• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.494-500
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• 2014

Indium-doped zinc oxide nanocrystals (IZO NCs), capped with stearic acid (SA) of different sizes, were synthesized using a hot injection method in a noncoordinating solvent 1-octadecene (ODE). The ligand exchange process was employed to modify the surface of IZO NCs by replacing the longer-chain ligand of stearic acid with the shorter-chain ligand of butylamine (BA). It should be noted that the ligand-exchange percentage was observed to be 75%. The change of particle size, morphology, and crystal structures were obtained using a field emission scanning electron microscope (FE-SEM) and X-ray diffraction pattern results. In our study, the 5 nm and 10 nm IZO NCs capped with stearic acid (SA-IZO) were ligand-exchanged with butylamine (BA), and were then spin-coated on a thermal oxide ($SiO_2$) gate insulator to fabricate a thin film transistor (TFT) device. The films were then annealed at various temperatures: $350^{\circ}C$, $400^{\circ}C$, $500^{\circ}C$, and $600^{\circ}C$. All samples showed semiconducting behavior and exhibited n-channel TFT. Curing temperature dependent on mobility was observed. Interestingly, mobility decreases with the increasing size of NCs from 5 to 10 nm. Miller-Abrahams hopping formalism was employed to explain the hopping mechanism insight our IZO NC films. By focusing on the effect of size, different curing temperatures, electron coupling, tunneling rate, and inter-NC separation, we found that the decrease in electron mobility for larger NCs was due to smaller electronic coupling.

• Journal of the Korean Physical Society
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• v.73 no.11
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• pp.1703-1707
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• 2018

Ferromagnetic ${\tau}-phase$ $Mn_{54}Al_{46}C_{2.44}$ particles were synthesized, and its composites with commercial $Sm_2Fe_{17}N_3$ and synthesized $Fe_{65}Co_{35}$ powders were fabricated. Smaller grain size than the single domain size of the $Mn_{54}Al_{46}C_{2.44}$ without obvious grain boundaries and secondary phases is the origin for the low intrinsic coercivity. It was confirmed that the magnetic properties of the $Mn_{54}Al_{46}C_{2.44}$ can be enhanced by magnetic exchange coupling with the hard magnetic $Sm_2Fe_{17}N_3$ and soft magnetic $Fe_{65}Co_{35}$. The high degrees of the exchange coupling were verified by calculating first derivative curves. Thermo-magnetic stabilities of the composites from 100 to 400 K were measured and compared. It was demonstrated that the $Mn_{54}Al_{46}C_{2.44}$ based composites containing $Sm_2Fe_{17}N_3$ and $Fe_{65}Co_{35}$ could be promising candidates for future permanent magnetic materials with the proper control of purity, magnetic properties, etc.

• Journal of Drive and Control
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• v.21 no.2
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• pp.44-52
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• 2024

In this study, we predicted PTO power requirements based on torque predicted by the discrete element method and the multi-body dynamics coupling method. Six different scenarios were simulated to predict PTO power requirements in different soil conditions. The first scenario was a tillage operation on cohesionless soil, and the field was modeled using the Hertz-Mindlin contact model. In the second through sixth scenarios, tillage operations were performed on viscous soils, and the field was represented by the Hertz-Mindlin + JKR model for cohesion. To check the influence of surface energy, a parameter to reproduce cohesion, on the power requirement, a simple regression analysis was performed. The significance and appropriateness of the regression model were checked and found to be acceptable. The study findings are expected to be used in design optimization studies of agricultural machinery by predicting power requirements using the discrete element method and the multi-body dynamics coupling method and analyzing the effect of soil cohesion on the power requirement.

• Electrical & Electronic Materials
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• v.10 no.5
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• pp.440-446
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• 1997

This research has been performed for the fabrication of high quality ferrite plastic magnet. The magnetic properties of S $r_{5.9}$F $e_2$ $O_3$ ferrite bonded magnets by injection moulding with a variety of applied magnetic field were investigated. 0.3wt% CaCO3, 0.2wt% $SiO_2$, 0.5wt% $Al_2$ $O_3$and 0.5wt% N $a_2$ $SiO_3$are added in order to improve the magnetic properties of Sr-ferrite plastic magnets during the powder fabrication. For carbon coating on chemical compound specimen, 5wt% polyvinyl alcohol is added, and then calcinated under $N_2$ environment of 12$25^{\circ}C$. The particle size is distributed from 0.9~1.2${\mu}{\textrm}{m}$ which approximates to the single domain. The obtained Sr ferrite powder is well mixed with silane coupling and calcium stearate of 1wt%. Nest, the specimen is pelleted after kneading each of them with polyamidel2 as a binder. When the temperature of injection and mould were 25$0^{\circ}C$ and 8$0^{\circ}C$ respectively at injection pressure of 200kgf/$\textrm{cm}^2$, the degree of orientation was 85.3% under the applied magnetic field of 12kOe. As the results, when the packing density of Sr ferrite powder was 90wt%, the magnetic properties of Sr ferrite bonded magnet were follows : $_{B}$ $H_{c}$=2.41kOe, Br=3.1kG, (BH)$_{max}$=2.21MgOe. Especially, the Sr-ferrite bonded magnet with 10wt% N $d_2$F $e_{14}$B additive were as follows : $_{B}$ $H_{c}$=2.57kOe, Br=3.14kG and (BH)$_{max}$=2.39MGOe.GOe.GOe.GOe.e.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.36 no.12
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• pp.1222-1228
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• 2008

A small satellite, DubaiSat-1 FM(Flight Model), which is based on SI-200 standard bus platform and scheduled to be launched in 2008, is being developed by Satrec Initiative and EIAST(Emirates Institution for Advanced Science and Technology). The TCS(Thermal Control Subsystem) of DubaiSat-1 FM has been designed to mainly utilize passive thermal control in order to minimize power consumption, but the active control method using heaters has been applied to some critical parts. Also, thermal analysis has been performed for DubaiSat-1's mission orbit using a thermal analysis model. The thermal design is modified and optimized to satisfy the design temperature requirements for all parts according to the analysis result. The thermal control performance of DubaiSat-1 FM is verified by thermal vacuum space simulation, consisting of thermal cycling and thermal balance test. Also, to validate the thermal modeling of DubaiSat-1 FM, comparison of test results with analysis has been performed and model calibration has been completed.

