• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.516-516
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• 2015

본 연구는 한강유역($2,6018km^2$)을 대상으로 SWAT(Soil and Water Assessment Tool)을 이용하여 지표수와 지하수의 상호작용에 의한 물수지 분석을 수행하고, 수량측면의 유역 건전성을 평가하였다. 유역의 물수지 분석을 위해 한강유역을 표준유역 단위로 구분하고, 기상자료, 하천유량, 다목적댐(소양강댐, 충주댐, 횡성댐) 운영자료, 다기능보(강천보, 여주보, 이포보) 운영자료, 증발산량, 토양수분 자료를 수집하였다. SWAT 모형의 신뢰성 있는 유출량 보정을 위해 한강유역 내 위치하는 다목적댐 및 다기능보의 실측 방류량을 이용하여 댐 운영모의를 고려하였고, 실측 지하수위, 증발산, 토양수분 자료를 이용하여 모형의 보정(2005~2009)과 검증(2010~2014)을 실시하였다. 그 결과 토양수분으로부터 증발산이 발생하고 유출 및 지하수까지 영향을 미치는 물수지 현상을 잘 재현하고 있음을 알 수 있었다. 이후 유역의 수량측면의 건전성 평가를 위한 수문요소로 하천 유출량, 증발산량, 침투, 침루, 기저유출, 토양수분, 지하수 함양량 등을 도출하고 유역의 물순환을 해석하여 유역의 건전성을 평가하였다.

• Economic and Environmental Geology
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• v.41 no.2
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• pp.183-199
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• 2008

This study is focused on characterization of the physio-chemical and mineralogical properties, investigation of their vertical changes in the tailing profile of the Guryoung mining area, classification of the profile into distinct zones, and condition conceptual model of physio-chemical conditions and phases-water relationships controlling the element behaviors in the tailings. The upper part of the groundwater is characterized by the high contents of $Fe_2O_3$ and $SO_3$ for whole rock analysis, low pH, and the occurrence of jarosite, schwertmannite and Fe-oxyhydroxide as the secondary mineral phases. The tailing profile can be divided into the covering soil, jarosite zone, Fe-sulfate zone, Fe-oxyhydroxide and gypsum-bearing pyrite zone, calcite-bearing pyrite zone, soil zone, and weathered zone on the based of the geochemical and mineralogical characteristics. The profile can be sampled into the oxidized zone and the carbonate-rich primary zone with the dramatic changes in pH and the secondary mineral phases. The conceptual model proposed for the tailing profile can be summarized that the oxidation of pyrite is the most important reaction controlling the changes in pH, the dissolution of the primary silicates and carbonates, the precipitation of secondary mineral phases, acid-neutralizing, and heavy metal behaviors through the profile.

• Journal of Korea Soil Environment Society
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• v.1 no.2
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• pp.23-34
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• 1996

The biological magnification of Pb, Cu, Zn and Fe in vascular plant, Persicaria thunbergii, Trapa japonica and Nymphoides peltata natually grown at the river and riverside and relationship between the concentration of heavy metals in these vascular plants and in the soil were investigated in the Chonju river, Chonju city. The biological magnification values of these metals in P thunbergii were founded as follows ; Pb, Cu, Zn and Fe were 80.4~254.6$mu\textrm{g}$/g, 284.6~688.4$mu\textrm{g}$/g, 635.5~1979.4$mu\textrm{g}$/g and 1160.0~3590.9$mu\textrm{g}$/g respectively. In the case of T. japonica, Pb, Cu, Zn and Fe were 107.8~306.0$mu\textrm{g}$/g, 282.7~963.0p$mu\textrm{g}$/g, 1328.3~3546.$mu\textrm{g}$/g and 656.8~9944.0$mu\textrm{g}$/g and in N. peltata, 140.1~ 193.9$mu\textrm{g}$/g, 187.7~327.3$mu\textrm{g}$/g, 1126.6~1723.6$mu\textrm{g}$/g and 611.7~1914.6$mu\textrm{g}$/g respectively. The amount of the biological magnification of heavy metals in the leaf, stem and root of these plants was generally increased in the sequence of leaf

• Korean Journal of Soil Science and Fertilizer
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• v.36 no.3
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• pp.154-162
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• 2003

