• Title/Summary/Keyword: Si membrane

Search Result 396, Processing Time 0.029 seconds

Process Development of Wastewater Containing Silicon Fine Particles by Ultrafiltration for Water Reuse -III. Permeation Characteristics of Pilot Scale Hollow Fiber Membrane Modules- (한외여과에 의한 Si 미립자 함유폐수 재이용 공정개발(III) -Pilot-Scale 중공사막 모듈에 의한 투과 특성)

  • 전재홍;함용규;이석기;박영태;남석태;최호상
    • Membrane Journal
    • /
    • v.9 no.3
    • /
    • pp.185-192
    • /
    • 1999
  • The ultrafiltration characteristics of wafer processing wastewater produced from semicon¬ductor industry was investigated for wastewater reuse. Using the pilot-scale ultrafiltration system con¬taining poly sulfone hollow fiber membranes (MWCO : 10,000, 20,000, 30,(00), the membrane performance, such as flux, rejection rate and concentration factor for flux was examined. The SDhs, turbidity, electrical conductivity and concentration of Si particles were measured, and the possibility of permeate reuse was validated from the experimental results. It was shown that the flux was recovered by the sweeping with air and water effectively. The permeate flux of 30,000 MWCO membrane was about 5 times higher than that of 10,000 and 20,000 MWCO membranes. The concentration of Si particle in the saw wastewater was analyzed 3.8-5.6 mg/$\ell$ and that of Si particle in the permeate was analyzed less than 0.2${\mu}g$/$\ell$. This means the rejection of silicon particle was over 96%.

  • PDF

Synthesis of Microporous Zeolitic Membranes and Application in Alcohol/water Separation (다공성 제올라이트 멤브레인의 합성 및 알코올 /물 분리에의 응용)

  • 김건중;남세종
    • Membrane Journal
    • /
    • v.9 no.2
    • /
    • pp.97-106
    • /
    • 1999
  • A and 2SM-5 type zeoli tic crystal films were synthesized on porous supports from the reaction mixture of 1.9 ${SiO}_2$1.5 $Na_20-Al_2O_3-40$ $H_20$ and $Si0_2$-0.l3 $Na_2O$-52 $H_20$-O.l2 TPAOH composition, respectively. The zeolite films were characterized by XRD and SEM. The 2SM -5 crystals grown on the porous matrix were very closely bound together. It was so difficult to obtain the perfectly intergrown crystals in the case of A-type zeolite and this crystal was transformed into P-type zeolite membrane with a prolonged reaction time. The densely intergrown A type zeolite crystal membrane could be also synthesized by the hydrothermal treatment at 100$^{\cirt}C$ after pressing the reaction mixture without addition of water. The pervaporation performance of the synthesized porous inorganic membranes was investigated for alcohol and water mixtures. A-type zeolite membrane crystallized as a thin film showed the selective \'Jermeability of water from the mixtures through the molecular sieving activity of micropores.

  • PDF

Fabrication and characteristic of thin-film NTC thermal sensors (박막형 NTC 열형 센서의 제작 및 특성 평가)

  • Yoo, Mi-Na;Lee, Moon-Ho;Yu, Jae-Yong
    • Journal of Sensor Science and Technology
    • /
    • v.15 no.1
    • /
    • pp.65-70
    • /
    • 2006
  • Characteristics of thin-film NTC thermal sensors fabricated by micromachining technology were studied as a function of the thickness of membrane. The overall-structure of thermal sensor has a form of Au/Ti/NTC/$SiO_{X}$/(100)Si. NTC film of $Mn_{1.5}CoNi_{0.5}O_{4}$ with 0.5 mm in thickness was deposited on $SiO_{X}$ layer (1.2 mm) by PLD (pulsed laser deposition) and annealed at 873-1073 K in air for 1 hour. Au(200 nm)/Ti(100 nm) electrode was coated on NTC film by dc sputtering. By the results of microstructure, X-ray and NTC analysis, post-annealed NTC films at 973 K for 1 hour showed the best characteristics as NTC thermal sensing film. In order to reduce the thermal mass and thermal time constant of sensor, the sensing element was built-up on a thin membrane with the thickness of 20-65 mm. Sensors with thin sensing membrane showed the good detecting characteristics.

