• Title/Summary/Keyword: Solid carbon

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Glucoamylase Production in Batch and Fed-Batch Solid State Fermentation: Effect of Maltose or Starch Addition

  • Bertolin, Telma Elita;Jorge Alberto Vieira Costa;Gean Delise Leal Pasquali
    • Journal of Microbiology and Biotechnology
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    • v.11 no.1
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    • pp.13-16
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    • 2001
  • Maltose and soluble starch were used as secondary sources of carbon for glucoamylase production by Aspergillus awamori in solid state fermentation. During batch cultivation, maltose above 2.5%(w/w) repressed glucoamylase production, but, by adding either 2.5% (w/w) maltose or 1.25% (w/w) soluble starch to fed-batch cultivations, glucoamylase activity was increased by 15% and 170% over standard medium, respectively. The data showed that maltose is a weak inducer of glucoamylase production in solid stat fermentation.

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Study on Pneumatic Transport for Pulverized coal Combustion (미분탄 연소를 위한 공기압 수송에 관한 연구)

  • Oh, C.S.;Choi, B.S.;Hong, S.S.;Hwang, K.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.4 no.4
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    • pp.299-305
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    • 1992
  • Saltation occurs in horizontal flow of solid and gas when the carrier gas velocity is small enough to permit enough to settling of the solid particles within the transport line. So we should examine the pneumatic flow system to lessen the unbured carbon in the power plant. In this paper the saltation velocity was studied on the various solid flow rate in the constant pipe diameter and on the various temperatures of the flow gas. The air velocity in the power plant transport lines was also surveyed in order to compare with the saltation velocity. As the solid flow rate increased in the constant diameter, saltation velocity increased and as the temperater of the flow gas inereased in the transport line, saltation velocity also increased.

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Solid Fuel in the Highly Preheated Air Combustion (고체 연료의 고온 공기 연소 특성에 관한 연구)

  • Jin, Hong-Jong;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2002.11a
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    • pp.185-192
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    • 2002
  • A laboratory scale thermogravimetric analyser was developed to investigate the combustion characteristics of selected solid fuel(wood) in the highly preheated air. The aims are to introduce in the means of experimental determination of the solid fuel particle characteristics through the combustion process in the environment of highly preheated air. A nearly single particle combustion condition was reproduced in a thermogravimetric analyser and regenerating combustor. For a fuel particle whose characteristic length was a few centimeter, the sub-processes of fuel drying, pyrolysis as well as the combustion of residual carbon were identified. Fluidized environment of carrier gas was selected as the major parameter which affect the combustion process.

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Production of Red Pigments by Monascus purpureus in Solid-state Culture

  • Lee Bum-Kyu;Piao Hai Yan;Chung Wook-Jin
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.1
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    • pp.21-25
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    • 2002
  • To maximize and sustain the productivity of Monascus pigments, various environmental and nutritional parameters, such as the initial moisture content, pH, inoculum size, sample size, and nutrient supplement, that influence pigment production were evaluated in solid-state cultures as follows: initial moisture content, $50\%;$ pH, 6.0; inoculum size $1\;\times\;10^4$ spore cells $(grams\;of\;dry\;solid\;substrate)^{-1};$ sample size, 300 g. All supplementary nutrients (carbon, nitrogen, and mineral sources) added has inhibitory effects on the cell growth and red pigment production. In open tray culture the maximum biomass yield and specific productivity of red pigments were 223 mg DCW $(grams\;of\;initial\;dry\;substrate)^{-1}$ and, $47.6\;OD_{500}\;(DCW\;grams)^{-1}h^h{-1}$ respectively.

A Study on Synthesis and Characterization of $Ti_xZr_{1-x}C$ Solid-Solution by Self-propagation High Temperature Synthesis Method (SHS법에 의한 $Ti_xZr_{1-x}C$ 고용체의 합성 및 특성 연구)

  • 이형복;오유근;이성민
    • Journal of the Korean Ceramic Society
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    • v.34 no.7
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    • pp.731-737
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    • 1997
  • TixZr1-xC(0$0^{\circ}C$, 5.1 mm/sec respectively. The relative density, three point flexural strength, and the hardness of composites, which was sintered at 190$0^{\circ}C$ for 60 min by using hot-pressing under a pressure of 30 MPa, were 99%, 525 MPa and 24 GPa respectively.

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Electrochemical Performance of a Metal-supported Solid Oxide Electrolysis Cell

  • Lee, Taehee;Jeon, Sang-Yun;Yoo, Young-Sung
    • KEPCO Journal on Electric Power and Energy
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    • v.5 no.2
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    • pp.121-125
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    • 2019
  • A YSZ electrolyte based ceramic supported Solid Oxide Cell (SOC) and a metal interconnect supported SOC was investigated under both fuel cell and co-electrolysis (steam and $CO_2$) mode at $800^{\circ}C$. The single cell performance was analyzed by impedance spectra and product gas composition with gas chromatography(GC). The long-term performance in the co-electrolysis mode under a current density of $800mA/cm^2$ was obtained using steam and carbon dioxide ($CO_2$) mixed gas condition.