This study was conducted to investigate the effects of tile drain on Physicochemical properties and crop productivity of soils under plastic film house for three years (1999 - 2001). Tiles (${\Phi}100mm$ PVC pipe) were established at 50-60 cm depth with 1 m, 2 m, and 3 m intervals in Gangseo silt loam soil under 2W-type plastic film house. Cropping system was a pumpkin-pumpkin in the first year, a cucumber-spinach-crown daisy-spinach-young radish in the second year, and a green red pepper-tomato-spinach in last year, with conventional fertilization and drip or furrow irrigation by groundwater pumping. Bulk density and soil hardness of plot with tile drain were lower than those of control (plot without tile drain). Soil water content was also lower in tile drain plot than in control regardless of soil depth, and decreased at narrower interval and longer distance from tile in the same plot, thus suggesting that water flow and density of tile drain plot was higher than those of control. Rhizosphere of spinach, a final crop of third year, was expanded more than 2 cm due probably to improvement of soil physical properties caused by tiles establishment. Electrical conductivity (EC) of topsoil decreased from $1.22dS\;m^{-1}$ to $0.82dS\;m^{-1}$ by tile drain system, and the extent of EC decrease was different with season: higher in spring and lower in summer and autumn. The $NO_{3^-}-N$ concentration in topsoil decreased, from $200mg\;kg^{-1}$ to $39mg\;kg^{-1}$. The effect of tile drain on crop yield varied with crops. Average crop productivity obtained in tile drain plot than that of control crop: 18.2% in 2 m interval, 14.2% in 3 m interval, but lower 0.2% in 1 m interval.

• Journal of the Korean Geotechnical Society
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• v.15 no.5
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• pp.241-257
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• 1999

Subsurface contamination of industrial hazardous organic substances is a serious social issue. Decomposing the hydrophobic organic compounds in the subsurface is technically difficult and the compounds can last as long-term contaminant sources of groundwater once they are sorbed on the soil. Although the danger of contaminated subsurface has long been recognized little was known about the effective remediation technique. Focusing on the remediation of the p-Cresol and 3, 5-Dichlorobiphenyl among subsurface contaminants, this paper studies the surfactant-enhanced desorption technique. Nonionic surfactant(Triton X-100) and anionic surfactant(SDS ) were used as desorbing solvents for extracting organic compound sorbed on soil particles. Sorption characteristics of soils and organic compounds were analyzed and the applications of surfactant solution were studied through batch tests and the flexible-wall permeameter tests. As a result of the sorption isotherm tests, a log-log linear relation was obtained between the linear-partition coefficient, $K_p$ and the octanol-water partition coefficient, $K_{ow}$ of each organic compound. The result of the batch test also showed that Triton X-100 at 0.5% of solution desorbs the 3, 5-Dichlorobiphenyl 28 times more than the water in the batch tests. The surfactant-enhanced subsurface remediation technique becomes more effective when the contaminants are hydrophobic and hard to be decomposed.

• Journal of the Korean Geotechnical Society
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• v.26 no.10
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• pp.61-68
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• 2010

A pilot-scale model test was performed to estimate the availability of new material, Fe-loaded zeolite, as the filling material in permeable reactive barrier (PRB) against the contaminated groundwater with both Cd and Cr(VI). Aquifer was simulated by filling up a large scale soil tank with sands, and mobilizing the water flow by the head difference of water level in both ends of the tank. Then, the mixture of concentrated Cd and Cr(VI) solution was injected into the aquifer to form a contaminant plume, and its behavior through Fe-loaded zeolite barrier was monitored. The test results showed that Fe-loaded zeolite barrier successfully treated the contaminant plume containing both Cd and Cr(VI) and that the immobilized contaminants in the barrier were not desorbed or released. The results indicated that the Fe-loaded zeolite could be a promising material in PRBs against the multiple contaminants with different ionic forms like Cr(VI) and Cd.

• Journal of Soil and Groundwater Environment
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• v.14 no.2
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• pp.33-44
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• 2009

The objective of the study was to develop a hybrid technology integrating biological and physicochemical technologies to efficiently remediate arsenic contaminated lands such as abandoned mine area. The tailing soil samples contaminated with As at a high level were obtained from Songchon abandoned mine, and the content of arsenic and heavy metals as well as physicochemical properties and mineral composition were investigated. In addition, two sets of sequential extraction methods were applied to analyze chemical speciations of arsenic and heavy metals to expect their leachability and mobility in geoenvironment. Based on these geochemical data of arsenic and heavy metal contaminants, column-type experiments on the bioleaching of arsenic were undertaken. Subsequently, experiments on the hybrid process incorporating bioleaching and electrokinetics were accomplished and its removal efficiency of arsenic was compared with that of the individual electrokinetic process. With the results, finally, the feasibilty of the hybrid technnology was evaluated. The arsenic removal efficiencies of the individual electrokinetic process (44 days) and the hybrid process incorporating bioleaching (28 days) and electrokinetics (16 dyas) were measured 57.8% and 64.5%, respectively, when both two processes were operated in an identical condition. On the contrary, the arsenic removal efficiency during the bioleaching process (28 days) appeared relatively lower (11.8%), and the result indicates that the bioleaching process enhanced the efficacy of the electrokinetic process as a result of mobilization of arsenic rather than removed arsenic by itself. In particular, the arsenic removal rate of the electrokinetics integrated with bioleaching was observed over than 2 times larger than that obtained by the electrokinetics alone. From the results of the study, if the bioleaching which is considered a relatively economic process is applied sufficiently prior to electrokinetics, the removal efficiency and rate of arsenic can be significantly improved. Consequently, the study proves the feasibility of the hybrid process integrating both technologies.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.4B
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• pp.337-346
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• 2010

