• Journal of the Korea Organic Resources Recycling Association
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• v.31 no.3
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• pp.5-13
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• 2023

In this study, a comparative study is conducted on the synthesis methods for silica nanoparticle employing the silicon sludge waste generated from the semiconductor manufacturing processes. Specifically, acid-washed silicon sludge wastes with no impurities are employed as the precursors of sol-gel and hydrothermal methods for silica nanoparticles preparation. The morphologies and properties of silica nanoparticles synthesized via two synthetic methods are examined by various analysis methods. As a result, silica nanoparticles from the sol-gel method are fabricated with high purity and uniform shape, while the hydrothermal method exhibits advantages in yield and ease of synthetic process. This comparative study offers detailed experimental results on the two synthetic methods for silica nanoparticle synthesis, which may contribute to the establishment of manufacturing high-value materials using the by-products generated in the semiconductor process.

• Advances in materials Research
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• v.12 no.3
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• pp.227-242
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• 2023

Polyester composites play a vital role in civil engineering applications, especially in bridge and car park structures. Therefore, the addition of waste silica-based fillers will both improve the mechanical and durability performance of composites and produce an environmentally friendly material. In this study, the mechanical performance of polyester composites was investigated experimentally and numerically by adding micro and nano-sized silica-based fillers, marble powder, silica fume and nano-silica. 24 cubes for the compression test and 18 prisms for the flexural test were produced in six different groups containing 30% marble powder, 5% silica fume and 1% nano-silica by weight. SEM/EDS testing was used to investigate the distribution of filler particles in the matrix. Experimentally collected results were used to validate tests in the Abaqus software. Additionally, the Extended Finite Element Method (XFEM) was used to estimate the fracture process for the flexural test. The results show that the added silica fume, marble powder and nano silica improves the compressive strength of polyester composites by 32-38% and the flexural tensile strength by 10-60% compared to pure polyester composite. The numerically obtained results matched well with the experimental data, demonstrating the accuracy and feasibility of the calibrated finite element model.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.9 no.1
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• pp.1-11
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• 2011

Tetraethoxysilane(TEOS) as a silica precursor and hydrochloric acid as an acid catalyst have been used in a surfactant-template synthesis of micrometer-sized mesoporous silica microspheres based on the macroemulsion technique. Increase in the concentration of tetraethoxysilane of the reaction mixture has a serious destructive effect on the particle shape and pore structure. As the acid concentration increases, relatively small microspheres are formed without destroying their spherical morphology of the particles as well as the pore structures. However, due to the attractive interaction between particles in an acidic condition, strong silica agglomerates are formed, and therefore are subject to a post-ultrasonic treatment to separate into an individual single particle.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.41 no.3
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• pp.22-28
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• 2009

The rice hull could be the one of the most abundant agricultural waste in Korea. Since the efficient utilization of agricultural waste or byproducts of food industry would be critical for the sustainable growth, this study conducted the investigation of the chemical composition and the morphological properties of rice hull and rice hull fiber. It was found that there was big difference between the outer surface and the inner surface in the chemical composition and the morphological properties. Expecially, the outer surface showed the rugged patterns in which most of silica of rice hull existed. Little or no silica was found in the inner surface and rice hull fiber. The average fiber length of rice hull fiber was 0.45mm which was shorter than that of hardwood fiber. Rice hull fiber showed a round long shape which is typical shape of non-wood fibers

• Membrane Journal
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• v.32 no.5
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• pp.265-274
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• 2022

Separation of oily wastewater, which is a byproduct of various industries such as petroleum refineries, is essential to not exceed the tolerance limit of wastewater streams. Ceramic membranes show potential in oily wastewater separation, due to their excellent oil removal efficiency, good chemical, thermal, and mechanical stability, and simple operation. However, widespread application of ceramic membranes is limited due to high material cost of alumina, silica, and other ceramic based materials used to fabricate them. Recent efforts to reduce material cost have been made, using fly ash and clay. This review examines the fabrication and efficiency of ceramic membranes in oily wastewater separation according to material: silica, alumina, and waste ash.

