• Title/Summary/Keyword: Solid carbon

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Optimization for the Solid-Phase Extraction of Trace Clobazam from Biological Samples (생체시료로부터 미량 크로바잠의 고상추출을 위한 최적화)

  • Kim, Kyoung-Rae;Kim, Jeong-Ho;Kim, Hyub;Yoon, Hye-Ran
    • YAKHAK HOEJI
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    • v.39 no.4
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    • pp.395-400
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    • 1995
  • The sorption and desorption properties of four adsorbents were evaluated for the trace enrichment of clobazam from biological samples. Graphitized carbon black(GCB) gaved the highest dynamic adsorption coefficient. Among the six organic solvents examined, acetone gave the highest desorption coefficient for the clobazam adsorbed on GCB. Using the GCB column, the optimum elution volume of the eluting solvent was evaluated from the on-line monitored breakthrough curve for clobazam. When GCB as the solid adsorbent and acetone as the eluting solvent were used for the solidphase extraction of clobazam from serum, the recoveries were higher than 83% with good reproducibility in the concentration range of 20-50 $\mu\textrm{g}$/ml.

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Nonlinear forced vibration of sandwich plate with considering FG core and CNTs reinforced nano-composite face sheets

  • Rostami, Rasoul;Rahaghi, Mohsen Irani;Mohammadimehr, Mehdi
    • Smart Structures and Systems
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    • v.26 no.2
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    • pp.185-193
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    • 2020
  • Nonlinear vibration of sandwich plate with functionally graded material (FGM) core and carbon nano tubes reinforced (CNTs) nano-composite layers by considering temperature-dependent material properties are studied in this paper. Base on Classical plate theory (CPT), the governing partial differential equations of motion for sandwich plate are derived using Hamilton principle. The Galerkin procedure and multiple scales perturbation method are used to find relation between nonlinear frequency and amplitude of vibration response. The dynamic responses of the sandwich plate are also investigated in both time and frequency domains. Then, the effects of nonlinearity, excitation, power law index of FG core, volume fraction of carbon nanotube, the function of material variations of FG core, temperature changes, scale transformation parameter and damping factor on the frequency responses are investigated.

Gas-Solid Heat Transfer Analysis of Bubbling Fluidized Bed at Bottom Ash Cooler (바닥재 냉각기 기포유동층의 기체-고체 연전달 분석)

  • Gyu-Hwa, Lee;Dongwon, Kim;Jong-min, Lee;Kyoungil, Park;Byeongchul, Park
    • KEPCO Journal on Electric Power and Energy
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    • v.8 no.2
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    • pp.97-101
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    • 2022
  • In this study we investigated the gas to solid heat transfer of bubbling fluidized bed bottom ash cooler installed at the Donghae power plant in South Korea. Several different analyses are done through 1-D calculations and 3-D CFD simulation to predict the bottom ash exit temperatures when it exits the ash cooler. Three different cases are set up to have consideration of unburnt carbon in the bottom ash. Sensible heat comparison and heat transfer calculation between the fluidization air and the bottom ash are conducted and 3-D CFD analysis is done on three cases. We have obtained the results that the bottom ash with unburnt carbon is exiting the ash cooler, exceeding the targeted temperature from both 1-D calculation and 3-D CFD simulation.

Tribological Properties of Carbon Nanotube Thin Films by using Electrodynamic Spraying Method (전기 분사 증착 방식을 이용한 탄소 나노 튜브 박막의 트라이볼로지적 특성에 관한 연구)

  • Kim, Chang-Lae;Kim, Dae-Eun;Kim, Hae-Jin
    • Tribology and Lubricants
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    • v.34 no.6
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    • pp.313-317
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    • 2018
  • Carbon-based coatings, including carbon nanotubes (CNTs), graphene, and buckyball ($C_{60}$), receive much interest because of their outstanding mechanical and electrical properties for a wide range of electromechanical component-based applications. Previous experimental results demonstrate that these carbon-based coatings are promising solid lubricants because of their superior tribological properties, and thus help prolong the lifetime of silicon-based applications. In this study, CNT coatings are deposited on a bare silicon (100) substrate by electrodynamic spraying under different deposition conditions. During the coating deposition, the applied voltage, CNT concentration of the solution, distance between the injecting nozzle and the substrate and diameter of the injecting nozzle are optimized to control the thickness and surface roughness of the CNT coatings. The surface morphology and thickness of the coatings are characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM), respectively. The friction and wear properties of the coatings are investigated by using a pin-on-reciprocating-type tribotester under various experimental conditions. The friction coefficient of the CNT coating is as low as 0.15 under high normal loads. The overall results reveal that CNT coatings deposited by electrodynamic spraying provide relatively uniform with superior lubrication performance.

