전기영동 패턴은 염농도의 증가에 따라 새로운 polypeptide band의 생성과 소멸은 없었으며 약 74Kd의 polypeptide band에서 30mM과 60mM까지는 뚜렷한 양이 증가하였고 90mM부터는 감소하였다. 엽록소함량은 염농도의 증가에 따라 감소하였으며 특히 염해에 의한 반응은 엽록소b보다는 엽록소a가 민감하였다. ATPase활성과 peroxidase의 활성은 염농도가 높아질수록 120mM까지는 일정하게 증가하였으나 150mM에서 급격히 증가하여 담배의 염해의 생화학적인 제한범위는 120mM로 나타났다.

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간석지 제람에 관한 연구 (Study on the Desalinization in Tiolal Land)

  • 이중기
    • 한국농공학회지
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    • 제20권2호
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    • pp.4695-4707
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    • 1978
  • The objeative of this study is to study how to rapidly convert tidal land into cultivable land. The study of a rapid, reasonable desalinization method is conducted at Namyang tidal land which represents soil texture of tidal lands along the south west costa larea of Korea. Therefore, Researches were made at many Pilots in order to find a way of high efficiency of leaching with simpler facilities and cheaper costs. The results of study are briefly summarized as follaws: 1. Subdrainage efficieny is 35%. This is a Poorly drained area, and needs longer leaching desalinization period. 2. The efficieny of desalinization in P.V.C 16 meters plot is the same as that of mole drainage 2 meters plot. P.V.C 4 meters plot has desalinization effect as much as two times compared to P.V.C 16 meters plot. 3. Because the soil texture is silty-clay, desalinization in non-treated plot of sub-drainage and surface drainage desalinization take three times longer period in comparision with P.V.C 4 meters plot. 4. As to the desalinization rate of soluble salt in the soil, the efficieny of desalinization of the topsoil in P.V.C plots was 50% higher than that of mole drainage plot and about 170% higher than that of non-treated plot. In the deep soil salt accumulation at topsoil was observed in non-treated and mole drainage plots, but efficiency in P.V.C polt is about 40 times as high as that of mole drainage and non-treated plot. 5. As to the results of use gypsum and lime as sub-drainage soil improver, gypsum was 60% more efficieny than lime in the continuously inundated plot and 44% in the intermittently inundated plot. The efficieny of gypsum and lime in the intermittently flooded plot is 35% and 42% higher than that of continuously flooded plot reapeaticee1y.

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고령 양전동암각화의 암석학적 특징과 훼손양상 분석 (Petrological Characteristics and Deterioration Aspect of the Goryeong Yangjeondong Petroglyph)

  • 최기주;이상헌
    • 보존과학회지
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    • 제25권2호
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    • pp.131-145
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    • 2009
  • 고령 양전동암각화는 녹색 사암으로 구성된 너비 6m 높이 3m의 암반의 절리면에 겹동그라미(3점)와 방패무늬(30점)의 그림들이 있다. 구성암석의 주 구성광물은 석영, 장석 및 녹니석이며, 교질물인 점토광물 중 녹니석이 대부분이나 일라이트와 소량의 방해석도 산출된다. 이들 점토광물들은 구성광물을 피복 및 성분을 교대하거나 공극을 충진하는 양상으로 산출된다. 수용성 염과 암석의 풍화현상과의 관계를 포함한 훼손양상과 암각화가 그려진 암반의 사면안정성을 조사하였다. 훼손양상은 주로 표면박리, 입자박락, 균열 및 파손 등이다. 그리고 절리와 균열이 발달한 암반은 낙석의 가능성이 있는 것으로 해석된다. 보존을 위해서는 균열 및 파손 부위에 대한 접착처리와 약해진 표면층에 강화처리가 필요하다.

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용해 현상에 대한 초등학교 과학 교과서의 내용 분석 및 지도 실태 (A Textbook Analysis and Teaching Practices on Dissolution in Elementary School)

  • 강대훈;백성혜
    • 한국초등과학교육학회지:초등과학교육
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    • 제22권2호
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    • pp.138-148
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    • 2003
  • This study was to analyze how elementary school science textbooks explain dissolution and to examine the patterns of elementary school teachers' conceptions on dissolution and the teaching practices on dissolution of elementary school teachers. According to the result of the textbook analysis, the textbooks based on the 7th curriculum didn't explain dissolution very differently from those based on the 6th curriculum. The contents dealing with dissolution in the textbooks of 7th curriculum became difficult gradually as the year went up, but the connected organization of the contents made students learn it easily. For example, in order to learn dissolution introduced first in the 3rd year 2nd semester textbook, students would tell soluble substance in water from insoluble substance in water as they put powdered substance in water. In the 5th year 1st semester textbook students were supposed to acquire the knowledge related to dissolution through the designed activities such as comparing solubility produced by different solvents and defining a solvent, a solute, dissolution, and a solution. In addition, teachers' guide for 5th year 1st semester textbook elucidated the principle of dissolution using attraction concept that was scientific. The result of the survey on teachers showed that 90% of elementary school teachers understood the dissolution of salt in water just as millet particles' filling the space between bean particles and they responded that they demonstrated millet particles' filling the space between been particles when they taught the dissolution of salt in water. When it comes to teachers who had the right idea on dissolution as the attraction conception, understanding was one thing and teaching was another, because they often instructed dissolution as the space conception in the real teaching.

