• Korean Chemical Engineering Research
• /
• v.48 no.4
• /
• pp.506-510
• /
• 2010

Electron recombinations in electrolyte solution reduce light-to-energy conversion efficiency at the nanoporous electrode surface of dye sensitized solar cells. In this study, we improved the conversion efficiency using an energy barrier at the nanoporous electrode surface to control the recombination process. The energy barrier was formed by coating nanoporous $TiO_2$ electrode with $Nb_2O_5$ material. We investigated the influence of energy barrier on the cell efficiency depending on the coating thickness. Nanoporous $TiO_2$ electrode was coated about 5 nm thickness by 12 times coatings, and so the coating layer was grown about 0.417 nm for every time. Enhancement of conversion efficiency from 2.55% to 4.25% was achieved at 0.834 nm coating thickness, and it was believed as the optimum thickness for minimizing the electron recombination process in our experimental system.

• Journal of the Korean Solar Energy Society
• /
• v.23 no.2
• /
• pp.59-70
• /
• 2003

A stoichiometric mixture of evaporating materials for $CuGaSe_2$ single crystal thin films was prepared from horizontal electric furnace. Using extrapolation method of X-ray diffraction patterns for the polycrystal $CuGaSe_2$, it was found tetragonal structure whose lattice constant $a_0$ and $c_0$ were $5.615{\AA}$ and $11.025{\AA}$, respectively. To obtain the single crystal thin films, $CuGaSe_2$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the hot wall epitaxy (HWE) system. The source and substrate temperatures were $610^{\circ}C$ and $450^{\circ}C$, respectively. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of $CuGaSe_2$ single crystal thin films measured with Hall effect by van der Pauw method are $5.01\times10^{17}cm^{-3}$ and $245cm^2/V{\cdot}s$ at 293K. respectively. The temperature dependence of the energy band gap of the $CuGaSe_2$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g$(T)=1.7998 eV-($8.7489\times10^{-4}$ eV/K)$T^2$/(T+335K). After the as-grown $CuGaSe_2$ single crystal thin films was annealed in Cu-, Se-, and Ga-atmospheres, the origin of point defects of $CuGaSe_2$ single crystal thin films has been investigated by the photoluminescence(PL) at 10 K. The native defects of $V_{CU},\;V_{Se},\;Cu_{int}$ and $Se_{int}$ obtained by PL measurements were classified as a donors or acceptors type. And we concluded that the heat-treatment in the Cu-atmosphere converted $CuGaSe_2$ single crystal thin films to an optical n-type. Also, we confirmed that Ga in $CuGaSe_2$/GaAs did not form the native defects because Ga in $CuGaSe_2$ single crystal thin films existed in the form of stable bonds.

• Journal of Navigation and Port Research
• /
• v.31 no.3 s.119
• /
• pp.229-233
• /
• 2007

This paper presents the performance of PV(Photovoltaic) system, the design of MPPT(Maximum Power Point Tracker). Output of PV power system is DC, and PV power system is linked to the DC bus. The current(I)-voltage(V) output characteristic of PV cells changes with solar irradiance and cell temperature as parameters. As various PV modules respond differently to each of the parameters cited above. Maximum output of PV modules am be achieved by MPPT(Maximum Power Point Tracker) algorithm This paper includes a discussion on the performance of PV module, MPPT algorithm and the influence of PV module angle.

