• Resources Recycling
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• v.27 no.2
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• pp.24-31
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• 2018

In this study, waste ITO target is dissolved into hydrochloric acid to generate a complex indium-tin chloride solution. Nano sized ITO powder with an average particle size below 30 nm are generated from these raw material solutions by spray pyrolysis process. Also, in this study, thermodynamic equations for the formation of indium-tin oxide (ITO) are established. As the reaction temperature increased from $800^{\circ}C$ to $900^{\circ}C$, the proportion and size of the spherical droplet shape in which nano sized particles aggregated gradually decreased, and the surface structure gradually became densified. When the reaction temperature was $800^{\circ}C$, the average particle size of the generated powder was about 20 nm, and no significant sintering was observed. At a reaction temperature of $900^{\circ}C$, the split of the droplet was more severe than at $800^{\circ}C$, and the rate of maintenance of the initial atomized droplet shape decreased sharply. The average particle size of the powder formed was about 25 nm. The ITO particles were composed of single solid crystals, regardless of reaction temperature. XRD analysis showed that only the ITO phase was formed. Remarkably, the specific surface area decreased by about 30% as the reaction temperature increased from $800^{\circ}C$ to $900^{\circ}C$.

• Journal of Electrical Engineering and Technology
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• v.1 no.3
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• pp.371-375
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• 2006

Effects of $Ag_2O$ doping on the electromagnetic properties in the BiSrCaCuO superconductor. The electromagnetic properties of doped and undoped $Ag_2O$ in the BiSrCaCuO superconductor were evaluated to investigate the contribution of the pinning centers. It was confirmed experimentally that a larger amount of magnetic flux was trapped in the $Ag_2O$ doped sample than in the undoped one, indicating that the pinning centers of magnetic flux are related closely to the occurrence of the magnetic effect. We have fabricated superconductor ceramics by the chemical process. A high Tc superconductor with a nominal composition of $Bi_2Sr_2Ca_2Cu_3O_y$ was prepared by the organic metal salts method. Experimental results suggest that the intermediate phase formed before the formation of the superconductor phase may be the most important factor. The relation between electromagnetic properties of Bi HTS and the external applied magnetic field was studied. The electrical resistance of the superconductor was increased by the application of the external magnetic field. But the increase in the electrical resistance continues even after the removal of the magnetic field. The reason is as follows; the magnetic flux due to the external magnetic field penetrates through the superconductor and the penetrated magnetic flux is trapped after the removal of the magnetic flux. During the sintering, doped $Ag_2O$ was converted to Ag particles that were finely dispersed in superconductor samples. It is considered that the area where normal conduction takes place increases by adding $Ag_2O$ and the magnetic flux penetrating through the sample increases. The results suggested that $Ag_2O$ acts to amplify pinning centers of magnetic flux, contributing to the occurrence of the electromagnetic properties.

• Resources Recycling
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• v.17 no.6
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• pp.57-61
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• 2008

The aim of this study is to produce the coke which can be used for the production of ferroalloy, by mixing phenolic resin and anthracite and sintering it. The influence of factors on the strength of coke were investigated. The results of this study are as follows: It is found that the anthracite coke of $100{\sim}150\;kgf/cm^2$ strength for ferroalloy can be made by a series of process as follows; Mixing homogeneously 6% liquefied phenolic resin and 6% water with $35{\sim}325$ mesh anthracite of low ash content. Making pellet by press the mixture in $10-50\;kgf/cm^2$ pressure. Dehydrating the pellet for 6 hrs at $50^{\circ}C$, and hardening it for 180 min at $200^{\circ}C$. Sinter the mixture for 6 hrs at $1,200^{\circ}C$.

• Journal of Hydrogen and New Energy
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• v.16 no.1
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• pp.49-57
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• 2005

[ $MO/Al_2O_3-ZrO_2$ ](M=Ni and Cu) mixed metal oxides were prepared using sol-gel method in order to investigate the applicability to the 2-step thermo-chemical water splitting process and their redox behaviors were studied by temperature programmed reaction(TPR) from room temperature to 900$^{\circ}C$ under 5% $H_2$/Ar for the reduction and $H_2O$/Ar for the oxidation, respectively. From the results, peaks of the reduction and the oxidation on temperature were shifted with the change of crystalline phases due to the addition of $Al_2O_3$ and $ZrO_2$. The intensities of the peaks were also increased with the increase of contents of NiO or CuO that could be considered as active species. In addition, based on the observation of SEM images before and after the redox test, it seemed that $Al_2O_3-ZrO_2$ added prevented high temperature sintering of active metal components such as Ni (or Cu) on the surface and played a role of dispersing the active species homogeneously in solid solution of mixed oxides.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.1
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• pp.21-26
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• 2014

