• Carbon letters
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• 제10권3호
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• pp.190-197
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• 2009

Various silanes, amino silane, vinyl silane, sulfur silane (TESPD), and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/soft clay/carbon black (CB) and CIIR/hard clay/CB compounds and they are investigated with respect to the vulcanization characteristics, the processability, and the mechanical properties. Comparing hard clay and soft clay filled compounds, hard clay (Suprex) filled system shows a higher die C tear than the soft clay (GK) filled one. The other properties (Mooney, extrusion torque/pressure, torque rise ($M_H-M_L$), modulus at 300%) are close to each other. Among various silanes, the ZS treated hard clay (Suprex) compound shows the highest mechanical property following hard clay(S)/vinyl silane(V) and soft clay(GK)/vinyl silane(V) compounds. The TESPD and the ZS effectively helps a formation of a strong 3-dimensional network structure between silica and CIIR via coupling reaction due to bifunctional nature of TESPD. In addition to that, the ZS added compounds show both a better processability and mechanical properties compared to the S2 ones at low concentration due to improved compatibility between zinc soap and CIIR matrix. Only the ZS added compound shows both improved processabilities (Mooney, Extrusion torque-& pressure) and improved mechanical properties (degree of crosslinking, elongation modulus, tear, and fatigue to failure counts) on both CIIR/hard clay/CB and CIIR/soft clay/CB compounds.

• 한국표면공학회지
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• 제37권4호
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• pp.215-219
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• 2004

We fabricated protein chip plates coated with silane carboxylate. The silane compound was immobilized by hydrogen bond and/or other chemical bonds on the surface of the plate. The plates were then prepared by binding $Ni^{2+}$ to surfaces terminated with silane carboxylate groups. The carboxylic acid surface was generated by chemical oxidation of the terminal double-bond functions of the silane-deposited layer. The $Ni^{2+}$ ions on the surface reacted readily to His-tagged proteins. A significant increase in His-tagged protein adsorption was achieved on the surface terminated with silane carboxylate with longer alkyl chain, suggesting better availability of these protein chip plates for proteomic studies.

• 폴리머
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• 제26권4호
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• pp.445-451
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• 2002

본 연구에서는 실리카의 표면처리를 위해 실란 커플링제인, ${\gamma}$-methacryloxy propyl trimethoxy silane (MPS), ${\gamma}$-glycidoxy propyl trimethoxy silane (GPS), and ${\gamma}$-mercapto propyl trimethoxy silane (MCPS) 등을 사용하여 실리카 흡착특성과 기계적 계면물성에 대하여 고착하였다. 실란처리에 따른 실리카의 평형 확산압력, 표면 자유에너지, 비표면적을 BET법을 이용한 $N_2$/77 K 기체 흡착을 통하여 알아보았다. 본 실험결과 신란처리에 의해 실리카 표면에 도입된 비극성 관능기로 인해 실리카의 비표면적, 평형 확산압력, 표면 자유에너지의 비극성 요소가 증가하였으며 결과적으로 실리카/고무 복합재료의 기계적 계면 물성인 tearing energy ($G_{mc}$)가 향상되었음을 확인할 수 있었다. 그리고 MPS로 표면처리한 경우가 GPS, MCPS에 비해서 우수한 기계적 계면물성을 나타남을 관찰할 수 있었다.

• 한국콘텐츠학회논문지
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• 제15권2호
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• pp.344-351
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• 2015

본 논문은 치과에서 많이 사용되고 있는 silane coupling agent로 표면 처리한 의치상 레진과 자가중합 레진 간의 전단 결합력에 미치는 영향에 대해 알아보고자 하였다. 의치상 레진에 silane coupling agent 농도별 표면 처리 후 자가중합레진을 주입하여 전단결합강도를 측정하였다. Silane coupling agent(MPS)의 농도별 표면 처리에 따른 의치상 레진과 자가중합레진 간의 전단결합강도에서는 Vertex self curing resin에서 5%, 7%에서 유의적으로 높게 나타났고(P<0.05), Kooliner에서는 5%에서 유의적으로 가장 높게 나타났다(P<0.05). 따라서 의치상 레진과 자가중합레진 사이에 MPS 5%를 이용한 표면처리가 전단결합강도에 효과적으로 영향을 미치는 것이라 사료된다.

• Journal of the Korean Wood Science and Technology
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• 제52권3호
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• pp.205-220
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• 2024

Various polylactic acid (PLA) blends were reinforced with untreated or silane-treated micro-sized cellulose fiber (MCF), successfully prepared as 3D printing filaments and then printed using a fused filament fabrication (FFF) 3D printer. In this study, we focused on developing 3D-printed MCF/PLA composites through silane treatment of MCF and investigating the effect of silane treatment on the various properties of FFF 3D-printed composites. Fourier transform infrared spectra confirmed the increase in hydrophobic properties of silane-treated MCF by showing the new absorption peaks at 1,100 cm^-1, 1,030 cm^-1, and 815 cm^-1 representing C-NH₂, Si-O-Si, and Si-CH₂ bonds, respectively. In scanning electron microscope images of silane-treated MCF filled PLA composites, the improved interfacial adhesion between MCF and PLA matrix was observed. The mechanical properties of the 3D-printed MCF/PLA composites with silane-treated MCF were improved compared to those of the 3D-printed MCF/PLA composites with untreated MCF. In particular, the highest tensile and flexural modulus values were observed for S-MCF10 (5,784.77 MPa) and S-MCF5 (2,441.67 MPa), respectively. The thermal stability of silane-treated MCF was enhanced by delaying the initial thermal decomposition temperature compared to untreated MCF. The thermal decomposition temperature difference at T₉₅ was around 26℃. This study suggests that the effect of silane treatment on the 3D-printed MCF/PLA composites is effective and promising.