• 한국신재생에너지학회:학술대회논문집
• /
• 2007.06a
• /
• pp.280-283
• /
• 2007

The first grid-connected, building-integrated transparent amorphous silicon photovoltaic installation has been operated since October 2004 in Yongin, Korea. The 2.2kWp transparent PV system was applied to the facade of entrance hall in newly constructed KOLON E&C R&D building. The PV module is a nominal 0.98m ${\times}$ 0.95m, 10% transparent, laminated, amorphous(a-Si) thin-film device rated at 44 Wp per module. To demonstrate the architectural features of thin film PV technologies for daylighting application, transparent PV modules are attached to the building envelope with the form of single glazed window and special point glazing(SPG) frames. Besides power generation, the 10% transmittance of a-Si PV module provides very smooth natural daylight to the entrance hall without any special shading devices for whole year. The installation is fully instrumented and is continuously monitored in order to allow the performance assessment of amorphous silicon PV operating at the prevailing conditions. This paper presents measured power performance data from the first 12 months of operation. For the first year, annual average system specific yield was just 486.4kWh/kWp/year which is almost half of typical amorphous silicon PV output under the best angle and orientation. It should be caused by building orientation and self-shading of adjacent mass. Besides annual power output, various statistical analysis was performed to identify the characteristics of transparent thin film PV system.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.24 no.12B
• /
• pp.2298-2319
• /
• 1999

In this paper, we propose a new moving mobile base station (MMBS) scheme for very low power and micro-size RMIMS (radio-interfaced micro information monitoring system) terminals. RMIMS terminals can be used in various application service areas such as pollution monitoring, environment surveillance, traffic monitoring, emergency monitoring (e.g., building, bridge, railroad breakdown), security monitoring (e.g., theft, alarm) and military application. For these applications based on wireless transmission technologies, sensor type RMIMS terminals must satisfy low cost and low power design (e.g., solar power, life limited battery) requirement. In RMIMS terminal design, this low power requirement limits transmission range of uplink or reverse link and means small cell size. Also these applications using RMIMS terminals may have a little bit non real-time traffic characteristic and low scattering density in service area.

• Molecular & Cellular Toxicology
• /
• v.3 no.1
• /
• pp.23-30
• /
• 2007

The effects of high energy short wave solar radiation on human skin have received much publicity as the major cause of accelerated skin ageing and of skin cancers. To meet public demand, the cosmetic industry has developed sun protection factor products, which contain a variety of so-called "UV filters", among others benzophenone (BP) and its metabolites are the widely used UV filters. UV filters are also used to prevent UV light from damaging scents and colors in a variety of cosmetics products and to protect of plastic products against light-induced degradation. There are many variants of BP in use. In this respect, to regulate and to evaluate the hazardous effect of BP-type UV filters will be important to environment and human health. The genotoxicity of 7 BP-type UV filters was evaluated in L5178Y $(tk^{+/-})$ mouse lymphoma cells in vitro. BP, benzhydrol, 4-hydroxybenzophenone 2-hydroxy-4-methoxybenzophenone and 2, 4-dihydroxybenzophenone did not induce significant mutation frequencies both in the presence and absence of metabolic activation system. 2, 2'-Dihydroxy-4-methoxybenzophenone appeared the positive results at the highest dose, i.e. 120.4 ${\mu}g/mL$ only in the absence of metabolic activation system. And also, 2, 3, 4-trihydroxybenzophenone revealed a significant increase of mutation frequencies in the range of 138.1-207.2 ${\mu}g/mL$ in the absence of metabolic activation system and 118.3-354.8 ${\mu}g/mL$ in the presence of metabolic activation system. Through the results of MLA with 7 BP-type UV filters in L5178Y cells in vitro, we may provide the important clues on the genotoxic potentials of these BP-type UV filters.

• Korean Journal of Agricultural and Forest Meteorology
• /
• v.3 no.3
• /
• pp.156-162
• /
• 2001