• Korean Journal of Optics and Photonics
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• v.6 no.4
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• pp.310-316
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• 1995

We designed the $1.3/1.55\mum$ WDM directional coupler and its coupling length was calculated with the variation of the two waveguide's core separation and other variables by the Fourier transformed scalar wave equation. We deposited the PSG films for optical waveguide by low pressure chemical vapor deposition and fabricated the WDM coupler using the laser lithography and $CF_4/O_2$ reactive ion etching process. A V -groove which was made to support and fix the optical fiber is fabricated on Si substrate by chemical etching. The WDM coupler and the V-groove are connected using UV curing epoxy. We found that propagation mode of each port of WDM coupler is single mode and maximum extinction ratio between two out ports is 6 dB for $1.3.\mum$, and 12 dB for $1.55\mum$. /TEX>.

• Journal of Magnetics
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• v.8 no.1
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• pp.1-6
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• 2003

The new class of $Gd_5(Si_xGe_{1-x})_4$ compounds undergoes a simultaneous magnetic/structural phase transition giving a high level of strain that can be induced either by change in temperature or by application of a magnetic field. Profound changes of structural, magnetic, and electronic changes occur in the $Gd_5(Si_xGe_{1-x})_4$ system lead to extreme behavior of the material such as the giant magnetocaloric effect, colossal magnetostriction, and giant magnetoresistance. These unique material characters can be utilized for various applications including magnetic solid refrigerants, sensors, and actuators.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.331-332
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• 2008

Couplings between electric, magnetic, and structural order parameters result in the so-called multiferroic phenomena with two or more ferroic phenomena such as ferroelectricity, ferromagnetism, or ferroelasticity. The simultaneous ferroelectricity and ferromagnetism (magnetoelectricity) permits potential applications in information storage, spintronics, and magnetic or electric field sensors. The perovskite BiFeO3(BFO) is known to be antiferromagnetic below the Neel temperature of 647K and ferroelectric with a high Curie temperature of 1043K. It exhibits weak magnetism at room temperature due to the residual moment from a canted spin structure. It is likely that non-stoichiometry and second-phase formation are the factors responsible for leakage current in BFO. It has been suggested that oxygen non-stoichiometry leads to valence fluctuations of Fe ions in BFO, resulting in high conductivity. To reduce the large leakage current of BFO, one attempt is to make donor-doped BFO compounds and thin films. In this study, (Bi1-x,Ndx)(Fe1-y,Tiy)O3 thin films have been deposited on Pt(111)/TiO2/SiO2/Si substrates by pulsed laser deposition. The effect of dopants on the phase evolution and surface morphology are analyzed. Furthermore, electrical and magnetic properties are measured and their coupling characteristics are discussed.

• Polymer(Korea)
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• v.26 no.5
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• pp.607-614
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• 2002

Polyorganosiloxane(HBPS) modified polyurethane (UMPS) was synthesized to improve weatherability in the polyurethane (ITPU) sealant and its rheological propoerty was investigated. It was found that the viscosity increased with increasing HBPS content in polyurethane and maximum viscosity was observed in UMPS having 70/30 ITPU/HBPS ratio. This was understood that the segregation of HBPS segment in UMPS chain has been developed. Further increasing of the content of HBPS resulted in the lowering of viscosity because of the flexibility of HBPS block segment in UMPS chain. It was also found that UMPS has more sensitive environmental dependency of viscosity than ITPU such as shear rate, humidity and temperature. In additions, UMPS having Si(O$CH_3$)$_3$ end group (TUMPS) by adding coupling agent up to 0.3 wt% resulted in the increase of viscosity by the acceleration of curing. But introducing more than 0.5wt% curing agent to TUMPS caused the lowering of viscosity because of less NCO group in TUMPS for the curing.

• Current Optics and Photonics
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• v.5 no.1
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• pp.1-7
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• 2021

For higher sensitivity in ultraviolet (UV) and even vacuum ultraviolet (VUV) detection of silicon-based sensors, a sandwich-structured film sensor based on Ag Localized Surface Plasmon Resonance (LSPR) was designed and fabricated. This film sensor was composed of a Ag nanoparticles (NPs) layer, SiO2 buffer and fluorescence layer by physical vapour deposition and thermal annealing. By tuning the annealing temperature and adding the SiO2 layer, the resonance absorption wavelength of Ag NPs matched with the emission wavelength of the fluorescence layer. Due to the strong plasmon resonance coupling and electromagnetic field formed on the surface of Ag NPs, the radiative recombination rate of the luminescent materials and the number of fluorescent molecules in the excited state increased. Therefore, the fluorescent emission intensity of the sandwich-structured film sensor was 1.10-1.58 times at 120-200 nm and 2.17-2.93 times at 240-360 nm that of the single-layer film sensor. A feasible method is provided for improving the detection performance of UV and VUV detectors.