• Title/Summary/Keyword: Slurry temperature

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Enhancement of Ethanol Production via Hyper Thermal Acid Hydrolysis and Co-Fermentation Using Waste Seaweed from Gwangalli Beach, Busan, Korea

  • Sunwoo, In Yung;Nguyen, Trung Hau;Sukwong, Pailin;Jeong, Gwi-Teak;Kim, Sung-Koo
    • Journal of Microbiology and Biotechnology
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    • v.28 no.3
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    • pp.401-408
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    • 2018
  • The waste seaweed from Gwangalli beach, Busan, Korea was utilized as biomass for ethanol production. Sagassum fulvellum (brown seaweed, Mojaban in Korean name) comprised 72% of the biomass. The optimal hyper thermal acid hydrolysis conditions were obtained as 8% slurry contents, 138 mM sulfuric acid, and $160^{\circ}C$ of treatment temperature for 10 min with a low content of inhibitory compounds. To obtain more monosaccharides, enzymatic saccharification was carried out with Viscozyme L for 48 h. After pretreatment, 34 g/l of monosaccharides were obtained. Pichia stipitis and Pichia angophorae were selected as optimal co-fermentation yeasts to convert all of the monosaccharides in the hydrolysate to ethanol. Co-fermentation was carried out with various inoculum ratios of P. stipitis and P. angophorae. The maximum ethanol concentration of 16.0 g/l was produced using P. stipitis and P. angophorae in a 3:1 inoculum ratio, with an ethanol yield of 0.47 in 72 h. Ethanol fermentation using yeast co-culture may offer an efficient disposal method for waste seaweed while enhancing the utilization of monosaccharides and production of ethanol.

Anaerobic/oxic Treatment of Slurry-type Swine Waste

  • Won, Chul-Hee;Rim, Jay-Myoung
    • Environmental Engineering Research
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    • v.13 no.4
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    • pp.203-209
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    • 2008
  • This paper presents the experimental results in five months operation from a combined anaerobic/oxic system treating swine waste with average concentrations in organic matter and nitrogen of 7,930 mgCOD/L and 671 mgTKN/L, respectively. The system was formed using an upflow anaerobic sludge blanket (UASB) reactor and oxic reactor connected in series with a recycling line of oxic effluents to UASB for its denitrification. The UASB reactor was operated at an organic volumetric loading rate (VLR) of $2.1{\sim}4.5\;kgTCOD/m^3$/day and the removal efficiency of TCOD was $66.3{\sim}85.4%$. The overall removal efficiency of TCOD was more than 99%. The oxic reactor was operated at a nitrogen VLR of $0.10{\sim}0.20\;kgTKN/m^3$/day and the nitrification efficiency was 75%. However, the complete denitrification was observed in the UASB reactor that was due to the optimal temperature and sufficient carbon source. The overall removal rate of TN was about 80%. About 76.2% of the influent COD mass was accountable in a COD mass balance at a level of VLR $3.64\;kgCOD/m^3$/day. The production rate of methane was $0.32\;LCH_4/gCOD_{removed}$ when influent organics, VLR, were recorded by $3.4{\sim}4.5\;kgCOD/m^3$/day.

Effect of Solidification Condition of Sublimable Vehicles on the Pore Characteristics in Freeze Drying Process (동결건조 공정에서 동결제의 응고조건이 기공특성에 미치는 영향)

  • Suk, Myung-Jin;Kim, Ji Soon;Oh, Sung-Tag
    • Journal of Powder Materials
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    • v.21 no.5
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    • pp.366-370
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    • 2014
  • The present study demonstrates the effect of solidification condition on the pore structure in freeze drying process using the slurries of CuO/sublimable vehicles. Camphene and Camphor-45 wt% naphthalene based slurries with 14 vol% CuO powder were frozen into a mold at $-25^{\circ}C$, followed by sublimation at room temperature. The green bodies were hydrogen-reduced and sintered at $500^{\circ}C$ for 1 h. The porous Cu specimen, frozen the CuO/camphene slurry into the heated mold of the upper part, showed large pores with unidirectional pore channels and small pores in their internal wall. Also, it was observed that the size of large pores was decreasing near the bottom part of specimen. The change of pore structure depending on the freezing condition was explained by the nucleation behavior of camphene crystals and rearrangement of solid powders during solidification. In case of porous Cu prepared from CuO/Camphor-naphthalene system, the pore structure exhibited plate shape as a replica of the original structure of crystallized vehicles with hypereutectic composition.

