• Journal of the Korean Ceramic Society
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• v.47 no.2
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• pp.117-121
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• 2010

$SnO_2-(1-x)P_2O_5-xB_2O_3$ glass system were prepared by melt-quenching technique in the compositional series containing 50, 55 and 60 mol% of $SnO_2$. Local structure of the glasses was investigated by Raman and FT-IR measurements. A large glass-forming region was found at the phosphate side of the ternary system with homogeneous glasses containing up to 5~25 mol% of $B_2O_3$. According as content of $B_2O_3$ increases, theraml expansion coefficient of glass decreased but transition temperature and softening temperature increased. Because these phenomenon changed local structure of glass. According as content of $B_2O_3$ increases, quantity of bridging oxygen increased. Also, according as content of $SnO_2$ increases, confirmed that quantity of non-bridging oxygen increases.

• Journal of the Korean Ceramic Society
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• v.39 no.2
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• pp.194-198
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• 2002

Various composition of $K_2O{\cdot}CaO{\cdot}P_2O_5$ glasses were studied by melting process to identify glass forming region. Thermal properties were observed by DSC and TG-DTA, structural properties were investigated by FT-IR and Raman Spectroscopy. The glass transition temperature (Tg) and softening temperature (Ts) were decreased with increasing $K_2O\;and\;P_2O_5$ contents. The basic structural unit of phosphate glasses is the $PO_2\;and\;PO_4^{3-}$ groups to make a cross-link and P-O-P group to form skeleton structure. As CaO content was increased, the P-O-P field strength in these glass was increased and intensity of $PO_2\;and\;PO_4^{3-}$ stretch was decreased.

• Transactions on Electrical and Electronic Materials
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• v.8 no.1
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• pp.5-10
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• 2007

Using a reference slurry, ammonium dodecyl sulfate (ADS), an anionic and environmentally friendly surfactant, was investigated as an alternative to BTA for its inhibition and lubrication characteristics. Results demonstrated that the inhibition efficiency of ADS was superior to that of BTA. Coefficient of friction (COF) was the lowest when the slurry contained ADS. This suggested that adsorbed ADS on the surface provided lubricating action thereby reducing the wear between the contacting surfaces. Temperature results were consistent with the COF and removal rate data. ADS showed the lowest temperature rise again confirming the softening effect of the adsorbed surfactant layer and less energy dissipation due to friction. Spectral analysis of shear force showed that increasing the pad-wafer sliding velocity at constant wafer pressure shifted the high frequency spectral peaks to lower frequencies while increasing the variance of the frictional force. Addition of ADS reduced the fluctuating component of the shear force and the extent of the pre-existing stick-slip phenomena caused by the kinematics of the process and collision event between pad asperities with the wafer. By contrast, in the case of BTA, there were no such observed benefits but instead undesirable effects were seen at some polishing conditions. This work underscored the importance of real-time force spectroscopy in elucidating the adsorption, lubrication and inhibition of additives in slurries in CMP.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.321-321
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• 2008

To obtaingood resolution in PDP, one of the important factors is to achieve the accuracy of barrier ribs. The photolithographic process can be used to form patterns of barrier rib with high accuracy and a high aspect ratio. The composition for photolithography is based on the $B_2O_3-SiO_2-Al_2O_3$ glass system including additives such as alkali oxides and alkali earth oxides. The refractive index and thermal properties in glass system are changed by amount of alkali oxides and alkali earth oxides. Therefore, it is important that additives are controlled to have proper refractive index and thermal properties. The additives are contributed to non-bridging oxygen within the glass network, causing a change of density. In addition to a change of the structural cross-link density, the refractive index, dielectric and thermal properties glass are correlated with ionic radius and polarizability of cations. In this study, we investigated the refractive index and the thermal properties such as glass transition temperature, glass softening temperature and coefficient of thermal expansion by changing composition in the $B_2O_3-SiO_2-Al_2O_3$ glass system.

