• Title/Summary/Keyword: Solid state reduction

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Synthesis and Electrochemical Characteristics of Carbon added Li3V2(PO4)3 (탄소첨가한 Li3V2(PO4)3의 합성 및 전기화학적 특성)

  • Jo, Yeong-Im;Na, Byung-Ki
    • Journal of the Korean Electrochemical Society
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    • v.15 no.2
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    • pp.101-108
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    • 2012
  • The purpose of this study was to improve the conductivity of $Li_3V_2(PO_4){_3}$ by adding carbon source so that the discharge rate and cyclic properties were improved. Glucose and CNT were added to $Li_3V_2(PO_4){_3}$ and the structure and electrochemical properties were studied. $Li_3V_2(PO_4){_3}$, $Li_3V_2(PO_4){_3}$/C and $Li_3V_2(PO_4){_3}$/CNT were synthesised by solid state reaction using hydrogen reduction method at 600, 700, 800, $900^{\circ}C$. The cathode materials were assembled to coin cell type 2032 with Lithium metal as a counter electrode. The coin cell was galvanostatically evaluated in the voltage range of 3.0~4.8 V.

Thermal Behavior of NiFe2O4 for Hydrogen Generation (NiFe2O4를 이용한 열화학 사이클 H2 제조)

  • Han, S.B.;Kang, T.B.;Joo, O.S.;Jung, K.D.
    • Transactions of the Korean hydrogen and new energy society
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    • v.14 no.4
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    • pp.298-304
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    • 2003
  • The thermal behavior of $NiFe_2O_4$ prepared by a solid-state reaction was investigated for $H_2$ generation by the thermochemical cycle. The reduction of $NiFe_2O_4$ started from $800^{\circ}C$, and the weight loss was 0.2-0.3 wt% up to $1000^{\circ}C$. In the $H_2O$ decomposition reaction, $H_2$ was generated by oxidation of reduced $NiFe_2O_4$. The crystal structure of $NiFe_2O_4$ maintained during the redox reaction of 5 cycles. From this observation, the lattice oxygen in $NiFe_2O_4$ is released without the structural change during the thermal reduction and oxygen deficient $NiFe_2O_4$ can be restored to the spinel structure of $NiFe_2O_4$.

Synthesis and Luminescence of Sr2Si5N8:Eu2+ Red Phosphor for High Color-Rendering White LED (고연색 LED용 적색 Sr2Si5N8:Eu2+ 형광체의 합성 및 발광특성 연구)

  • Lee, Sung Hoon;Kim, Jong Su;Kang, Tae Wook;Ryu, Jong Ho;Lee, Sang Nam
    • Journal of the Semiconductor & Display Technology
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    • v.16 no.4
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    • pp.11-15
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    • 2017
  • Red phosphors, $Sr_2Si_5N_8:Eu^{2+}$, were synthesized as a single-phase crystal structure by optimizing carbon and $Eu^{2+}$ contents in a carbothermal reduction nitridation method. With increasing $Eu^{2+}$ contents, the photoluminescence spectra were red-shifted from 600 nm peak for 1 mol% for to 700 nm for 7 mol%. It was suggested that this red shift is attributed to the energy transfer from one low-energy sited $Eu^{2+}$ (1) to other high-energy sited $Eu^{2+}$ (2). Finally, the best red sample (620 nm emission peak and 80 nm half width for 3 mole% of $Eu^{2+}$) was packaged on a Blue LED together with two additional green and yellow phosphors, the fabricated White LED showed a high color-rendering index of 90 and white color coordinates of x= 0.321 and y = 0.305.

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Enhancement of mechanical and durability properties of preplaced lightweight aggregate concrete

  • Bo Peng;Jiantao Wang;Xianzheng Dong;Feihua Yang;Chuming Sheng;Yunpeng Liu
    • Advances in concrete construction
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    • v.15 no.6
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    • pp.419-430
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    • 2023
  • In this study, the effect of two types of aggregates (fly ash aggregate and shale aggregate) on the density, strength, and durability of preplaced lightweight aggregate concrete (PLWAC) was studied. The results showed that the 7 - 28 days strength of concrete prepared with fly ash aggregates (high water absorption rate) significantly increased, which could attribute to the long-term water release of fly ash aggregates by the refined pore structure. In contrast, the strength increase of concrete prepared with shale aggregates (low water absorption rate) is not apparent. Although PLWAC prepared with fly ash aggregates has a lower density and higher strength (56.8 MPa @ 1600 kg/m3), the chloride diffusion coefficient is relatively high, which could attribute to the diffusion paths established by connected porous aggregates and the negative over-curing effect. Compared to the control group, the partial replacement of fly ash aggregates (30%) with asphalt emulsion (20% solid content) coated aggregates can reduce the chloride diffusion coefficient of concrete by 53.6% while increasing the peak load obtained in a three-point bending test by 107.3%, fracture energy by 30.3% and characteristic length by 103.5%. The improvement in concrete performance could be attributed to the reduction in the water absorption rate of aggregates and increased energy absorption by polymer during crack propagation.