Climate change has a huge impact on various parts of the world. This study quantified and analyzed the effects on hydrological behavior caused by climate, vegetation canopy and land use change of Soyanggang dam watershed (2,694.4 $km^2$) using the semi-distributed model SWAT (Soil Water Assessment Tool). For the 1997-2006 daily dam inflow data, the model was calibrated with the Nash-Sutcliffe model efficiencies between the range of 0.45 and 0.91. For the future climate change projection, three GCMs of MIROC3.2hires, ECHAM5-OM, and HadCM3 were used. The A2, A1B and B1 emission scenarios of IPCC (Intergovernmental Panel on Climate Change) were adopted. The data was corrected for each bias and downscaled by Change Factor (CF) method using 30 years (1977-2006, baseline period) weather data and 20C3M (20th Century Climate Coupled Model). Three periods of data; 2010-2039 (2020s), 2040-2069 (2050s), 2070-2099 (2080s) were prepared for future evaluation. The future annual temperature and precipitation were predicted to change from +2.0 to $+6.3^{\circ}C$ and from -20.4 to 32.3% respectively. Seasonal temperature change increased in all scenarios except for winter period of HadCM3. The precipitation of winter and spring increased while it decreased for summer and fall for all GCMs. Future land use and vegetation canopy condition were predicted by CA-Markov technique and MODIS LAI versus temperature regression respectively. The future hydrological evaluation showed that the annual evapotranspiration increases up to 30.1%, and the groundwater recharge and soil moisture decreases up to 55.4% and 32.4% respectively compared to 2000 condition. Dam inflow was predicted to change from -38.6 to 29.5%. For all scenarios, the fall dam inflow, soil moisture and groundwater recharge were predicted to decrease. The seasonal vapotranspiration was predicted to increase up to 64.2% for all seasons except for HadCM3 winter.

• Korean Journal of Environmental Agriculture
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• v.24 no.3
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• pp.253-260
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• 2005

Salt accumulation in the plastic film house soils under continuous cultivation condition causes problems such as salt damages to plants, nitrate accumulation in vegetables, groundwater contamination, etc. due to excess application of fertilizers. Objective of this research was to find an optimum adsorbent to reduce salt concentration in the soil solution of plastic film house soils, where crop injuries have been observed due to the salt accumulation. The soils were significantly high in available P $(1,431{\sim}6,516mg\;kg^{-1}),\;NO_3-N\;(117.60{\sim}395.73mg\;kg^{-1})$, exchangeable Ca $(4.06{\sim}11.07\;cmol_c\;kg^{-1})$ and Mg $(2.59{\sim}18.76\;cmol_c\;kg^{-1})$, as compared to those of the average upland soils in Korea. Soils were treated with each of adsorbent such as ion-exchange resin, zeolite, rice bran, etc. at 2% level and prepared into saturated-paste samples. After equilibrium, soil solution was vacuum-extracted from the soil and measured for changes of the pH, EC, and concentrations of $Ca^{2+},\;Mg^{2+},\;K^+,\;Na^+,\;{NH_4}^+,\;{PO_4}^{3-}\;and\;{NO_3}^-$. Rice bran effectively removed ${PO_4}^{3-}\;and\;{NO_3}^-$ in the soil solution up to 100%. Efficiency was decreased in the orders of rice bran > ion-exchange resin > zeolite. Removal efficiencies of zeolite and ion-exchange resin for $Ca^{2+}$ were ranged from 1 to 65% and from 7 to 61%, respectively. Ion-exchange resin was also effective for removing $Mg^{2+},\;K^+,\;Na^+,\;and\;{NH_4}^+$. Overall results demonstrated that rice bran and ion-exchange resin could be applicable for salt accumulated soil to remove the respective anion and cation.

• Korean Journal of Environmental Agriculture
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• v.20 no.4
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• pp.262-268
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• 2001

This study was conducted to investigate the effect of rice farming on seasonal, regional quality of shallow ground water. Ammonium $(NH_4\;^+)$ concentration of paddy soil was found to be the highest in April. Nitrate $(NO_3\;^-)$ concentration of soil and the ground water was determined to be lower during the growing period, May to August than any other periods. Seasonal change of K concentration in soils was shown to be in the tendency similar to that of $NH_4\;^+$. However, $Cl^-$ concentration of soils and the ground water was not changed significantly. $NH_4\;^+$, $NO_3\;^-$, K and $Cl^-$ concentration in W-3 ground water was higher than those of W-1 and W-2. It was clear that nutrients ($NH_4\;^+$, $NO_3\;^-$, K, $Cl^-$) should be leached from the adjacent soil to W-3 ground water by water stream. From this study it is apparent that nutrients can be easily leaching from sandy soils and transported into ground water, but rice plant farming is not non point source of groundwater pollution.