Shaping and Sintering of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$ System powders by Slurry Process (Slurr법에 의한 $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$계 미분말의 성형과 소결성)

  • 김복희;최석홍
    • Journal of the Korean Ceramic Society
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    • v.33 no.11
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    • pp.1267-1275
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    • 1996
  • Green sheet was prepared by tape casting in the composition of (1-x)Pb(Mg1/3Nb2/3)O3-PbTiO3 system using Pb(Mg1/3Nb2/3)O3 and PbTiO3 synthesized with PbO, Nb2O5 MgO and TiO2 The densest green sheet was obtained in the weight ratio 70:30 of powder to binder. Green sheet wasmultilayered in metal mould and formed into lamination at 7$0^{\circ}C$, 300kg/cm2 The lamination was sintered at 110$0^{\circ}C$ 2hr, Dielectric constant and Curie temperature of disc type sintered body was highered with increasing the amount of PbTiO3 and was in the range of 19000-21000, -7~45$^{\circ}C$ respectively. Green and sintered relative density of lamination was 61% and 95% respectively.

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Development of a Pad Conditioning Method for ILD CMP using a High Pressure Micro Jet System

  • Lee, Hyo-Sang;DeNardis, Darren;Philipossian, Ara;Seike, Yoshiyuki;Takaoka, Mineo;Miyachi, Keiji;Doi, Toshiro
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.1
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    • pp.26-31
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    • 2007
  • The goal of this study is to determine if High Pressure Micro Jet (HPMJ) conditioning can be used as a substitute for, or in conjunction with, conventional diamond pad conditioning. Five conditioning methods were studied during which 50 ILD wafers were polished successively in a 100-mm scaled polisher and removal rate (RR), coefficient of friction (COF), pad flattening ratio (PFR) and scanning electron microscopy (SEM) measurements were obtained. Results indicated that PFR increased rapidly, and COF and removal rate decreased significantly, when conditioning was not employed. With diamond conditioning, both removal rate and COF were stable from wafer to wafer, and low PFR values were observed. SEM images indicated that clean grooves could be achieved by HPMJ pad conditioning, suggesting that HPMJ may have the potential to reduce micro scratches and defects caused by slurry abrasive particle residues inside grooves. Regardless of different pad conditioning methods, a linear correlation was observed between temperature, COF and removal rate, while an inverse relationship was seen between COF and PFR.

The Effect of Pad Groove Density on CMP Characteristics (패드 그루브의 밀도변화가 연마특성에 미치는 영향)

  • Park Kihyun;Jung Jaewoo;Lee Hyunseop;Seo Heondeok;Jeong Seokhun;Lee Sangjik;Jeong Haedo
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.8 s.173
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    • pp.27-33
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    • 2005
  • Polishing pads play an important role in chemical mechanical polishing(CMP) which has recently been recognized at the most effective method to achieve global planarization. In this paper, we have investigated CMP characteristics as a change of groove density of polishing pads. The parameter $(K_n)$ is proposed to estimate groove density of pad. The $K_n$ is defined as groove area divided by pitch area. As the groove density value increased, removal rate increased to some point and then gradually saturated in case of increasing the groove density excessively. In addition Within wafer non-uniformity(WIWNU) worse as groove density increased excessively, although WIWNU improved as groove density increased. Also the uniformity of temperature of pad surface decreased as the groove density increased. It was because that the cooling effect increased as groove density increased. In other words, increasing the groove density which means the apparent contact area of pad has influence on amount of discharge of slurry during polishing process.

Composting Characteristics of a Continuous Aerated Pilot-scale Reactor Vessel for Commercial Composting (상업용 퇴비화를 위한 연속 통기식 파이로트 규모 반응조의 퇴비화 특성)

  • 홍지형;최병민
    • Journal of Animal Environmental Science
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    • v.4 no.2
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    • pp.149-160
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    • 1998
  • Hog manure slurry amended with sawdust was composted in pilot-scale reactor vessels using continuous aeration nuder different C/N ratios and pH conditions during composting high rate (decomposition) process. For each material two replicated piles were built and monitored over a period of three weeks. The compost piles had an initial volume of 0.18 ㎥. In this study we evaluated the temperature in compost O2 and CO2 evolution, aeration rate, NH3 concentration etc. and investigated the stability of compost during composting high rate process. According to measured results, while the maximum NH3 concentration during composting high rate process. According to measured results, while the maximum NH3 concentration during composting high rate was in the range of 213 to 412 ppm on 5th day which was near the optimum C/N(22∼24) and pH(7.5∼7.9). And then, the NH3 concentration reduced to between 22∼26 ppm by 13th day. The maximum NH3 concentration for the lower C/N(18∼19) and pH value of 6 reached 574∼1,063 ppm by the 16th through 11th days and the NH3 concentration during continuous aerated composting high rate process, it was more important to manage NH3 gas so that compost odor is reduced.

