• Journal of the Society of Naval Architects of Korea
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• v.33 no.4
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• pp.97-105
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• 1996

For the minimum weight design of ship structures it is desirable that tank arrangement is predetermined to obtain the minimum weight and then structural arrangement and scanting of each murder is determined to obtain the minimum weight within the given tank arrangement. To carry out the tank arrangement to give minimum weight a minimum weight design program which covers whole ship structures is developed by the combination of minimum weight design program of longitudinal members by classification rules and minimum weight design program of transverse members by generalized slope deflection method which were developed by the authors. The hullweight is estimated by summation of the weight of cargo hold part and the weight except cargo hold part which can be estimated by the empirical formula. In this study, the variation of hullweight is shown with the number of tank, the number of web and the location of longitudinal bulkhead. For the application of actual design alternative designs of tank arrangement which satisfy MARPOL regulation are determined. And several minimum weight designs of whole ship structures are carried out to obtain the tank arrangement which gives minimum weight and then the hullweight is compared with that of existing ship.

• Journal of the Korean Chemical Society
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• v.30 no.1
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• pp.3-8
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• 1986

The investigation of the effect of solvent structure on the first-order solvolysis of cis-$[Co(en)_2ClNO_2]^+$ion has been extended to water + co-solvent mixtures where the co-solvents are glycerol, ethylene glycol, isopropyl alcohol and t-butyl alcohol. Rates of solvolysis have been evaluated by spectrophotometric method at temperature 25∼30$^{\circ}$C. The polarity of solvent has influence on the variation of rate constant. The non-linear plot of the rate constant in log scale versus $\frac{D-1}{2D+1}$ implies that change in solvent structure with composition plays an important role in determining the variation of rate constant. The linearity of the plot of the rate constant in log scale versus the Grundwald-Winstein Y factor confirms that the solvolysis is an Id-type process with considerable extension of the metal chloride bond in the transition state. In the Kivinen equation the slope of the plot of log k versus $log(H_2O)$ suggests that the solvolysis is also an Id-type process. The application of free energy cycle shows that the effect of solvent structure is greater in the transition state than in the initial state.

• Bulletin of the Korean Chemical Society
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• v.34 no.4
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• pp.1153-1159
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• 2013

A novel solid-contact indium(III)-selective sensor based on bis-(1H-benzimidazole-5-methoxy-2-[(4-methoxy-3, 5-dimethyl-1-pyridinyl) 2-methyl]) thiosulfinate, known as an omeprazole dimer (OD) and a neutral ionophore, was constructed, and its performance characteristics were evaluated. The sensor was prepared by applying a membrane cocktail containing the ionophore to a graphite rod pre-coated with polyethylene dioxythiophene (PEDOT) conducting polymer as the ion-to-electron transducer. The membrane contained 3.6% OD, 2.3% oleic acid (OA) and 62% dioctyl phthalate (DOP) as the solvent mediator in PVC and produced a good potentiometric response to indium(III) ions with a Nernstian slope of 19.09 mV/decade. The constructed sensor possessed a linear concentration range from $3{\times}10^{-7}$ to $1{\times}10^{-2}$ M and a lower detection limit (LDL) of $1{\times}10^{-7}$ M indium(III) over a pH range of 4.0-7.0. It also displayed a fast response time and good selectivity for indium(III) over several other ions. The sensor can be used for longer than three months without any considerable divergence in potential. The sensor was utilized for direct and flow injection potentiometric (FIP) determination of indium(III) in alloys. The parameters that control the flow injection method were optimized. Indium(III) was quantitatively recovered, and the results agreed with those obtained using atomic absorption spectrophotometry, as confirmed by the f and t values. The sensor was also utilized as an indicator electrode for the potentiometric titration of fluoride in the presence of chloride, bromide, iodide and thiocyanate ions using indium(III) nitrate as the titrant.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.3 s.234
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• pp.390-401
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• 2005

