• Title/Summary/Keyword: Silica film

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A study on the structure of Si-O-C thin films with films size pore by ICPCVD (ICPCVD방법에 의한 나노기공을 갖는 Si-O-C 박막의 형성에 관한 연구)

  • Oh, Teresa
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2002.11a
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    • pp.477-480
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    • 2002
  • Si-O-C(-H) thin film with a tow dielectric constant were deposited on a P-type Si(100) substrate by an inductively coupled plasma chemical vapor deposition (ICPCVD). Bis-trimethylsilymethane (BTMSM, H$_{9}$C$_3$-Si-CH$_2$-Si-C$_3$H$_{9}$) and oxygen gas were used as Precursor. Hybrid type Si-O-C(-H) thin films with organic material have been generated many voids after annealing. Consequently, the Si-O-C(-H) films can be made a low dielectric material by the effect of void. The surface characterization of Si-O-C(-H) thin films were performed by SEM(scanning electron microscope). The characteristic analysis of Si-O-C(-H) thin films were performed by X-ray photoelectron spectroscopy (XPS).

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Preparation of Au fine particle dispersedf $TiO_{2}$ film by sol-gel and photoreduction process (Sol-Gel and photoreduction 공정에 의한 Au 미립자분산 $TiO_{2}$ 박막 제조)

  • 현부성;김병일;강원호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.1
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    • pp.23-28
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    • 1999
  • Au fine particles dispersed $TiO_{2}$ film was prepared on silica glass substrate by sol-gel dipping and firing process. The $TiO_{2}$ films were fabricated from the system of titanium tetraisopropoxide-EtOH-HCl-$H_{2}O$-hydrogen tetrachloroaurat (III) tetrahydrate. The conditions for the formation of clear solution and dissolving high concentration of Au compound were examined. Photoreduction process was adopted to control the size of gold metal particles. Phase evolution of matrix $TiO_{2}$ and variation of Au particle with UV irradiation were investigated by XRD, SEM, TEM and UV-visible spectrophotometer. The effect of CPCl (Cetylpyridinium chloride monohydrate) as a dispersion agent was evaluated.

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Effect of annealing on the electrical properties of amorphous oxide semiconductor $InGaZnO_4$ films (열처리에 의한 비정질 산화물 반도체 $InGaZnO_4$ 박막의 전기적 특성 변화 연구)

  • Bae, Sung-Hwan;Koo, Hyun;Yoo, Il-Hwan;Jung, Myung-Jin;Kang, Suk-Ill;Park, Chan
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1277_1278
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    • 2009
  • Amorphous oxide semiconductor $InGaZnO_4$(IGZO) is a very promising candidate of channel layer in transparent thin film trasisitor(TTFT) because of its high mobility and high transparency in visible light region. Amorphous IGZO films were deposited at room temperature on a fused silica substrate using pulsed laser deposition method. In-situ post annealing was carried out at 150-450C right after film deposition. The $O_2$ partial pressures during the deposition and the post annealing was fixed to 10mTorr. The electron transport properties of the amorphous IGZO films were improved by thermal annealing. The temperature range in which the improvement of the electrical properties, was 150C~300C.

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Optical properties of metal doped TiO2 thin films prepared by spin coating-pyrolysis process (스핀코팅으로 금속물질을 도핑한 TiO2박막의 광학적 특성)

  • Hwang, Kyu-Seong;Kim, Jai-Min;Jung, Ju-Hyun
    • Journal of Korean Ophthalmic Optics Society
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    • v.12 no.1
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    • pp.17-22
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    • 2007
  • Metal-doped $TiO_2$ thin films were prepared on soda-lime-silica glass substrates by using a spin coating-pyrolysis process. As-deposited films were prefired at $500^{\circ}C$ or 10 min in air. Five-coated films were finally annealed at $600^{\circ}C$ for 30 min in air. High resolution X-ray diffraction, field emission scanning electron microscope and UV spectrophotometer were used to analyze film's property. The largest red shift in optical energy gap is obtained in the Fe-doped $TiO_2$ film.

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Effects of additives on properties of Sol-Gel derived $TiO_2$ coating films for nonlinear optics (Effects of additives on properties of Sol-Gel derived $TiO_2$coating films for nonlinear optics)

  • 김세훈;정용선;김인기;강승민;현부성;김병일;박원규
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.2
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    • pp.315-323
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    • 1998
  • $TiO_2$films of rutile and anatase phase have been prepared on silica glass substrates by the sol-gel method using $Ti(i-OC_3H_7)_4$. The effect of additives on the polymorph of $TiO_2$film has been examined in view of degree of crystallization. Third-order nonlinear optical properties of the both film have been investigated by the third harmonic generation method. The measured 3rd order nonlinear optical susceptibility of rutile and anatase thin films were about $1.4{\times}10^{-12}$ and $9.7{\times}10^{-13}$ esu, respectively.