• Journal of Advanced Marine Engineering and Technology
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• v.33 no.7
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• pp.1026-1033
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• 2009

Fine ceramics have high strength, excellent wear resistance, chemical stability and high strength at high temperature and are receiving attention in various fields such as construction, engineering, aerospace and marine science. Finish machining process is required to obtain precise ceramics components because sintering process necessary for obtaining high strength and high quality ceramics reduces the dimensions of components and precision of shape. But high strength and brittleness of ceramics materials cause difficulty in processing. So a process for obtaining wanted dimensions is studying using high temperature which makes ceramics softened and thermal affected recently. Laser beam is a very useful optical device for these kinds of processes. Laser process such as laser cutting, laser machining, laser heat treatment and laser-assisted machining(LAM) is researching to manufacture practical ceramics components using intense laser source which can cause local softening and damage of workpiece. In this paper, microstructural and mechanical properties of silicon nitride heated are studied as a basic study for researching of ceramics process by laser beam. The surface variation of HIP and SSN-silicon nitride was analyzed with SEM and EDS. A processing at $1,300^{\circ}C$ or above causes N element to combine into $N_2$ gas and the gas busts from surface. These phenomena make bloat, craters and heat defects on the surface of silicon nitride. Also, oxygen content is largely increased to oxidize the surface and it causes changing of phases and reducing of hardness of surface.

• Proceedings of the KWS Conference
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• 2010.05a
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• pp.18-18
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• 2010

최근에 건조되는 선박이나 구조물들은 점차 대형화 되어가고, 이에 사용되는 판재들은 점차 고강도 극후판재화 되어가고 있다. 극후판재의 용접성을 향상시키기 위해서는 대입열 용접이 주로 적용되고 있는 실정인데, 30 mmt 이상의 후판을 1 pass로 용접하기 위해서는 EGW(Electro-gas welding) 기법을 사용한다. 대입열 용접은 용접입열(heat input)이 매우 높아 용착금속과 열영향부의 냉각속도가 매우 느려 용접열영향부에서 특히 fusion line 근처의 열영향부는 결정립 조대화 및 취약한 미세조직을 형성함으로서 저온인성을 크게 저하시키고, 연화 현상(softening effect)을 발생시켜 강도가 저하되는 문제점이 주로 발생하였다. 하지만 이런 문제점을 해결하기 위해 대입열용접에 사용된는 강재의 미세조직을 제어하여 AlN, TiN, $TiO_2$ 등의 석출물을 이용한 용접열영향부의 저온인성을 향상시켰다. 이러한 문제점이 발생하는 대입열용접에서 저온인성 시험은 주로 fuison line + 1, 2mm에서 수행한다. 하지만 대입열 용접시 용착금속의 냉각속도도 매우 느리기 때문에 용착금속의 위치에 따라 저온 인성 특성이 다르게 나타날 수 있다. 본 연구에서는 EGW 용착금속의 위치에 따른 저온인성 특성을 평가하기 위해 EH-36N, 40mmt 판재를 사용하여 1pole EG 용접 하였다. 용착금속의 저온인성 특성을 평가하기위해 충격 시편의 노치 위치가 fusion line - 2mm와 용접부 중앙을 기준으로 4곳을 선정하여 충격시험을 수행하였다. 또한 용착금속의 경도 분포를 알아보기 위해 micro vickers hardness tester(mitutoyo UR-501)을 사용해 hardness mapping 시험을 하였다. 용착금속의 저온인성은 미세조직과, 산소량에 따라 변화 할 수 있기 때문에 용착금속 위치를 달리하여 미세조직과 산소량도 각각 분석하였다. 용착금속의 저온인성을 향상시킬 수 있는 침상형페라이트와 비금속개재물의 상관관계에 관해 검토 하였다.

• Journal of the Korean Ceramic Society
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• v.43 no.6 s.289
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• pp.338-343
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• 2006

The effects of lead-borosilicate glass frits on the sintering behavior and microwave dielectric properties of ceramic-glass composites were investigated as functions of glass composition of glass addition ($10{\sim}50vol%$), softening point (Ts) of the glass, and sintering temperature of the composites ($500{\sim}900^{\circ}C$ for 2 h). The addition of 50 vol% glass ensured successful sintering below $900^{\circ}C$. Sintering characteristics of the composites were well described in terms of Ts. PbO addition in to the glass enhanced the reaction with $Al_{2}O_3$ to form liquid phase and $PbAl_{2}Si_{2}O_8$, which was responsible to lower Ts. Dielectric constant(${\epsilon}_r$), $Q{\times}f_0$ and temperature coefficient of resonant frequency (${\tau}_f$) of the composite with 50 vol% glass contents ($B_{2}O_{3}:PbO:SiO_{2}:CaO:Al_{2}O_3$ = 5:40:45:5:5) demonstrated 8.5, 6,000 GHz, $-70\;ppm/^{\circ}C$, respectively, which is applicable to substrate requiring a low dielectric constant. When the same glass composition was applied sinter $MgTiO_3\;and\;TiO_2,\;at\;900^{\circ}C$ (50 vol% glass in total), the properties were 23.8, 4,000 GHz, $-65ppm/^{\circ}C$ and 31.1, 2,500 GHz, $+80ppm/^{\circ}C$ respectively, which is applicable to filter requiring an intermidiate dielectric constant.

