• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.3
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• pp.310-316
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• 2020

In this study, the stability and EMP shielding performance of metal-based industrial by-products aggregates with excellent conductivity and easy procurement to be used as concrete aggregates for EMP shielding are evaluated. The industrial by-products are electronic-arc-furnace oxidizing slag, copper smelting slag, and ferro-moldibdenum. The composition analysis of aggregates and aggregate stability are evaluated. As a result of the experiment, ferro-moldibdenum is shown to have l ow stability as an aggregate due to its high Free-CaO. The remaining aggregates are evaluated to be safe to use as aggregates for concrete. In addition, industrial by-products aggreagate-specimens excluding ferro-moldibdenum are shown higher compressive strength than the plain specimen. The recycle aggregates, electronic-arc-furnace oxidizing slag and copper smelting slag, are shown excellent EMP shielding performance, the EMP shielding performance is expected to increase if the average particle diameter of the aggregate is small or evenly distributed.

• Resources Recycling
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• v.28 no.3
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• pp.59-67
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• 2019

This study was conducted to fabrication pig iron containing copper and to reduce sulfur content pig iron. Roasting test was conducted for 1 ~ 9 hours at each temperature of $500^{\circ}C$, $700^{\circ}C$, and $900^{\circ}C$. In addition, the effect of oxygen partial pressure with 0.5, 0.8, and 1 atm was carried out for 30 minutes at $900^{\circ}C$. It was found that there is no effect to reduce sulfure in pig iron through roasting and oxygen partial pressures. The addition of CaO with 15 wt.% was found to reduce sulfur content up to 0.001 wt.%. The suitable temperature and reactive time for carbothermic reduction were $1600^{\circ}C$ and 30 minutes which shows the highest recovery rate of iron from the copper slag.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2004.05a
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• pp.53-58
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• 2004

동제련 공정중 고품질의 전기동을 효율적으로 생산하기 위해서는 Anode중에 적정량의 비소(As)가 필요하다. 그러나 Cu가 약30% 함유되어 있는 동정광에 함유된 비소는 Smelting Furnace 용련과정에서 비소 특성상 약 70%가 Offgas로 휘발되어 황산공장으로 유입 처리되고, 나머지 30%만 아노드(Anode)로 유입되므로 별도로 전련공정에서 발생된 Cu-Cement(비소 함유)를 정제로에 Recycle 하고 있으며, 부족시 추가로 비소 Source를 구입하여 정제로에 투입하고 있다. 이를 효과적으로 해결하기 위하여 현재 위탁처리를 하고있는 As가 함유된 폐수처리 2차 중화시 발생된 2차 Cake 60W.T/D중 30W.T/D를 기존 Converter Slag 건조용 Rotary Dryer를 이용하여 Converter Furnace에 Recycle 함으로써 전련 Anode에 필요한 비소를 공급하고, 또한 2차 Cake에 혼입되어 있는 CaO 활용으로 부재료 절감, 유가금속(Cu등) 회수등 및 2차 Cake 위탁처리비용을 절감하며, Cu-Cement는 Smelting Furnace에 투입하여 정제로 투입시 발생되는 문제점들을 동시에 해결코자 한다.

• Journal of the Korean Geotechnical Society
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• v.18 no.5
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• pp.195-207
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• 2002

The domestic, quantity of copper slag as a by-product at copper smelting process reaches 700,000 tons annually while its application is limited. Therefore, the secure disposal plan of copper slag is urgently required. For this reason, in this study, copper slag was used as a substitute for sand in Sand Compaction Pile that is one of the improvement methods of soft ground because the particle size distribution of copper slag ranges from 0.15mm to 5m(coarse state) and it maintains stable glassy state environmentally. The geotechnical characteristics of copper slag were evaluated through laboratory model tests and the field application of copper slag was compared with generally used sand by pilot tests. From these experimental results, copper slag's material characteristics, bearing capacity, settlement reduction and improvement effects of surrounding ground were found to be superior to generally used sand. The copper slag can be used as a substitute far sand in the Sand Compaction Pile method and as recycling material of industrial by-product with high econonical and environmental value when natural resources are being exhausted.

• Journal of Conservation Science
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• v.29 no.2
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• pp.139-147
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• 2013

This study focused on iron making related information through analyzing slags and furnace wall collected from iron production site of Suryong-ri Wonmorongi, Chungju. Total Fe content of slags were from 36.98% to 44.47% and this range was general recovery rate of iron in ancient. Compounds of calcium included slags was supposed to add intentionally during smelting process as deoxidation agent in order that these helped to separate iron from impurities. Furnace wall didn't make of high alumina clay because of low $Al_2O_3$. Microstructure and main components of slags show that No. 1 to 3 slags with fayalite and wustite were products of iron ore smelting. However, No.4 slag is more likely to smelt by iron sand because of ulvospinel with $TiO_2$ in No. 4 slag. Therefore, iron ore were not only used but iron sand in smelting and furnace wall made of general clay with low $Al_2O_3$ content in this area.