When iodine container for dental mouth treatment is opened, thread for treatment is cut by the blade in cap of container. Due to the problem of corrosion in a short period time after the reaction of metal blade to iodine solution, it gives impact on patient hygiene. In order to solve the problem, alternative products such as ceramic blade are developed and produced recently. In case of ceramic blade, it is produced by handwork and machine work. In this study, for the quantity production of ceramic blade with powder injection molding, we proposed a delivery system to have uniform charge of 20 cavity. Using Moldflow, simulation on 20 Cavity flow was performed. And then the mold was obtained through mold production and modification.(based on simulation) After injection molding, debinder, sintering process was achieved for ceramic blade, and the cap product was completed via insert injection on ceramic blade. In this study, we verified possibility of quantity production of ceramic blade which showed effective performance for cutting.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.139-139
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• 2010

LSM is widely used as a cathode material in SOFC, because of its high electrochemical activity, good stability and compatibility with YSZ electrolyte at high temperature. However, LSM in traditional cathode materials will not generate a satisfactory performance at intermediate temperature. In order to reduce the polarization resistance of cell with the operating temperature of SOFC system, the cathode material of LSCF is one of the most suitable electrode materials because of its high mixed ionic and electronic conductivity. In this report, cathode material, $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$ powder for intermediate temperature SOFC was synthesized by Pechini method using the starting materials such as nitrate of La, Sr, Co and Fe including ethylene glycol, etc. As a result, the synthesized powder that calcined above $700^{\circ}C$ exhibits successfully perovskite structure, indicating phase-pure of LSCF. Moreover, the particle size, surface area, crystal structure and morphology of the synthesized oxide powders were characterized by SEM, XRD, and BET, etc. In order to evaluate the electrochemical performance for the synthesized powder, slury mixture using the synthesized cathode material was coated by screen-printing process on the anode-supported electrolyte which was prepared by a tape casting method and co-sintering. Finally, electrochemical studies of the SOFC unit cell, including measurements such as power density and impedance, were performed.

• Transactions on Electrical and Electronic Materials
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• v.16 no.6
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• pp.342-345
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• 2015

The n -type Hf_0.25Zr_0.25Ti_0.5NiSn_0.998Sb_0.002 Half-Heusler (HH) alloy composition was prepared by using the induction melting method in addition to the mechanical grinding, annealing, and spark plasma sintering processes. Analysis of X-ray diffraction (XRD) results indicated the formation of a pure phase HH structured compound. The electrical and thermal properties at temperatures ranging from room temperature to 718 K were investigated. The electrical conductivity increased with increasing temperatures and demonstrated nondegenerate semiconducting behavior, and a large reduction in the thermal conductivity to the value of 2.5 W/mK at room temperature was observed. With the power factor and thermal conductivity, the dimensionless figure of merit was increased with temperature and measured at 0.94 at 718 K for the compound synthesized by the induction melting process.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.1 s.173
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• pp.1-6
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• 2000

As dies and molds have become more and more complicated in the recent years, the demand for lower cost and shorter production time is also growing stronger. Rapid prototyping and Tooling technologies are expected to be used for more rapid and lower cost tool fabrication. However the rapid tooling methods have not yet reached the level of application to the manufacturing of metallic dies and molds which require high dimensional accuracy. As the rapid tooling technology, there are the slurry casting, the powder casting, the direct laser sintering, and so on. Generally, in the slurry casting, the alumina powder and the water soluble phenol were mainly used. However, the mechanical properties of the phenol were not good enough to apply to molds directly. In this study, pure epoxy and two types of aluminium powder reinforced resin are applied to the slurry casting. The mechanical and thermal properties are better than phenol because the epoxy is the thermosetting resin. And mechanical characteristics such as shrinkage rate, hardness, surface roughness are measured for the sake of comparison. Metal powder reinforced resin molds are better than the resin tool form the viewpoint of shrinkage rate and hardness. Finally, it has been shown that the application possibility of this process is high, because the manufacturing time and cost savings are significant.

• Journal of the Microelectronics and Packaging Society
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• v.11 no.3 s.32
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• pp.77-82
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• 2004

In this paper, warpages of heterogeneous LTCC substrates comprised of high K/low K hi-layered structure were investigated. The effect of glass content in high K LTCC layer on the warpage of substrate during co-firing process was examined. Shrinkage and dielectric properties of high K and low K green sheets were measured. In-situ camber observation by hot stage microscopy showed different camber development of heterogeneous LTCC substrates according to glass content in high K green sheet. High K green sheet containing $50\%$ glass was matched to low K green sheet in the shrinkage. Therefore, LTCC substrate of Low K/High K+$50\%$ glass structure showed flat surface after sintering.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.24 no.3
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• pp.127-132
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• 2014

$Y_2O_3$-BN ceramic composites were fabricated from the slurries of yttria powder with average particle size of 3~10 ${\mu}m$. The slurry was fabricated by mixing PVA binder, NaOH for Ph control, PEG, BN powder and $Y_2O_3$ powder. The mixed $Y_2O_3$ powders were obtained by spray drying process from the slurry. The $Y_2O_3$-BN composite specimen was shaped in size of ${\O}14mm$ and then sintered at $1550^{\circ}C$ and $1600^{\circ}C$, respectively. The characteristics, microstructure, purities, densities, bulk resistance, thermal expansion, hardness and plasma resistance of the $Y_2O_3$-BN composites were investigated with the function of BN contents and sintering temperature.