In this study, extinction limit extension of unsteady $(CH_{4}+N_{2})$/air diffusion flames was investigated experimentally. A spatially locked flame in an opposing jet burner was perturbed by linear velocity variation, and time-dependent flame luminosity, transient maximum flame temperature and OH radical were measured over time with the high speed camera, Rayleigh scattering method and OH laser-induced fluorescence, respectively. Unsteady flames survive at strain rates that are much higher than the extinction limit of steady flames, and unsteady extinction limits extend as the slope of the strain rate increases or the initial strain rate decreases. We verified the validity of the equivalent strain rate concept by comparing the course of unsteady extinction process and steady extinction process, and it was found that the equivalent strain rate concept represents well the unsteady effect of a convective-diffusive zone. To investigate the reason of the unsteady extinction limit extension, we subtracted the time lag of the convective-diffusive zone by using the equivalent strain concept. Then the modified unsteady extinction limits become smaller than the original unsteady extinction limits, however, the modified unsteady extinction limits are still larger than the steady extinction limits. These results suggest that there exist the unsteady behavior of a diffusive-reactive zone near the extinction limit due to the chemical non-equilibrium states associated with unsteady flames.

• Journal of Korea Water Resources Association
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• v.38 no.12 s.161
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• pp.1021-1028
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• 2005

This study purpose to develop simulation model of optimal design condition of urban storm sewer system considering risk. Urban Storm Sewer Optimal Design Model(USSOD) can compute pipe capacity, pipe slope, crown elevation, excavation depth, risk and return cost in the condition of design discharge. Rational formula is adopted for design discharge and Manning's formula is used for pipe capacity. Discrete differential dynamic programming(DDDP) technique which is a kind of dynamic programming(DP) is used for optimization and first order second moment approximation method and uncertainty analysis is also for developing model. USSOD is applied to hypothetical drainage basin to test and verify, which resulted economical and efficient design in urban drainage sewer system.

• Journal of Environmental Science International
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• v.15 no.8
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• pp.727-735
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• 2006

In this study, the PHYTO-PAM-fluorometric method was used to evaluate the ETR$_{max}$ in terms of sensitivity to DIN/DIP against 14 microalgae: Prorocentrum micans, Heterocapsa triquetra, Gymnodinium impudicum, Cymnodinium catenatum, Amphidinium caterae, Chlorella vulgaris, Chroococcus minutus, Microcystis aeruginosa, Chlorella ellipsoidea, Nannochloris oculata, Oocystis lacustris, Chroomonas salina, Gloeocystis gigas, and Prymnessium parvum. We found that P. micans, H. triquetra, and A. caterae exposed to the maximum level of DIN/DIP were significantly smaller in the ETR$_{max}$ than that of the minimum and moderate mixture. Unlikely the ETR$_{max}$, the initial slope alpha was not significantly different at the level of 60 DIN/DIP. In G. catenatum, the moderate levels of 15 and 20 in DIN/DIP were found to be significantly different from the ETR$_{max}$ at Chl-Ch4. Gymnodinium impudicum had a higher value than that of the ETR$_{max}$ than that of dinoflagellates used in this study, ranging from 306.1 (Ch4, DIN/DIP: 10) to 520.1 (Ch4, DIN/DIP: 30). The ETR$_{max}$ value obtained from other microalgae was similar to C. impudicum at any of the ratios of DIN/DIP and channels. Consequently, the influence of offshore water current assures us of the suppression of photosynthesis and electron transport rate in dinoflagellates. Gymnodinium impudicum has not been researched in the area of red tides in Korea, but it will be enough to creat the massive algal blooms in the future because of higher potential photochemical availability.

• Journal of Korean Society for Geospatial Information Science
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• v.18 no.4
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• pp.61-69
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• 2010

The collapse of a slope or cut embankment brings much damage to life and property. Accordingly, it is very important to analyze the spatial distribution by calculating the landslide susceptibility in the estimation of the risk of landslide occurrence. The heuristic, statistic, deterministic, and probabilistic methods have been introduced to make landslide susceptibility maps. In many cases, however, the reliability is low due to insufficient field data, and the qualitative experience and knowledge of experts could not be combined with the quantitative mechanical?analysis model in the existing methods. In this paper, new modeling method for a probabilistic landslide susceptibility analysis combined Bayesian Network with ontology model about experts' knowledge and spatial data was proposed. The ontology model, which was made using the reasoning engine, was automatically converted into the Bayesian Network structure. Through conditional probabilistic reasoning using the created Bayesian Network, landslide susceptibility with uncertainty was analyzed, and the results were described in maps, using GIS. The developed Bayesian Network was then applied to the test-site to verify its effect, and the result corresponded to the landslide traces boundary at 86.5% accuracy. We expect that general users will be able to make a landslide susceptibility analysis over a wide area without experts' help.

