고연색 LED용 적색 Sr2Si5N8:Eu2+ 형광체의 합성 및 발광특성 연구

Synthesis and Luminescence of Sr2Si5N8:Eu2+ Red Phosphor for High Color-Rendering White LED

  • 이성훈 ((주)효성) ;
  • 김종수 (부경대학교 융합디스플레이공학과) ;
  • 강태욱 (부경대학교 LED협동과정) ;
  • 류종호 (부경대학교 융합디스플레이공학과) ;
  • 이상남 (부경대학교 인쇄공학과)
  • Lee, Sung Hoon (R&D Business Lab, Hyosung Corporation) ;
  • Kim, Jong Su (Department of Display Engineering, Pukyong National University) ;
  • Kang, Tae Wook (Interdisciplinary Program of LED and Solid State Lighting Engineering, Pukyong National University) ;
  • Ryu, Jong Ho (Department of Display Engineering, Pukyong National University) ;
  • Lee, Sang Nam (Department of Graphic arts and Information Engineering, Pukyong National University)
  • 투고 : 2017.10.30
  • 심사 : 2017.12.21
  • 발행 : 2017.12.31

초록

Red phosphors, $Sr_2Si_5N_8:Eu^{2+}$, were synthesized as a single-phase crystal structure by optimizing carbon and $Eu^{2+}$ contents in a carbothermal reduction nitridation method. With increasing $Eu^{2+}$ contents, the photoluminescence spectra were red-shifted from 600 nm peak for 1 mol% for to 700 nm for 7 mol%. It was suggested that this red shift is attributed to the energy transfer from one low-energy sited $Eu^{2+}$ (1) to other high-energy sited $Eu^{2+}$ (2). Finally, the best red sample (620 nm emission peak and 80 nm half width for 3 mole% of $Eu^{2+}$) was packaged on a Blue LED together with two additional green and yellow phosphors, the fabricated White LED showed a high color-rendering index of 90 and white color coordinates of x= 0.321 and y = 0.305.

키워드

참고문헌

  1. U. Zehnder, A. Weimar, U. Strauss, M. Fehrer, B. Hahn, H. J. Lugauer and V. Harle, J. Cryst. Growth, 230, 497, (2001). https://doi.org/10.1016/S0022-0248(01)01304-5
  2. E. F. Schubert and J. K Kim, Science, 308, 1274, (2005). https://doi.org/10.1126/science.1108712
  3. W. M. Yen, S. Shionoya, H. Yamamoto, Phosphor Handbook, 2nd ed., CRC Press, Boca Raton, (2007).
  4. S. Pimputkar, J. S. Speck, S. P. Denbaars and S. Nakamura, Nat. Photonics, 3, 179, (2009). https://doi.org/10.1038/nphoton.2009.31
  5. Philippe F. Smet, Antjony B. Parmentier and D. Poelman, J. Electrochem. Soc., 158(6), R37, (2011). https://doi.org/10.1149/1.3568524
  6. K. Sakuma, N. Hirosaki, N. Kimura, M. Ohashi, R.-J. Xie, Y. Yamamoto, T. Suehiro, K. Asano and Tanaka, IEICE Trans. Electron., E88-C, 2057, (2005). https://doi.org/10.1093/ietele/e88-c.11.2057
  7. K. Sakuma, N. Hirosaki, R.-J. Xie J. Lumin., 126, 843, (2007). https://doi.org/10.1016/j.jlumin.2006.12.006
  8. R. J. Xie, N. Hirosaki and T. Takeda, Materials, 3, 3777, (2010). https://doi.org/10.3390/ma3063777
  9. G.Blasse, B. C. Grabmaier, Luminescent Materials, Springer-Verlag, Berlin, (1994).
  10. J. W. H. van Krevel, H. T. Hitzen, R. Meijerink, J. Alloys and Compounds. 268, 277, (1998).
  11. Brian F. Aull' and Hans P. Jenssen, Phys. Rev. B. 34, 10, (1986).
  12. K .S. Shon, S. Lee, R. J. Xie, and N. Horisaki, Appl. Phys. Lett 95, 12903, (2009). https://doi.org/10.1063/1.3171936