A Study on Reactions of Carbon-Carbonate Mixture at Elevated Temperature: As an Anode Media of SO-DCFC (SO-DCFC 적용을 위한 카본블랙-탄산염 혼합 매개체의 고온 반응 특성에 대한 연구)

  • Yu, Jun Ho;Kang, Kyungtae;Hwang, Jun Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.8
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    • pp.677-685
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    • 2014
  • A direct carbon fuel cell (DCFC) generates electricity directly by converting the chemical energy in coal. In particular, a DCFC system with a solid oxide electrolyte and molten carbonate anode media has been proposed by SRI. In this system, however, there are conflicting effects of temperature, which enhances the ion conductivity of the solid electrolyte and reactivity at the electrodes while causing a stability problem for the anode media. In this study, the effect of temperature on the stability of a carbon-carbonate mixture was investigated experimentally. TGA analysis was conducted under either nitrogen or carbon dioxide ambient for $Li_2CO_3$, $K_2CO_3$, and their mixtures with carbon black. The composition of the exit gas was also monitored during temperature elevation. A simplified reaction model was suggested by considering the decomposition of carbonates and the catalyzed Boudouard reactions. The suggested model could well explain both the measured weight loss of the mixture and the gas formation from it.

Reduction of Li4Ti5O12 Powder Agglomeration by the Addition of Carbon Black during Solid-state Synthesis (고상법을 사용한 Li4Ti5O12의 합성공정 중 카본블랙 추가를 통한 입자뭉침 억제)

  • Kim, Duri;Kang, Sang June;Hong, Min Young;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.63-68
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    • 2016
  • $Li_4Ti_5O_{12}$ is prepared through a solid-state reaction between anatase $TiO_2$ and $Li_2CO_3$ for the negative electrode active materials in quick-charging lithium-ion batteries. The small amount of carbon black (0, 0.5, 1.0, and 3.0 wt%) is added for the reduction of powder agglomeration during heat-treatment. As the amount of the added carbon black increases, the tap density of $Li_4Ti_5O_{12}$ powder gradually decreases. Furthermore, the $Li_4Ti_5O_{12}$ powder prepared with 1.0 wt% of carbon black shows the highest sieved fraction at the powder classification by 325 mesh standard sieve. The $Li_4Ti_5O_{12}$ powders with various contents of carbon black are almost same at the rate capability for the negative electrode materials in lithium-ion batteries.

Synthesis of Uniformly Doped Ge Nanowires with Carbon Sheath

  • Kim, Tae-Heon;;Choe, Sun-Hyeong;Seo, Yeong-Min;Lee, Jong-Cheol;Hwang, Dong-Hun;Kim, Dae-Won;Choe, Yun-Jeong;Hwang, Seong-U;Hwang, Dong-Mok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.289-289
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    • 2013
  • While there are plenty of studies on synthesizing semiconducting germanium nanowires (Ge NWs) by vapor-liquid-solid (VLS) process, it is difficult to inject dopants into them with uniform dopants distribution due to vapor-solid (VS) deposition. In particular, as precursors and dopants such as germane ($GeH_4$), phosphine ($PH_3$) or diborane ($B_2H_6$) incorporate through sidewall of nanowire, it is hard to obtain the structural and electrical uniformity of Ge NWs. Moreover, the drastic tapered structure of Ge NWs is observed when it is synthesized at high temperature over $400^{\circ}C$ because of excessive VS deposition. In 2006, Emanuel Tutuc et al. demonstrated Ge NW pn junction using p-type shell as depleted layer. However, it could not be prevented from undesirable VS deposition and it still kept the tapered structures of Ge NWs as a result. Herein, we adopt $C_2H_2$ gas in order to passivate Ge NWs with carbon sheath, which makes the entire Ge NWs uniform at even higher temperature over $450^{\circ}C$. We can also synthesize non-tapered and uniformly doped Ge NWs, restricting incorporation of excess germanium on the surface. The Ge NWs with carbon sheath are grown via VLS process on a $Si/SiO_2$ substrate coated 2 nm Au film. Thin Au film is thermally evaporated on a $Si/SiO_2$ substrate. The NW is grown flowing $GeH_4$, HCl, $C_2H_2$ and PH3 for n-type, $B_2H_6$ for p-type at a total pressure of 15 Torr and temperatures of $480{\sim}500^{\circ}C$. Scanning electron microscopy (SEM) reveals clear surface of the Ge NWs synthesized at $500^{\circ}C$. Raman spectroscopy peaked at about ~300 $cm^{-1}$ indicates it is comprised of single crystalline germanium in the core of Ge NWs and it is proved to be covered by thin amorphous carbon by two peaks of 1330 $cm^{-1}$ (D-band) and 1590 $cm^{-1}$ (G-band). Furthermore, the electrical performances of Ge NWs doped with boron and phosphorus are measured by field effect transistor (FET) and they shows typical curves of p-type and n-type FET. It is expected to have general potentials for development of logic devices and solar cells using p-type and n-type Ge NWs with carbon sheath.

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Characterization of electrochemical behaviour for supercapacitor based on porous activated carbon composite with various contents of metal-organic framework(MOF) (금속유기골격체(Metal-organic Framework)의 함량에 따른 다공성 활성탄소 복합재료 기반 슈퍼커패시터의 전기화학적 거동 분석)

  • Jeong, Hyeon Taek;Kim, Yong Ryeol
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.5
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    • pp.1200-1207
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    • 2020
  • We have fabricated the supercapacitor composed of porous activated carbon, metal-organic framework (MOF) with polymer based solid state electrolyte as a "ion gel" and characterized its electrochemical behaviour as a function of the MOF contents. The electrochemical properties of the supercapacitor were analyzed via cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS) and galvanostatic charge/discharge test. As a results, the supercapacitor based on porous activated carbon/MOF composite showed the highest capacitance value at 0.5 wt% of MOF contents and decreased capacitance with increase MOF contents over the 0.5 wt%. Consequently, the porous activated carbon/MOF composite based supercapacitor is applicable to various aspect for energy storage device.