Fabrication of Nickel Oxide Film Microbolometer Using Amorphous Silicon Sacrificial Layer (비정질 실리콘 희생층을 이용한 니켈산화막 볼로미터 제작)

  • Kim, Ji-Hyun;Bang, Jin-Bae;Lee, Jung-Hee;Lee, Yong Soo
    • Journal of Sensor Science and Technology
    • /
    • v.24 no.6
    • /
    • pp.379-384
    • /
    • 2015
  • An infrared image sensor is a core device in a thermal imaging system. The fabrication method of a focal plane array (FPA) is a key technology for a high resolution infrared image sensor. Each pixels in the FPA have $Si_3N_4/SiO_2$ membranes including legs to deposit bolometric materials and electrodes on Si readout circuits (ROIC). Instead of polyimide used to form a sacrificial layer, the feasibility of an amorphous silicon (${\alpha}-Si$) was verified experimentally in a $8{\times}8$ micro-bolometer array with a $50{\mu}m$ pitch. The elimination of the polyimide sacrificial layer hardened by a following plasma assisted deposition process is sometimes far from perfect, and thus requires longer plasma ashing times leading to the deformation of the membrane and leg. Since the amorphous Si could be removed in $XeF_2$ gas at room temperature, however, the fabricated micro-bolomertic structure was not damaged seriously. A radio frequency (RF) sputtered nickel oxide film was grown on a $Si_3N_4/SiO_2$ membrane fabricated using a low stress silicon nitride (LSSiN) technology with a LPCVD system. The deformation of the membrane was effectively reduced by a combining the ${\alpha}-Si$ and LSSiN process for a nickel oxide micro-bolometer.

A study on wet etching for silicon membrane construction formation (실리콘 Membrane 구조 형성을 위한 Wet Etching에 관한 연구)

  • 김동수;정원채
    • Proceedings of the IEEK Conference
    • /
    • 2001.06b
    • /
    • pp.237-240
    • /
    • 2001
  • In this paper, we have presented processing technique about wet etching for silicon membrane construction formation. In order to make selective etching of backside silicon wafer, we used Si$_3$N$_4$ layer by PECVD(Plasma Enhanced Chemical Vapor Deposition). We have measured the surface thickness in backside silicon wafer after anisortropic wet etching with KOH:distilled water solutions. Through this experiment, we acquired the etching rate for 1.29${\mu}{\textrm}{m}$/min. The average rough of Si-membrane frontside and backside was 0.26${\mu}{\textrm}{m}$, 0.90${\mu}{\textrm}{m}$, respectively.

  • PDF

Photovoltaic Performance of Dye-sensitized Solar Cells assembled with Hybrid Composite Membrane based on Polypropylene Non-woven Matrix

  • Choi, Yeon-Jeong;Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.2
    • /
    • pp.605-608
    • /
    • 2011
  • Hybrid composite membranes were prepared by coating poly(ethylene oxide) and $SiO_2$ particles onto the porous polypropylene nonwoven matrix. Gel polymer electrolytes prepared by soaking the hybrid composite membranes in an organic electrolyte solution exhibited ionic conductivities higher than $1.1{\times}10^{-3}Scm^{-1}$ at room temperature. Dyesensitized solar cell (DSSC) employing the hybrid composite membrane with PEO and 10 wt % $SiO_2$ exhibited an open circuit voltage of 0.77 V and a short circuit current of 10.78 $mAcm^{-2}$ at an incident light intensity of 100 $mWcm^{-2}$, yielding a conversion efficiency of 5.2%. DSSC employing the hybrid composite membrane showed more stable photovoltaic performance than that of the DSSC assembled with liquid electrolyte.