Mechanical Properties and Solid Lubricant Wear Behavior of MMCs Reinforced with a Hybrid of $Al_{2}O_{3}$ and Carbon Short Fibers (알루미나와 탄소단섬유를 혼합한 금속복합재료의 기계적 성질과 고체윤활 마모거동)

  • 송정일;봉하동;한경섭
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.4
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    • pp.968-980
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    • 1995
  • Al/Al$_{2}$O$_{3}$/C hybrid metal matrix composites are fabricated by the direct squeeze infiltration method. From the microstructure of Al/Al$_{2}$O$_{3}$/C composites, uniform distribution of reinforcements and good bondings are found. Optimum processing conditions for preforms and squeeze castings are suggested. Mechanical properties, such as elastic modulus, elongation, 0.2% offset yield strength and ultimate tensile strength are obtained. Through the abrasive were test and wear surface analsis, wear behavior and its mechanism of AC2B aluminum and Al/Al$_{2}$O$_{3}$/C composites can be characterized under various sliding speed conditions. Tensile strenght elongation of Al/Al$_{2}$O$_{3}$/C composites are decreased with increasing the addition of carbon fiber. On the contrary, elastic modulus of Al/Al$_{2}$O$_{3}$/C composites is slightly improved compared with that of the unreinforced matrix alloy. The addition of carbon fiber to al/al$_{2}$O$_{3}$/C composites gives rise to improvement of the wear resistance. Specially, carbon chopped fibers play an important role in interfering sticking between the counter material and metal matirix composites. Al/Al$_{2}$O$_{3}$/C composites are suitable to high speed due to solid lubication of carbon. And wear model of Al/Al$_{2}$O$_{3}$/C composites is suggested by the examination of worn surfaces.

A Study on the Improvement of Strength in NiO-YSZ Porous Anode Material for Solid Oxide Fuel Cell (SOFC용 다공성 NiO-YSZ 음극소재의 강도향상에 관한 연구)

  • 이기성;서두원;유지행;우상국
    • Journal of the Korean Ceramic Society
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    • v.40 no.3
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    • pp.241-248
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    • 2003
  • We controlled the amount of Y$_2$O$_3$additives, 8 mol% and 10 mol%, and the type of carbon pore former, activated carbon and carbon black, to improve the strength of porous NiO-YSZ anode materials for solid oxide fuel ceil. The 3-point flexural strength, porosity and electrical conductivity were evaluated. As a result, the strength of anode materials with the addition of carbon black was markedly improved. The strength of NiO-10 mol%YSZ sintered at relatively higher temperature was higher than that of NiO-8 mol%YSZ materials. The electrical conductivity of NiO-10 mol%YSZ with carbon black was evaluated as much as 10$^2$∼10$^3$S/cm at 700$^{\circ}C$∼1000$^{\circ}C$ in reducing atmosphere.

Analysis of Boundary Layer in Solid Rocket Nozzle and Numerical Analysis of Thermal Response of Carbon/Phenolic using Finite Difference Method (고체 로켓 노즐의 경계층 해석과 유한차분법을 이용한 탄소/페놀릭의 열반응 해석 연구)

  • Seo, Sang Kyu;Hahm, Hee Cheol;Kang, Yoon Goo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.1
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    • pp.36-44
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    • 2018
  • The thermal response of carbon/phenolic used in a solid rocket nozzle liner was analyzed. In this paper, the numerical analysis of the thermal response of carbon/phenolic consists of (1) the integration equation of the boundary layer to obtain the convective heat transfer coefficient of the combustion gas on the rocket nozzle wall and (2) 1-D finite difference method for heat conduction of carbon/phenolic to calculate the ablation, char, and temperature. The calculated result was compared with the result of a blast-tube-type test motor. It is found that the calculated result shows good agreement with the thermal response of the test motor, except at the vicinity of the throat insert.

Syngas Production Based on Co-electrolysis of CO2 and H2O in Solid Oxide Electrolysis Cell (고체 산화물 CO2-H2O 공전해 기반 합성가스 생산 기술 )

  • NAMGI JEON;SANGHYEOK LEE;SANGKUK KIM;CHIKYU AHN;JIN SOO AHN
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.2
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    • pp.140-145
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    • 2024
  • High temperature co-electrolysis of H2O-CO2 mixtures using solid oxide cells has attracted attention as promising CO2 utilization technology for production of syngas (H2/CO), feedstock for E-fuel synthesis. For direct supply to E-fuel production such as hydrocarbon and methanol, the outlet gas ratio (H2/CO/CO2) of co-electrolysis should be controlled. In this work, current voltage characteristic test and product gas analysis were carried out under various reaction conditions which could attain proper syngas ratio.

A Study on Reverse-water Gas Shift Reaction in Solid Oxide Water Electrolysis Cell-stack for CO2 Reduction (CO2 저감을 위한 고체산화물 수전해 스택의 역수성가스 전환 반응 고찰)

  • SANGKUK KIM;NAMGI JEON;SANGHYEOK LEE;CHIKYU AHN;JIN SOO AHN
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.2
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    • pp.162-167
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    • 2024
  • Fossil fuels have been main energy source to people. However, enormous amount of CO2 was emitted over the world , resulting in global climate crisis today. Recently, solid oxide electrolyzer cell (SOEC) is getting attention as an effective way for producing H2, a clean energy resource for the future. Also, SOEC could be applicable to reverse water-gas shift reaction process due to its high-temperature operating condition. Here, SOEC system was utilized for both H2 production and CO2 reduction process, allowing product gas composition change by controlling operating conditions.

Char Gasification Model Including the Effects of Pore Structure and Solid Reaction Product (기공 구조와 반응 부산물의 영향을 고려한 촤의 가스화 모델)

  • Chi, Jun-Hwa
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.4
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    • pp.328-339
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    • 2010
  • A new gasification model for coal char was developed considering the effects of pore structure and solid reaction product (ash) and compared with conventional models. Among various parameters reflecting microscopic pore structure, initial pore surface per unit volume of char was found to have the largest effect on carbon conversions. Reaction studies showed that the proposed model can predict carbon conversion more accurately over a broader range of reaction degree compared to the conventional models. Therefore the model proposed in this study would be useful for the design of pilot or commercial scale gasifiers.