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Optimization Of CMP for $SiO_2$ Thin Film with a Control of Temperature in Pad Conditioning Process (패드 컨디셔닝시 온도조절을 통한 산화막 CMP 최적화)

  • Choi, Gwon-Woo;Park, Sung-Woo;Kim, Nam-Hoon;Chang, Eui-Goo;Seo, Yong-Jin;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.731-734
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    • 2004
  • As the integrated circuit device shrinks to the smaller dimension, the chemical mechanical polishing (CMP) process was required for the global planarization of inter-metal dielectric(IMD) layer with free-defect. Polishing pads play a key role in CMP, which has been recognized as a critical step to improve the topography of wafers for semiconductor fabrication. It is investigated the performance of $SiO_2-CMP$ process using commercial silica slurry as a pad conditioning temperature increased after CMP process. This study also showed the change of SEM images in the pore geometry on the CMP pad surface after use with a different pad conditioning temperature.

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Chemical Mechanical Polishing Characteristics of BTO Thin Film for Vertical Sidewall Patterning of High-Density Memory Capacitor (고집적 메모리 커패시터의 Vertical Sidewall Patterning을 위한 BTO 박막의 CMP 특성)

  • Ko, Pil-Ju;Park, Sung-Woo;Lee, Kang-Yeon;Lee, Woo-Sun;Seo, Yong-Jin
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.3
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    • pp.116-121
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    • 2006
  • Most high-k materials are well known not to be etched easily, Some problems such as low etch rate poor sidewall angle, plasma damage, and process complexity were emerged from the high-density DRAM fabrication. Chemical mechanical polishing (CMP) by a damascene process was proposed to pattern this high-k material was polished with some commercial silica slurry as a function of pH variation. Sufficient removal rate with adequate selectivity to realize the pattern mask of tera-ethyl ortho-silicate (TEOS) film for the vertical sidewall angle were obtained. The changes of X-ray diffraction pattern and dielectric constant by CMP process were negligible. The planarization was also achieved for the subsequent multi-level processes. Our new CMP approach will provide a guideline for effective patterning of high-k material by CMP technique.

The fabrication of Er-doped silica film for optical amplifier (광증폭기 응용을 위한 Er 첨가 실리카 유리 박막의 제조)

  • Kim, Jae-Seon;Sin, Dong-Uk;Jeong, Seon-Tae;Song, Yeong-Hwi
    • Korean Journal of Materials Research
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    • v.11 no.5
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    • pp.385-392
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    • 2001
  • There have been many investigations and researches on PLC type of optical amplifiers because they are convenient for mass production and also can integrate multi-functional devices into a single chip. In this research. the fabrication of optical waveguide made of Si/$Sio_2$ by FHD(Flame Hydrolysis Deposition) for passive integrated optical devices and $1.5\mu\textrm{m}$ optical amplifier by Solution Doping method, which is one of the method doping $Er^{3+}$ into the thin film, are mainly discussed.

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Fabrication and Performance Investigation of Surface Temperature Sensor Using Fluorescent Nanoporous Thin Film I (형광 나노 포러스 박막을 이용한 표면 온도 센서의 제작 및 성능 연구 I)

  • Kim, Hyun Jung;Yoo, Jaisuk;Park, Jinil
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.25 no.12
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    • pp.668-673
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    • 2013
  • In this study, specimens with nano-sized porous thin films were manufactured by injecting fluorescence solution into the pores. We intended to find out the difference of the fluorescence intensity in each region of the specimen through an experimental apparatus that makes a temperature field. Before conducting experiments, the optimized manufacturing conditions were determined by analysis of all parameters that influence the emission intensity, and the experiments were carried out with the specimens produced in the optimized conditions. Then, the calibration curves of the fluorescence intensity versus temperature were performed by taking the intensity distributions from the specimen in various temperature fields. The surfaces of specimens were coated with Rhodamine-B (Rh-B) fluorescent dye and measured based on the fluorescence intensity. Silica (SiO2) nanoporous structure with 1-um thickness was constructed on a cover glass, and fluorescence dye was absorbed into these porous thin films.

Electrical Properties of Porous SiO2/ITO Nano Films (다공성 SiO2/ITO 나노박막의 전기적 특성)

  • Sin, Yong-Uk;Kim, Sang-U
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.94-99
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    • 2002
  • The electrical properties of porous $SiO_2/ITO$ nano thin film were studied by complex impedance and conductive mechanisms were analyzed. According to the results of complex impedance, the activation energy of $SiO_2/ITO$ and $Zn-SiO_2/ITO$ were 0.309 eV, 0.077 eV in below $450^{\circ}C$ and 0.147 eV in over $450^{\circ}C$, respectively. In case of $SiO_2/ ITO$, slightly direct tunneling occurred at room temperature. The contribution for conduction was very tiny because of high barrier of silica. However, the conductivity abruptly increased in over $300^{\circ}C$ by Thermally assisted tunneling. In case of $Zn-SiO_2/ITO$, high conductivity in 1.26 ${\Omega}^{ -1}{cdot}cm^{-1}$ at room temperature appeared by space charge conduction or Frenkel-poole emission that Zn ions play a role as localized electron states.