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아미노산 곁사슬 치환 폴리아스팔트산계 생분해성 고흡수성 젤의 제조와 물성 (Preparation and Properties of Biodegradable Superabsorbent Gels Based on Poly(aspartic acid)s with Amino Acid Pendants)

  • 손창모;전영실;김지흥
    • 폴리머
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    • 제35권6호
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    • pp.558-564
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    • 2011
  • 생체적합하고 생분해성을 갖는 폴리아미노산의 하나인 폴리아스팔트산은 팹타이드 결합으로 이루어진 수용성 합성고분자로서 의료용 소재 및 다양한 응용분야의 연구가 흥미있게 진행되어 왔다. 본 연구에서는 아미노산인 GABA(${\gamma}$-aminobutylic acid)와 ${\beta}$-alanine을 곁사슬에 도입한 폴리아스팔트산 유도체 고분자를 제조하고, 이들을 서로 다른 함량의 ethylene glycol diglycidyl ether(EGDE)를 사용하여 가교시켜 고흡수성 하이드로젤을 제조하였다. 각 하이드로젤에 대해 증류수와 PBS 용액에서 기본적인 팽윤물성, 젤의 가수분해 거동과 모폴로지를 조사하였다. 제조한 하이드로젤은 수용액에서 pH와 염(salt) 농도에 의존하는 민감성 팽윤거동을 보였으며, 또한 비교적 빠른 가수분해 거동을 나타내었다.

방사선 가교 기술을 이용한 유효성분 방출력이 우수한 하이드로겔 제조 및 특성 분석 (Characterization and Preparation of the Hydrogel has Excellent Release Effect of the Active Ingredients Using a Radiation Cross-linking Technology)

  • 황승현;안성준;박종석;정성린;권희정;이동윤;임윤묵
    • 방사선산업학회지
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    • 제9권4호
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    • pp.199-207
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    • 2015
  • Typical radiation cross-linked hydrogels has the characteristic that high water content, but low emission efficiency of active ingredients. Therefore, the hydrogel was prepared by the addition to collagen, which is closely related to the formation of skin wrinkles in biocompatibility and highly water-soluble carboxymethyl cellulose sodium salt (CMC) in order to preparation of hydrogels has excellent emission efficiency of active ingredients. Hydrogels were prepared by dissolving CMC and collagen each of 0.5%, 10% concentration in deionized water. Then, prepared hydrogels are performed by gamma-radiation at 1, 3, 5 kGy irradiation dose. The results showed that the gel fraction of after irradiated 3 kGy hydrogel was higher than before irradiated gelation as long as the 55.3%. The swelling rate of irradiated 3 kGy hydrogel was lower than the non-irradiated sample. The compressive strength of 3 kGy irradiated hydrogel was the highest. The visco-elastic did not show any significant differences, even after irradiation. The CMC hydrogel in this study suggested a potential use as a material for the mask pack for improved emission efficiency of the active ingredient and anti-wrinkles.

About Chromium (VI) Extraction from Fertilizers and Soils

  • Sager Manfred
    • 자원환경지질
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    • 제38권6호
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    • pp.657-662
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    • 2005
  • Extractions fro fertilizer and soil samples were performed to yield the operationally defined fractions 'soluble' chromate (extractable with $NH_4NO_3$), 'exchangeable' chromate (extractable with phosphate buffer pH 7.2), and these results were compared with the data obtained by extractions with ammonium sulfate, borate buffer pH 7.2, saturated borax pH 9.6, and polyphosphate (Graham's salt). In order to maintain the pH of extractant solution about constant, the concentration of extractant buffer had to be raised to at least 0.5 M. The results strongly depended on the kind of extractant, and the solid: liquid ratio. For most of the samples investigated, the extraction efficiency increased in the order borate-sulfate-nitrate-phosphate. Whereas the recovery of $K_2CrO_4\;and\;CaCrO_4$ added to the samples of basic slags prior to the extraction was about complete, the recovery of added $PbCrO_4$ was highly variable. In soil extracts, the color reaction was interfered from co-extracted humics, which react with the chromate in weak acid solution during the time period necessary for color reaction (1 hour). However, this problem can be overcome by standard addition and subtraction of the color of the extractant solution. In soil extract of about pH < 7, organic material reduced chromate during the extraction period also, and standard addition of soluble chromate is recommended to prove recovery and the stability of chromate in the samples. In admixtures of soils and basic slags, results for hexavalent chromium were lower than from the mere basic slags. This effect was more pronounced in phosphate than in nitrate extracts. As a proficiency test, samples low in organic carbon from contaminated sites in Hungary were tested. The results from $NH_4NO_3$ extracts satisfactorily matched the results of the Hungarian labs obtained from $CalCl_2$ extractants.