• Title/Summary/Keyword: Si/Al ratio

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Effect of nano-stabilizer on geotechnical properties of leached gypsiferous soil

  • Bahrami, Reza;Khayat, Navid;Nazarpour, Ahad
    • Geomechanics and Engineering
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    • v.23 no.2
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    • pp.103-113
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    • 2020
  • Gypsiferous soils classified as problematic soils due to the dissolution of gypsum. Presence of gypsum in the soils texture subjected to steady flow can cause serious damages for the buildings, roads and water transmission canals. Therefore, researchers have conducted a series of physical, mechanical and microstructural laboratory tests to study the effect of gypsum leaching on the geotechnical properties of a lean clay containing 0%, 3%, 6%, 9%, 12%, and 15% raw gypsum. In addition, a combination of two nano-chemical stabilizers named Terrasil and Zycobond was used in equal proportions to stabilize the gypsiferous clayey samples. The results indicated that gypsum leaching considerably changed the physical and mechanical properties of gypsiferous soils. Further, adding the combination of Terrasil and Zycobond nano-polymeric stabilizers to the gypsiferous soil led to a remarkable reduction in the settlement drop, compressibility, and electrical conductivity (EC) of the water passing through the specimens, resulting in improving the engineering properties of the soil samples. The X-ray diffraction patterns indicate that stabilization by terrasil and zycobond causes formation of new peaks such as CSH and alteration of pure soil structure by adding raw gypsum. Scanning electron microscope (SEM) images show the denser texture of the soil samples due to chemical stabilization and decrease of Si/Al ratio which indicates by Energy dispersive X-ray (EDS) interpretation, proved the enhance of shear strength in stabilized samples.

Lean Combustion Characteristics in a S.I Engine with SCV by Operating Conditions (SCV 가솔린 엔진의 운전조건에 따른 희박연소 특성)

  • Choi, Su-Jin;Jeon, Chung-Hwan;Chang, Young-June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.2
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    • pp.161-168
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    • 2000
  • Lean combustion in a SI engine is one of the best solution for the improvement of fuel economy and reduction of pollutant emission. In order to access a lean combustion engine, stable combustion at lean AlF ratio is needed. In this paper, the effect of fuel injection timing on lean misfire limit has been investigated in an MPI engine. To investigate the interaction of injection timing and intake flow characteristics, three different swirl generating SCV(swirl control valve) configurations were considered, and investigated their effects on lean misfire limit and torque at full load operation. Also the effects of spark timing on lean combustion has been investigated. Lean combustion has been examined and the results are reported in this paper. SCV B has been developed to satisfy the requirements of sufficient swirl generation to improve lean combustion and stable performance. It is found that injection timing, spark timing and intake air motion govern the stable lean combustion.

A Study of the Fabrication and Enhancement of Film Bulk Acoustic Wave Resonator using Two-Step Deposition Method of Piezoelectric Layer (압전층의 2단 증착법을 이용한 체적 음향파 박막형 공진기의 제작과 성능향상에 관한 연구)

  • Park Sung-Hyun;Chu Soon-Nam;Lee Neung-Heon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.7
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    • pp.308-314
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    • 2005
  • The 2 GHz film bulk acoustic wave resonator(FBAR), one of the most necessary device of the next generation mobile communication system, consisted of solidly mounted resonator(SMR) structure using Brags reflector, was researched in this paper The FBAR applied SiO$_{2}$ and W had large difference of the acoustic impedance to reflector Al to electrode and ZnO to piezoelectric layer. Specially, the FBAR applied the two-step deposition method to improve the c-axis orientation and increase reproducibility of the fabrication device had good performance. The electrical properties of plasma such as impedance, resistance, reactance, $V_{pp},\;I{pp}$, VSWR and phase difference of voltage and current, was analyzed and measured by RF sensor with the variable experiment process factors such as gas ratio, RF power and base vacuum level about concerning the thickness, c-axis orientation, adhesion and roughness. The FBAR device about the optimum condition resulted reflection loss(S$_{11}$) of -17 dB, resonance frequency of 1.93 GHz, electric-mechanical coefficient(k$_{eff}$) of 2.38 $\%$ and Qualify factor of 580. It was seen better qualify than the common dielectric filter at present and expected on business to the filter device of 2 GHz bandwidth with the MMIC technology.