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Selective Oxidation of Hydrogen Sulfide to Elemental Sulfur with Fe/MgO Catalysts in a Slurry Reactor

  • Lee, Eun-Ku;Jung, Kwang-Deog;Joo, Oh-Shim;Shul, Yong-Gun
    • Bulletin of the Korean Chemical Society
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    • v.26 no.2
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    • pp.281-284
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    • 2005
  • The Fe/MgO catalysts with different Fe loadings (1, 4, 6, 15 and 30 wt% Fe) were prepared by a wet impregnation with iron nitrate as precursor. All of the catalysts were characterized by BET surface analyzer, X-ray diffraction (XRD), temperature-programmed reduction (TPR), and X-ray photoelectron spectroscopy (XPS). The maximum removal capacity of $H_2S$ was obtained with 15 wt% Fe/MgO catalyst which had the highest BET surface area among the measured catalysts. XRD of Fe/MgO catalysts showed that well dispersed Fe particles could be present on Fe/MgO with Fe loadings below 15 wt%. The crystallites of bulk $\alpha$-$Fe_2O_3$ became evident on 30 wt% Fe/MgO, which were confirmed by XRD. TPR profiles showed that the reducibility of Fe/MgO was strongly related to the loaded amounts of Fe on MgO support. Therefore, the highest removal efficiency of $H_2S$ in wet oxidation could be ascribed to a good dispersion and high reducibility of Fe/MgO catalyst. XPS studies indicated that the $H_2S$ oxidation with Fe/MgO could proceed via the redox mechanism ($Fe^{3+}\;{\leftrightarrow}\;Fe^{2+}$).

Case Study on Seepage Analysis and Countermeasure Against the Seepage Flow of In-ground LNG Storage Tank (LNG 지하저장탱크의 침투해석 및 용수 대책공법에 대한 사례분석)

  • 신은철;오영인;이상혁
    • Proceedings of the Korean Geotechical Society Conference
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    • 2001.03a
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    • pp.65-72
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    • 2001
  • Since Pyoungtaek thermal power plant began using natural gas in 1986, the annual using volume has rapidly increased and reached 12.7 million tons in 1999. When the natural gas is cooled to a temperature of approximately -162$^{\circ}$C at atmospheric pressure, it condenses to a liquid called liquefied natural gas(LNG). LNG has a special characters such as odorless, colorless, non-corrosive, and non-toxic. So, LNG storage tank, tanker ship, transfer pipelines are required the special storage and transportation systems and technology. The presently operating LNG terminals are Pyongtaek and Inchon terminals. A total of 19 above-ground LNG storage tanks(100 thousand ㎘ grade) are currently in operation with a sendout capacity of 4,360tons/hour. To meet the growing domestic demand of LNG supply, the Inchon receiving terminal is expanding(six in-ground tank) and constructing a third LNG terminal at Tongyong. In this paper, case study on seepage analysis and countermeasure against increasing the seepage volume of in-ground LNG storage tank excavation work is reported. The results of an additional seepage analysis are presented to verify the design seepage volume of assumption section and seepage volume after curtain-grouting in the slurry wall.

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Microstructure and Characteristic of Rheocast Al-6.2wt%Si Alloy (Al-6.2wt%Si합금의 리오캐스트 조직과 특성)

  • Lee, Jung-Il;Park, Ji-Ho;Lee, Ho-In;Kim, Moon-Il
    • Journal of Korea Foundry Society
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    • v.14 no.5
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    • pp.438-446
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    • 1994
  • The effect of various thermomechanical treatments on the structure and rheological behaviour of Al-6.2wt%Si alloy in its solidification range were investigated using a Searle type high temperature viscometer. During continuous cooling, the viscosity increases gradually with increasing fraction of solidified alloy, until a critical fraction of solidified alloy is reached above which the viscosity sharply increases. The viscosity of the slurry, at a given volume fraction wolid, decreased with increasing shear rate. The size and morphology of primary solid particles during stirring is influenced strongly by shear rates, cooling rates, volume fraction and stirring time of solid. Morphological changes during stirring as a function of solid volume fractions, shear rate and processing time were also reported. In this study, the size of primary solid particles in these alloys consistently increases and the it`s aspect ratio decrease with the increase in fraction solid and decrease in shear rate. Crystal morphology changes from rosette type to spheroid type with the increase in shear rate and solid fraction.

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