• Journal of the Korean Ceramic Society
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• v.13 no.1
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• pp.30-34
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• 1976

In general the chemical composition of glass ceramics in Li2O-Al2O3-SiO2 system is similar to the composition of $\beta$-spodumene (Li2O-Al2O3-4SiO2). With the object to manufacture the glass ceramics which can be produced in the domestic pot the composition of glass was so settled at 1.0 Li2O.0.9Al2O3.6.0SiO2 in order to reduce the contents of Li2O, to prevent the corrosion of the pot and to decrease the cost of raw materials. 0.2 mole and 0.1 mole of the mixture of TiO2 and ZrO2 as nucleants were added to the basic composition of 1.0 Li2O-0.9Al2O3-6.0SiO2. Each sample was divided into two kinds with a TiO2/ZrO2 ratio of 2 to 1 and the other with a TiO2/ZrO2 ratio fo 1 to 1. Thermal expansion coefficient, the most important property of glass ceramics, was tested. The softening point and the melting point of the samples were observed by the use of a heating microscope. The results obtained were as follows. The manufacturing of glass ceramics seems to be possible in the industrial plant using the domestic pot. 1) The composition of the glass which can be melted in the domestic pot process was near 1.0 Li2O.0.9Al2O3.6.0SiO2. 2) The temperature range of crystal creation and crystal growth was between 850-94$0^{\circ}C$, and 5 hours holding the samples at the temperature range was enough to crystallize them. The major crystal was $\beta$-spdumene and there existed petalite partialy. 3) The thermal expansion coefficient fo the crystallized glass was negative. 4) The deforming point of the crystallized glass was 1435$^{\circ}C$.

• Journal of the Korean Ceramic Society
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• v.51 no.3
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• pp.170-176
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• 2014

Effective glass frit compositions enabled to absorb laser energy, and to seal a commercial dye-sensitized solar-cell-panel substrate were developed by using $V_2O_5$-based glasses with various amounts of $TeO_2$ substitution. The latter was intended to increase the lifetime of the solar cells. Substitution of $V_2O_5$ by $TeO_2$ provided a strong network structure for the glasses via the formation of tetrahedral pyramids in the glass, and changed the various glass properties, such as glass transition temperature ($T_g$), dilatometric softening point ($T_d$), crystallization temperature, coefficient of thermal expansion (CTE), and glass flowage without any detrimental effect on the laser absorption property of the glasses. The thermal expansion mismatch (${\Delta}{\alpha}$) between the glass frit and the substrate could be controlled within less than ${\pm}5%$ by addition of 10 wt% of ${\beta}$-eucryptite. An 810 nm diode laser was used for the sealing test. The laser sealing test revealed that the VZBT20 glass frit with 10 wt% ${\beta}$-eucryptite was successfully sealed the substrates without interfacial cracks and pores. The optimum sealing conditions were provided by a beam size of 3 mm, laser power of 40 watt, scan speed of 300 mm/s, and 200 irradiation cycles.

• Journal of Advanced Marine Engineering and Technology
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• v.24 no.6
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• pp.70-77
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• 2000

In this paper, the effect of solution and age heat treatment to the corrosion behavior for the Ti-6Al-4V alloy were studied by cyclic polarization methods. Ti-6Al-4V was solution heat treated at $1,066^{\circ}C$ and $966^{\circ}C$ for 5 hours, and followed by age heat treated at $650^{\circ}C$, $600^{\circ}C$ and $550^{\circ}C$ with 1, 2, 4, 8 and 16 hours under vacuum environment. Test solution was 3.5% NaCl with temperature $25^{\circ}C$. The obtained results were as follows: 1. Base metal was exhibited higher electrical charge than that of solution and aged material. With decrease of solution-treatment temperature from 1066 to $966^{\circ}C$, the electrical charge was increased due to softening of micro structure. 2. The corrosion resistance of specimen that solution treated at $966^{\circ}C$ for 5 hours and age heat treated at 650, 660 and $550^{\circ}C$ were increased with increase of aging time to 4, 8 and 16 hours respectively, and then decreased. 3. In case of 316L stainless steel, measured charge and corrosion potential was 0.0627 coulomb and -614 mV respectively. Corrosion resistance of Ti-6Al-4V was higher than that of 316L.