Feasibility Study of Forestry Project in Sarawak State, Malaysia

  • Woo, Heesung;Turner, Paul;Kang, Byongrho;Jang, Jaeyoung;Woo, Jongchoon
    • Journal of Forest and Environmental Science
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    • v.34 no.4
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    • pp.352-358
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    • 2018
  • This research paper investigates available options for implementing clean development mechanism (CDM) project in Sarawak state, Malaysia. To investigate economic feasibility, data was collected using survey and field research methods. Also, economic analysis was estimated using net present value (NPV), internal rate of return (IRR) and payback period (PBP) during the 30 years CDM: afforestation and reforestation periods. The result of economic analysis indicated that, the payback period was estimated at 9 years with 18 percent of internal rate of return (IRR). This study also highlighted that CDM biomass supply project have a lot of challenges due to the reduction and exclusion of bio-Solid Recovered Fuel (SRF), supply and demand scenario, and impact of restriction of illegal logging in Malaysia. This study results demonstrate the methodology and guideline for future CDM investment and projects.

Studies into a high performance composite connection for high-rise buildings

  • Lou, G.B.;Wang, A.J.
    • Steel and Composite Structures
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    • v.19 no.4
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    • pp.789-809
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    • 2015
  • This paper presents experimental and numerical studies into the structural behavior of a high performance corbel type composite connection adopted in Raffles City of Hangzhou, China. Physical tests under both monotonic and quasi-static cyclic loads were conducted to investigate the load carrying capacities and deformation characteristics of this new type of composite connection. A variety of structural responses are examined in detail, including load-deformation characteristics, the development of sectional direct and shear strains, and the history of cumulative plastic deformation and energy. A three-dimensional finite element model built up with solid elements was also proposed for the verification against test results. The studies demonstrate the high rigidity, strength and rotation capacities of the corbel type composite connections, and give detailed structural understanding for engineering design and practice. Structural engineers are encouraged to adopt the proposed corbel type composite connections in mega high-rise buildings to achieve an economical and buildable and architectural friendly engineering solution.

Pharmacetical Characteristics and Analysis of Garlic Extract (마늘 추출물의 약리적 특성 및 분석)

  • Sung, Ki-Chun
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.3
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    • pp.301-308
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    • 2007
  • From the experiment result on pharmacetical characteristics and analysis of Garlic extract, some conclusions were obtained as follows. From the results on extract experiment of Garlic, extraction ratio was about 6.0%, and after dried with dry oven from Garlic extract, it obtained about 50%-Garlic extract of solid state. From results on antimicrobial experiment of Garlic extract, number of staphylococcus and fungus in microbe decreased more and more according to time passage. This phenomenon showed that Garlic extract keeps antimicrobial effect. From results on antioxidation experiment of Garlic extract, DPPH scavenging activity of free radical showed that Garlic extract appears more remarkable reduction ability than reference samples. This phenomenon means that antioxidation of Garlic extract appears higher than Vitamin-C and BHA. From results on instrument analysis, inorganic components of K, Na, Ca, Si, Mg, Zn etcs from Garlic extract were detected with ICP/OES and the fatty and aromatic components of trimethyl sulfide, diallyl disulfide, diallyl trisulfide, 2-mercaptobenzothiazole etcs from Garlic extract were detected with GC/MS.

A Study on harmonics generation and reduction in Dimmer circuits (Dimmer 회로에서의 고조파 발생과 저감에 관한 연구)

  • Park, Seok-Hoon;Yu, In-Keun
    • Proceedings of the KIEE Conference
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    • 2000.07a
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    • pp.252-254
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    • 2000
  • For many years, electric utility has used sustained interruption rates as a reliability index. Today, however, many electricity consumers are adversely affected by more subtle voltage disturbances such as harmonic distortion. This paper deals with observations of events that occur in the Dimmer circuits and phase control which could affect harmonics problem to the commercial power system. In order to reduce the effect of harmonics and design filters, Solid State Relay Dimmer(SCRs or TRIACs) and Noise Filter are described, and the effects of harmonics is also analyzed. IGBT Dimmer which is appropriate method to reduce harmonics and improve efficiency is introduced.

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Synthesis and Luminescent Property Investigation of the $Lu_3Al_5O_{12}$:Ce for the White LEDs

  • Lee, Seung-Jae;Park, Joung-Kyu;Bae, Pan-Kee;Kim, Chang-Hae;Chang, Hyun-Ju;Kim, Yong-Rok
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.591-593
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    • 2008
  • In this report, cerium doped lutetium aluminate ($Lu_3Al_5O_{12}$:Ce) phosphor has been synthesized by the solid state method under reduction atmosphere with mixture gas. The prepared phosphor shows a main luminescent peak at 555nm. Consequently, this phosphor is possible to be applicable to white LED lamp by InGaN chips.

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A BINARY OBSERVING PROJECT ON THE NCUO SPECKLE INTERFEROMETER

  • TSAY WEAN-SHUN;KUO HUI-JEAN;CHAN PEI-CHING
    • Journal of The Korean Astronomical Society
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    • v.29 no.spc1
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    • pp.409-410
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    • 1996
  • Speckle Interferometer equipped with an ITT intensified CCD have been used on the NCUO ( National Central University Observatory, Taiwan) 24-inch telescope for studying the orbits of bright binary systems selected from the Yale's Bright Star Catalogue. The high resolution and high sensitivity ITT intensified solid state video camera ( F4577 ) has external gain and gate control functions which will simplify the design of the speckle camera and allow us to do precise speckle photometry. The goal of this project is trying to study the bright binary systems with separations between the average size of seeing disk and the diffraction limit of the 24-inch telescope. Recently some observing data have been reduced and compared with the other teams' results. We are now improving the data reduction technology and trying to use real time observing mode on the monthly routine observation.

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