Characteristics of Hot-Film Type Micro-Flowsensors Fabricated on SOI Membrane and Trench Structures (SOI 멤브레인과 트랜치 구조상에 제작된 발열저항체형 마이크로 유량세선의 특성)

  • 정귀상;김미목;남태철
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.14 no.8
    • /
    • pp.658-662
    • /
    • 2001
  • This paper describes on the fabrication and characteristics of hot-film type micro-flowsensors integrated with Pt-RTD(resistance thermometer device) and micro-heater on the SOI(Si-on-insulator) membrane and trench structures, in which MGO thin-film was used as medium layer in order to improve adhesion of Pt thin-film to SiO$_2$ layer. Output voltages increased due to increase of heat-loss from sensor to external. The output voltage was 250 nV at N$_2$ flow rate of 2000 sccm/min, heating power of 0.3 W. The response time($\tau$:63%) was about 42 msec when input flow was step-input. The results indicated that micro-flowsensors with the SOI membrane and trench structures have properties of a high-resolution and ow consume power.

  • PDF

Thickness Optimization of SiO2/Al2O3 Stacked Layer for High Performance pH Sensor Based on Electrolyte-insulator-semiconductor Structure (SiO2/Al2O3 적층 감지막의 두께 최적화를 통한 고성능 Electrolyte-insulator-semiconductor pH 센서의 제작)

  • Gu, Ja-Gyeong;Jang, Hyun-June;Cho, Won-Ju
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.25 no.1
    • /
    • pp.33-36
    • /
    • 2012
  • In this study, the thickness effects of $Al_2O_3$ layer on the sensing properties of $SiO_2/Al_2O_3$ (OA) stacked membrane were investigated using electrolyte-insulator-semiconductor (EIS) structure for high quality pH sensor. The $Al_2O_3$ layers with a respective thickness of 5 nm, 15 nm, 23 nm, 50 nm, and 100 nm were deposited on the 5-nm-thick $SiO_2$ layers. The electrical characteristics and sensing properties of each OA membranes were investigated using metal-insulator-semiconductor (MIS) and EIS devices, respectively. As a result, the OA stacked membrane with 23-nm-thick $Al_2O_3$ layer shows the excellent characteristics as a sensing membrane of EIS sensor, which can enhance the signal to noise ratio.

Characteristics and Fabrication of Optimal Thermopile on SiNx Membrane for Microspectrometer (마이크로 스펙트로미터 적외선 센서용 저응력 SiNx Membrane상에서의 최적화된 Thermopile 제작 및 특성)

  • Kim, Dong-Sik
    • 전자공학회논문지 IE
    • /
    • v.44 no.1
    • /
    • pp.6-9
    • /
    • 2007
  • Twenty four types of thermopile for micro spectrometer infrared sensors were fabricated on low-stress Si3N4 membranes with $l.2{\mu}m-thickness$ using MEMS technology. Thermopile were designed and fabricated for optimum conditions by five parameters of thermocouple numbers $(16\sim48)$, thermocouple line widths $(10{\mu}m-25{\mu}m)$, thermocouple lengths $(100{\mu}m-500{\mu}m)$, membrane areas $(12mm2\sim2.52mm2)$ and junction areas $(150{\mu}m2\sim750{\mu}m2)$, respectively. It was thought that measurement results could be used for thermopile infrared sensors optimum structure for micro spectrometers.

Preparation and Characterizations of poly(arylene ether sulfone)/SiO2 Composite Membranes for Polymer Electrolyte Fuel Cell (고분자 전해질 연료전지(PEFC)용 poly(arylene ether sulfone)/SiO2 복합막의 제조 및 특성분석)

  • Shin, Mun-Sik;Kim, Da-Eun;Park, Jin-Soo
    • Membrane Journal
    • /
    • v.27 no.2
    • /
    • pp.182-188
    • /
    • 2017
  • Sulfonated poly(arylene ether sulfone) (SPAES)-3-mercaptopropyl silica gel (3MPTSG) composite membranes with improved oxidative stability were prepared for polymer electrolyte fuel cell application. It has been reported that ether part of main chain of aromatic hydrocarbon based membranes were weak to radical attack to decrease membrane durability. In this study, the hydrophilic inorganic particles were introduced by minimizing a decrease in ion conductivity and increasing an oxidative stability. The composite membranes were investigated in terms of ionic conductivity, ion exchange capacity (IEC), FT-IR, TGA and contact angle, etc. As a result, increasing amount of the 3MPTSG resulted in decrease in proton conductivities and water uptakes at 100% R.H. but enhanced thermal and oxidative stabilities.