Friction and Wear Characteristics of Bonded Film Lubricants of Organically Modified Hybrid Ceramic Binder Materials (유기변성 하이브리드 세라믹 물질을 결합제로 이용한 고체피막윤활제의 마찰마모 특성)

  • 한흥구;공호성;윤의성
    • Tribology and Lubricants
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    • v.19 no.4
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    • pp.203-210
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    • 2003
  • In order to enhance the thermal stability of binder materials of bonded type solid lubricants, several metal-alkoxide based sol-gel materials such as methyltrimethoxysilane(MTMOS), titaniumisopropoxide (Ti(Opr$\^$i/)$_4$), zirconiumisopropoxide (Zr(Opr$\^$i/)$_4$) and aluminumbutoxide (Al(Obu$\^$t/)$_4$) were modified chemically by both epoxy and acrylic silane compounds. Friction and wear characteristics of the bonded solid lubricants, whose binders were of several hybrid ceramic materials, were tested with a reciprocating tribo-tester. Wear life was evaluated with respect to the heat-curing temperature, friction temperature, type of supplement lubricants, and ratio of binder materials. Test results showed that the Si-Zr hybrid ceramic materials modified by epoxy-silane compounds had a higher wear life compared to others. Sb$_2$O$_3$ was the most effective supplement lubricants in the high temperature, and BUS analyses revealed that it was caused mainly by a strong anti-oxidation effect to MoS$_2$ particles. The higher heat-curing temperature resulted in the higher wear life, and the higher friction temperature resulted in the lower wear life.

The Sintering Mechanism and Crystallization Characteristics of Alumina-filled Cordierite-type Glass-ceramics (알루미나를 첨가한 코디어라이트계 결정화 유리의 소결거동 및 결정화 특성)

  • 박정현;노재호;성재석;구기덕
    • Journal of the Korean Ceramic Society
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    • v.35 no.7
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    • pp.706-714
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    • 1998
  • The MgO-{{{{ { {Al }_{2 }O }_{3 } }}-{{{{ { {SiO }_{2 } }_{ } }}system containing alumina powder was fabricated sintered at various temperature and analyzed in order to study the sintering mechanism and crystallization characteristics. The specimen composed of glass powder with average particle size of 8.27 $\mu\textrm{m}$ and 0-40 vol% alumina powder were sint-ered for 3 hrs at the temperature between 850$^{\circ}C$ and 1350$^{\circ}C$ The sintering mechanism consists of the redis-tribution of particles occuring at 750$^{\circ}C$ and the viscous flow at 850∼950$^{\circ}C$. The degree of crystallization and sintering temperatue were dependent upon the ratio of glass/alumina. The second phase from the reaction between glass and alumina was not observed which was confirmed by XRD and properties analysis. The density dielectric constant and specific resistivity of specimen were 2.30∼3.26g/cm2 5.8∼7.38 at 1 GHz density dielectric constant and specific resistivity of specimen were 2.30∼3.26g/cm3 5.8∼7.38 at 1GHz and 1.23∼4.70${\times}$107 $\Omega$$.$m respectively.

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Energy-band-gap Variation of InxGaN1-x Thin Films with Indium Composition (인듐량에 따른 InxGaN1-x 박막의 에너지밴드갭 변화)

  • Park, Ki-Cheol;Ma, Tae-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.8
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    • pp.677-681
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    • 2009
  • $In_xGa_{1-x}N$ alloys with 20-nm-thickness were deposited onto Mg:GaN/AlN/SiC substrates by MOCVD at $800\;^{\circ}C$. TMGa, TMIn and $NH_3$ were used as the precursor of gallium, indium and nitrogen, respectively. The mole ratio of indium in $In_xGa_{1-x}N$ films varied between 0 and 0.2. The energy-band-gaps of the films were obtained from the photoluminescence and cathodoluminescence peaks. The mole ratios of $In_xGa_{1-x}N$ films were calculated by applying Vegard's law to XRD results. The energy-band-gap versus indium composition plot for $In_xGa_{1-x}N$ alloys were well fit with a bowing parameter of 2.27.