• 패션비즈니스
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• 제13권6호
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• pp.147-156
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• 2009

In this study, one of disadvantages is to improve the durability of natural dyeing. In order to enhance linkage of Chitosan or Linkage of between Chitosan and cotton fabrics, effect of increasing amount of Silane on Chitosan durability and possibility of using Chitosan as natural mordant were reviewed. After treatment of chitosan with silane, color effect is similar to dyeability used metal mordant. And the durability's washing fastness and air permeability as using chitosan with silane is better than treatment of metal mordant. Chitosan with silane can perform the natural mordant.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2001년도 추계학술대회 논문집 전기물성,응용부문
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• pp.140-145
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• 2001

In order to apply for silane crosslinking process to PTC products, especially. self-regulating heater, silane crosslinked samples were compared with radiation crosslinked sample in terms of PTC characteristic and PTC stability. Silane crosslinked samples have lower PTC intensity than radiation crosslinked sample. It can be explained that multiple networks of silane crosslink restrict the movement of molecules in the composite as the sample is heating. As a result of heat cycles at $140^{\circ}C$, the changes of volume resistivity and PTC intensity for radiation crosslinked sample were higher than those of silane crosslinked samples. Whereas, in the case of heat cycles at $85^{\circ}C$, which is limiting temperature for self-regulating heater, both silane and radiation crosslinked samples show stable results without pronounce changes of resistivity up to five cycles.

• E2M - 전기 전자와 첨단 소재
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• 제5권4호
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• pp.393-399
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• 1992

In order to increase the coupling strength between bisphenol-A type epoxy resin and filler SiO$_{2}$ it was treated to filler with silane coupling agent[KBM-603]. To observe how silane coupling agent effects on dielectric breakdown strength of Epoxy/SiO$_{2}$ compound material, specimens of eight type were made like following. (A-1, A-2), (B-1, B-2), (C-1, C-2), (D-1, D-2) (see 2-2. Specimen) Specimen treated with silane coupling agent had always bigger dielectric breakdown strength than non-treated specimen. Under the influence of silane coupling agent, increment ratio of dielectric breakdown strength at specimen manufactured by hand drill was very bigger than that of specimen inserted spherical electrode. Therefore, as the specimen shape was varied, it was studied on effect that silane coupling agent affects on dielectric breakdown strength of Epoxy/SiO$_{2}$ compound material.

• 한국표면공학회지
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• 제37권1호
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• pp.49-52
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• 2004

In this study, we investigated the fatigue characteristics of silane-treated aluminum/CFRP composite material. Three different specimens of cracked aluminum, cracked aluminum repaired with CFRP patch, and silane-treated aluminum repaired with CFRP patch were used in the fatigue tests. Load ratio and the frequency applied in the fatigue tests were 0 and 10 Hz, respectively. The results showed that the specimen repaired by composite patch showed three times more improved fatigue life than aluminum specimen. Furthermore, the silane-treated specimen repaired by composite patch showed four times more improved fatigue life than the non-treated specimen.

• 대한치과교정학회지
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• 제28권5호
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• pp.803-812
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• 1998

도재의 표면처리가 세라믹 브라켓의 전단 접착강도에 미치는 영향과 브라켓 탈락 양상을 알아보기 위해 60개의 ceradent 도재 시편을 glazing 후 군당 10개씩 여섯 군으로 다음과 같이 분류하였다: 1군(silane), 2군(etching+silane), 3군(stone+silane), 4군(sandblasting+silane), 5군(stone+etching+silane), 6군(sandblasting+etching+silane) 통상적인 방법으로 세라믹 브라켓을 접착한 후 전단 접착강도를 측정하고 탈락양상을 육안 및 주사전자현미경으로 관찰하여 다음과 같주 결론을 얻었다. 1. 표면처리 후 silane을 도포한 2군부터 6군은 silane만을 도포한 1군에 비해 유의성 있는 전단 접착강도의 증가를 보였다(P<0.05). 2. 한 가지 방법 이상으로 표면처리한 3군부터 6군은 서로 유의한 차이를 보이지 않았다(P>0.05). 3. etching 표면 처리한 2군은 sandblasting 표면 처리한 4군과 복합 표면 처리한 5,6 군에 비해 전단 접착 강도가 낮았다. (p<0.05) 4. sandblasting 표면 처리한 4군은 주사 전자 현미경 소견상 복합 처리한 5,6군보다 감소된 요철 정도를 보였으나 전단접착 강도 측정 결과 유의한 차이를 보이지 않았다. (p>0.05) 이상의 결론을 종합해볼 때 도재에 세라믹 브라켓을 접착하기 위해서는 한가지 이상의 방법에 의한 도재의 표면처리 후 silane을 도포해야 임상적으로 적절한 접착강도를 얻을 수 있으며, 술식의 간편성을 고려할 때 sandblasting 후 silane 처리를 하는 것이 효율적일 것으로 사료된다.