• Journal of Powder Materials
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• v.25 no.4
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• pp.322-326
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• 2018

The hydrogen reduction behavior of $MoO_3-CuO$ powder mixture for the synthesis of homogeneous Mo-20 wt% Cu composite powder is investigated. The reduction behavior of ball-milled powder mixture is analyzed by XRD and temperature programmed reduction method at various heating rates in Ar-10% $H_2$ atmosphere. The XRD analysis of the heat-treated powder at $300^{\circ}C$ shows Cu, $MoO_3$, and $Cu_2MoO_5$ phases. In contrast, the powder mixture heated at $400^{\circ}C$ is composed of Cu and $MoO_2$ phases. The hydrogen reduction kinetic is evaluated by the amount of peak shift with heating rates. The activation energies for the reduction, estimated by the slope of the Kissinger plot, are measured as 112.2 kJ/mol and 65.2 kJ/mol, depending on the reduction steps from CuO to Cu and from $MoO_3$ to $MoO_2$, respectively. The measured activation energy for the reduction of $MoO_3$ is explained by the effect of pre-reduced Cu particles. The powder mixture, hydrogen-reduced at $700^{\circ}C$, shows the dispersion of nano-sized Cu agglomerates on the surface of Mo powders.

• Journal of The Korean Society of Agricultural Engineers
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• v.60 no.1
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• pp.1-10
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• 2018

This study analyzed pore water pressure, seepage and leakage quantity, height of seepage and critical hydraulic gradient in order to suggest the seepage characteristics of agricultural reservoir embankment considering filter interval. The seepage characteristics of a deteriorated reservoir embankments were conducted according to the horizontal filter intervals range using three- dimensional finite element analysis. The wider the horizontal filter interval, the higher the pore water pressure increased, and the pore water pressure ratio in the center of the core has a greater effect than the base part. The seepage and leakage quantity appeared largely in the two-dimensional analysis conditions (case 1), where the filter was constructed totally in the longitudinal direction of the embankment, the wider the horizontal filter interval was gradually reduced. The reasonable filter intervals to yield efficient seepage characteristics were within 30 m for the pore water pressure of the core and the height of the seepage line. The stability of the filter installation was able to evaluate the stability of the piping by the critical hydraulic gradient method. The deteriorated reservoir with no filters or decreased functionality can significantly reduce the possibility of piping by simply installing a filter on the downstream slope. In the future, the deteriorated reservoir embankment should be checked for the reservoir remodeling because the core and filter functions have been lost or decreased significantly. In the case of a new installation, the seepage characteristic behavior due to the core and filter changes should be applied to the field after obtaining a reasonable horizontal filter interval that satisfies the safety factor by a three-dimensional analysis.

• The Journal of the Korea Contents Association
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• v.15 no.2
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• pp.499-506
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• 2015

The friction velocity is a quantity with the dimensions of velocity defined by the friction stress and density of a wall surface at near wall of flow condition. Also, the friction velocity is the hydraulic parameter describing shear force at the bottom flow. Moreover, it is a very important factor in designing open channel and essential to determine the mixing coefficient in the main flow direction. The estimation of the friction velocity are such as methods using channel slope, linear law of the mean velocity at viscous sub-layer and direct measurement of wall shear stress, etc. In the present study, we propose a friction velocity equation that has been optimized by combining the concept of entropy, which is used in stochastic method, and to verify the proposed equation, the experimental data measured by Song was used. The R squared for friction velocities between proposed equation and friction velocity formula analyzed 0.999 to 1.000 in a very good agreement with each equation.