Development of chemical conversion coating process for Mg-Al alloy and its anti-corrosion property (마그네슘-알루미늄 합금의 화성처리 공정 개발과 그 내식성 평가)

  • Kim, Seong-Jong
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.265-266
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    • 2006
  • The chemical conversion coating formed on magnesium alloy investigated for low cost and harmless in environment by using the colloidal silica as the main component. The film formed in 298 K is thick, the film, which was thought combination of Si-O, was formed. The film formed in 313 K is thinner than that in 298 K. The quantity of film formed at high temperature such as 333 K and 353 K is smaller than dissolved quantity. At the anodic polarization experiment, corrosion resistance in sealing by hot water after chemical conversion treatment in basic solution condition get worse than that in comparison with basic solution condition. In salt spray test, the ratio of black rust on specimen that did not conducted chemical conversion treatment was five times or more compared with those of chemical conversion treated specimen. The film thickness of chemical conversion coating produced by alkali treatment process is thinner than in comparison with that of specimen produced in basic chemical conversion treatment solution condition. It is thought, however, that it showed good corrosion resistance during salt spray test because the area of microcracks is small.

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Low k Materials for High Frequency High Integration Modules

  • Na, Yoon-Soo;Lim, Tae-Young;Kim, Jin-Ho;Shin, Hyo-Soon;Hwang, Jong-Hee;Cho, Yong-Soo
    • Journal of the Korean Ceramic Society
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    • v.46 no.4
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    • pp.413-418
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    • 2009
  • Glass systems based on Ca, Sr, Ba, and Zn modified alumino-boro silicates were investigated in order to improve the dielectric and mechanical properties of a typical LTCC (low temperature co-fired ceramic) which was developed for high frequency highly-integrated modules. The glass was prepared by a typical melting procedure and then mixed with cordierite fillers to fabricate glass/ceramic composite-type LTCC materials. The amount of cordierite filler was fixed at 50 volumetric%. For an optimal glass composition of 7.5% CaO, 7.5% BaO, 5% ZnO, 10% $Al_2O_3$, 30% $B_2O_3$, and 40% $SiO_2$ in mole ratio, the resultant LTCC composite showed a dielectric constant of 5.8 and a dielectric loss ($tan{\delta}$) of 0.0009 after firing at $900^{\circ}C$. An average bending strength of 160MPa was obtained for the optimal composition.

Adsorption of Pentachlorophenol (PCP) on Clay Minerals from Hexane Solution (Hexane 용액중(溶液中)에서 점토용물(粘土鏞物)에 의(依)한 PCP 흡착(吸着))

  • Choi, Jyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.7 no.3
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    • pp.141-145
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    • 1974
  • Adsorption experiments were carried out with several clay minerals and PCP hexane solution in order to clarify the status of adsorbed PCP on the clay surface. The amount of PCP adsorption on clay minerals was much greater in the clay-hexane system than in the clay water system. Among the clay minerals, allophane and imogolite ($SiO_2/Al_2O_3$ ratio of about 1) were the most efficient adsorbents of PCP. The PCP adsorption from hexane solution was greatly hindered by the presence of water, suggesting the occurrence of adsorption by a dipole-dipole interaction. PCP adsorption is dependent upon the nature of the clay surface and the exchangeable cations rather than the total surface area.

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The Influences of Water Vapor/Hydrogen Ratio, Gas-Flow Rate and Antimony on the Surface Oxidation of Trip Steels

  • Kwon, Youjong;Zhu, Jingxi;Sohn, Il-Ryong;Sridhar, Seetharaman
    • Corrosion Science and Technology
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    • v.10 no.6
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    • pp.189-193
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    • 2011
  • In the current paper, we are reporting the results from an investigation of the surface and sub-surface oxidation of a TRIP steel containing 2 wt.% Mn and 0.5 wt.% Al with and without 0.03 wt.% Sb. The oxidizing conditions in the gas were successively varied in terms of the linear gas flow-rate and dew-point, from conditions were gas-phase mass transport limited conditions prevailed, to those were solid state processes became the rate determining conditions. It was found, that at sufficient low oxidizing conditions (defined as flow-rate/dew-point), the metal surfaces were clear of any external oxides, and as the oxidizing conditions were increased, Mn- and Si- oxide nodules formed along with magnetite. As the oxidizing conditions were increased further, a dense magnetite layer was present. The limits of the various regions were experimentally quantified and a proposed hypothesis for their occurrences is presented. No obvious effect of Sb was noted in this micro-structural research of the oxides that results from the various conditions investigated in this study.