• Journal of Conservation Science
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• v.31 no.4
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• pp.411-427
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• 2015

The purpose of the present study is to examine the objects excavated from the archaeological site of the Nogye Village in terms of their relationships with the iron production facilities such as 1ho smithing hearth and 2ho smelting furnace. 32 samples including slags, iron ores, and wall were analyzed to identify the mineralogical and chemical characterization. In addition, in the case of the 1ho smithing hearth slag, differing points of the cross-section were analyzed to examine its formation in depth. The analysis results suggest that the slags from the each site adjacent to the 1ho smithing hearth and 2ho furnace are related to smithing and smelting process respectively. Furthermore, it is possible to draw some conclusions that the aspects of the increased contents of nonferrous elements such as CaO in the slags in comparison with those of the iron ores are due to various factors such as charcoal ash and analytical reasons rather than an addition of CaO as flux.

• Korean Journal of Heritage: History & Science
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• v.48 no.4
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• pp.138-153
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• 2015

A Jincheon Seokjangri B23 furnace was reconstructed and iron smelting experiment was performed to investigate an ancient Baekjae iron production process. The work mainly described in this paper is the $1^{st}$ and $2^{nd}$ experiments among the several experiments carried out at Jungwon National Research Institute of Cultural Heritage. Iron ore(magnetite) and oak charcoal were used as a source and a foot bellow was used for air supply. Common results of the experiments are masses of iron, slag and charcoal formed in the furnace. Most iron lumps were formed nearby the tuyere rather than the area of tapping hole. Metallographic and chemical analysis shows that the iron lumps can be used for either forge or cast depending on their carbon content. Low Fe content and glassy texture of the inner slags suggest that the operation environment was quite reducing. Based on the results of the iron smelting experiments, measurements and analysis, various information was obtained regarding physical-chemical and metallurgical processes of the ancient iron smelting process. It is firmly believed that its undisclosed contents can be revealed more in depth with continual reconstitution experiments.

• Economic and Environmental Geology
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• v.56 no.4
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• pp.475-499
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• 2023

To infer the provenance of raw iron materials utilized in iron production at the archaeological sites in Gyeongsang province, petrographic and geochemical analyses were conducted for smelting samples and major iron ores sourced from ore deposits. The smelting samples excavated from various iron archaeological sites were classified into different types according to their refining processes, such as iron bloom, iron bloom slag, pig iron, pig iron slag, forging iron flake, smithery iron, iron flake, and arrowhead. These samples exhibited discernable differences in their mineralogical components and texture. The enrichments of major elements such as aluminum and calcium in silicate minerals of the residual slags and the high contents of trace elements such as nickel and copper in some iron-making relics reflect the characteristics of raw iron ores, and thus can be regarded as potential indicators for inferring the provenance of source materials. In particular, the compositional ranges of Pb-Sr isotope ratios for the iron smelting samples were classified into three categories: 1) those exhibiting similar ratios to those of the raw iron ores, 2) those enriched in strontium isotope ratio, and 3) those enriched in both lead and strontium isotope ratios. The observed distinct Pb-Sr isotope characteristics in the iron smelting samples suggest the potential contribution of specific additives being introduced during the high-temperature refining process. These results provide a new perspective on the interpretation of the provenance study of the iron archaeological samples in Gyeongsang province, particularly in terms of the potential contribution of additives on the refining process.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.8
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• pp.338-343
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• 2017

In this study, blast furnace slag powder was used in concrete to help reduce carbon dioxide emissions and to recycle industrial waste. Blast furnace slag powder is a byproduct of smelting pig iron and is obtained by rapidly cooling molten high-temperature blast furnace slag. The powder has been used as an admixture for cement and concrete because of its high reactivity. Using fine blast furnace slag powders in concrete can reduce hydration heat, suppress temperature increases, improve long-term strength, improve durability by increasing watertightness, and inhibit corrosion of reinforcing bars by limiting chloride ion penetration. However, it has not been used much due to its low compressive strength at an early age. Therefore, this study evaluates the effects of steam curing for increasing the initial strength development of concrete made using slag powder. The relationship between compressive strength, SEM observations, and XRD measurements was also investigated. The concrete made with 30% powder showed the best performance. The steam curing seems to affect the compressive strength by destroying the coating on the powder and by producing hydrates such as ettringite and Calcium-Silicate-Hydrate gel.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.319-323
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• 2018

Ferronickel slag is a by-product from the ferronickel smelting process and it is divided into air-cooled ferronickel slag and water granulated ferronickel slag according to cooling system. The purpose of this experimental resesrch is to investigate the mechanical properties and resistance to freezing and thawing of concrete using air-cooled ferronickel slag(ACFNS) fine aggregate. For this purpose, the concrete specimens with water-cement ratio of 50% were made with ACFNS's replacement ratios of 0%, 20%, 30%, 40%, 50%, 70%, and 100% by volume of fine aggregate. It was observed from the test results that the compressive strength and static modulus of elasticity of ACFNS fine aggregate concrete were increased with increasing replacement ratio of ACFNS and the resistance to freezing and thawing of this was similar to reference concrete which had the relative dynamic modulus of elasticity of more than 90% during the freezing and thawing of 300 cycles.