• Computers and Concrete
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• v.31 no.4
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• pp.327-335
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• 2023

The most popular building material, concrete, is intrinsically linked to the advancement of humanity. Due to the ever-increasing complexity of cementitious systems, concrete formulation for desired qualities remains a difficult undertaking despite conceptual and methodological advancement in the field of concrete science. Recognising the significant pollution caused by the traditional cement industry, construction of civil engineering structures has been carried out successfully using Geopolymer Concrete (GPC), also known as High Performance Concrete (HPC). These are concretes formed by the reaction of inorganic materials with a high content of Silicon and Aluminium (Pozzolans) with alkalis to achieve cementitious properties. These supplementary cementitious materials include Ground Granulated Blast Furnace Slag (GGBFS), a waste material generated in the steel manufacturing industry; Fly Ash, which is a fine waste product produced by coal-fired power stations and Silica Fume, a by-product of producing silicon metal or ferrosilicon alloys. This result demonstrated that GPC/HPC can be utilised as a substitute for traditional Portland cement-based concrete, resulting in improvements in concrete properties in addition to environmental and economic benefits. This study explores utilising experimental data to train artificial neural networks, which are then used to determine the effect of supplementary cementitious material replacement, namely fly ash, Ground Granulated Blast Furnace Slag (GGBFS) and silica fume, on the compressive strength, tensile strength, and modulus of elasticity of concrete and to predict these values accordingly.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.04a
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• pp.52-57
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• 1999

The aimed of this study is to analyze the qualities of foundry waste sand and the basic physic of the concrete mixed with the foundry waste sand, as a way of study for reusing the foundry waste sand disused in the foundry as the fine aggregate for concrete. According to the experimental results, the foundry waste sand is composed of silica ore whose main ingredient is SiO2 and doesn't produce harmful objects of hydration reaction, and the fluidity of concrete shows a decline with the increase of replacement ratio of foundry waste sand, and the compress strength, the tensile strength, the elastic modulus of concrete containing foundry waste sand are improved at the replacement rate of 25%.

• Smart Structures and Systems
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• v.19 no.3
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• pp.323-333
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• 2017

Waste materials in concrete have been considered as one of the most important issues by the authorities, policy makers and researchers to maintain engineering serviceability in terms of economy, durability and sustainability. Therefore, evaluation and selection of waste materials with respect to multi criteria decision making (MCDM) for the construction industry has been gained importance for recovery and reuse. In this paper, Choquet integral based fuzzy approach is proposed for evaluating the most suitable waste materials with respect to compressive strength, tensile strength, flexural strength, compactness, toughness (resistivity for dynamic loads), water absorption and accessibility. On conclusion, waste tyre and silica fume were determined as the most suitable waste materials for concrete production. The obtained results are recommended to assist the authorities on configuring well designed strategies for construction industry with disposal materials.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.05a
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• pp.283-286
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• 2012

According to increase of the waste concrete occurrence, recycling has being important more and more. This study is to recycle the waste concrete powder, which is occurred in dry-process during recycling of construction waste. We have tried the waste concrete powder to apply as the replacement of the silica powder in cement extruding product. As a result, it is satisfied that the autoclave cured pannel of 50% replacement ratio of waste concrete powder staisty the level of the flexural strength of 14MPa stipulated by "KS F 4735 Extruding concrete panel" was the same thermal properties as base specimen.

• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.952-959
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• 2012

The photocatalytic reactor was designed to have improved efficiency by enhancing a light intensity of photocatalytic reactor using a reflector coated on the surface at the outer radius of annular shaped photocatalytic reactor. The improved photocatalytic reactor performed to treat waste air containing malodor and VOC with the enhanced light intensity, of which the effect on their removal efficiency was investigated. The intensities of illumination of the improved photocatalytic reactor filled with porous silica-based media and nonporous glass bead media carrying photocatalyst were observed to increase by 28.5% and 30.1%, respectively, compared to those of photocatalytic reactor without any reflector. Using the improved photocatalytic reactor filled with porous silica-based media and nonporous glass bead media carrying photocatalyst, the removal efficiencies were enhanced by 2~3% and insignificantly, respectively. The removal efficiencies of the optimized photocatalytic reactor with reflectors, filled with porous silica-based media carrying photocatalyst, were observed to increase by 26% and 60%, compared to those of photocatalytic reactor (i.e., 19% and 53%), without any reflector, filled with nonporous glass bead media carrying photocatalyst, for hydrogen sulfide and toluene, respectively. The roughness of used reflector surface was measured to be ca. four times as big as that of a commercial mirror. However, their removal efficiencies are expected to be enhanced by increasing an light intensity resulting from lowering the roughness of used reflector coated on the improved photocatalytic reactor in the future.