In order to monitor local climatic information, twelve automated weather stations (AWS) were installed in alpine area by the Alpine Agricultural Experiment Station, Rural Development Administration (RDA), at the field of major crop located in around highland area, and collected data from 1993 to 2000. Hourly measurements of air and soil temperature (underground 10 cm,20 cm), relative humidity, wind speed and direction, precipitation, solar radiation and leaf wetness were automatically performed and the data could be collected through a public phone line. Datalogger was selected as CR10X (Campbell scientific, LTD, USA) out of consideration for sensers' compatibility, economics, endurance and conveniences. All AWS in alpine area were combined for net work and daily climatic data were analyzed in text and graphic file by program (Chumsungdae, LTD) on 1 km $\times$ 1 km grid tell basis. In this analysis system, important multi-functionalities, monitoring and analysis of local climatic information in alpine area was emphasized. The first objective was to obtain the output of a real time data from AWS. Secondly, daily climatic normals for each grid tell were calculated from geo-statistical relationships based on the climatic records of existing weather stations as well as their topographical informations. On 1 km $\times$ 1 km grid cell basis, real time climatic data from the automated weather stations and daily climatic normals were analyzed and graphed. In the future, if several simulation models were developed and connected with this system it would be possible to precisely forecast crop growth and yield or plant disease and pest by using climatic information in alpine area.

• Transactions of the Korean hydrogen and new energy society
• /
• v.22 no.1
• /
• pp.118-127
• /
• 2011

An IGCC was evaluated as one of the next generation technologies that would be able to substitute for coal-fired power plants. According to "The 4th Basic Plan of Long-term Electricity Supply & Demand" which is developed by the Electricity Business Acts, the first IGCC will be operated at 2015. Like other new and renewable energy such as solar PV, Fuel cell, The IGCC is considered as non-competitive generation technology because it is not maturity technology. Before the commercial operation of an IGCC in our electricity market, its economic feasibility under the Korean electricity market, which is cost-based trading system, is studied to find out institutional support system. The results of feasibility summarized that under the current electricity trading system, if the IGCC is considered like a conventional plant such as nuclear or coal-fired power plants, it will not be expected that its investment will be recouped within life-time. The reason is that the availability of an IGCC will plummet since 2016 when several nuclear and coal-fired power plants will be constructed additionally. To ensure the reasonable return on investment (NPV>0 IRR>Discount rate), the availability of IGCC should be higher than 77%. To do so, the current electricity trading system is amended that the IGCC generator must be considered as renewable generators to set up Price Setting Schedule and it should be considered as pick load generators, not Genco's coal fired-generators, in the Settlement Payment.

• Korean Chemical Engineering Research
• /
• v.53 no.5
• /
• pp.632-637
• /
• 2015

Mesoporous $TiO_2$ granules were prepared by spray pyrolysis using nano-sized titania particles which were synthesized by a hydrothermal method, and they were evaluated as the photoanode of dye-sensitized solar cells. To enhance the cell efficiency, nanoparticles within granules were chemically interconnected by adding titanium ethoxide (TEOT) to colloidal spray solution. The resulting titania particles had anatase phase without forming rutile. $TiO_2$ granules obtained showed about 400 nm in size, the specific surface area of $74-77m^2/g$, and average pore size of 13-17 nm. The chemical modification of $TiO_2$ granules by adding TEOT initially to the colloidal spray solution was proved to be an effective way in terms of increasing both the light scattering within photoanode and the lifetimes of photo-excited electrons. Consequently, the light-harvesting efficiency of TEOT-modified granules (${\eta}=6.72%$) was enhanced about 14% higher than primitive nanoparticles.

• Current Photovoltaic Research
• /
• v.2 no.1
• /
• pp.36-39
• /
• 2014

Formation mechanism of residual carbon layer, frequently observed in the $CuInSe_2$ (CIS) thin film prepared by direct solution coating routes, was investigated in order to find a way to eliminate it. As a model system, a methanol solution with dissolved Cu and In salts, whose viscosity was adjusted by adding ethylcellulose (EC), was chosen. It was found that a double layer, a top metal ion-derived film and bottom EC-derived layer, formed during an air drying step presumably due to different solubility between metal salts and EC in methanol. Consequently, the top metal ion-derived film acts as a barrier layer inhibiting further thermal decomposition of underlying EC, resulting a formation of bottom carbon residue layer.