• 마이크로전자및패키징학회지
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• 제24권1호
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• pp.1-8
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• 2017

Fe-9.8Si-6.0Al mother alloy was manufactured using by Fe-3.5Si recycled scrap and Si powder. And then, soft magnetic alloy powder of $D_{50}$ size and sphere type were prepared by gas atomization process. To obtain the soft magnetic powder of a high aspect ratio, in the first, we conducted the ball milling process for 8 hours. And heat treatment was performed under $650^{\circ}C$, 2 hours and $N_2$ atmosphere condition for reducing the residual stress of the powder. Based on these process, we made around $50{\mu}m$ diameter Fe-9.8Si-6.0Al powder, which morphology and shape was a similar to the commercial Fe-Si-Al powder. Finally, the soft magnetic sheets were prepared by tape casting process using by those powders. The permeability of the tape casting sheet was measured, and we confirmed the possibility of reusing to the soft magnetic materials of Fe-Si electric sheet scrap.

• 한국세라믹학회지
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• 제18권1호
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• pp.41-47
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• 1981

The sintering characteristics of the SiC-Clay-Kaolin chamotte system were studied by addition of $Al_2O_3$ for the manufacture of silicate-bonded silicon carbide refractories at $1350^{\circ}C$. The sinterbilit of SiC-Binder mixture was measured by apparent porosity and compressive strength. And its mineral compositions were identified with X-ray diffractometer. The following results were obtained; 1) Optimum amount of mixed clay ($\textrm{Al}_2\textrm{O}_3$ 40 wt% mixed) as a binder was about 25wt% 2) Appropriate mixing ratio of mixed Kaolin chamotte ($\textrm{Al}_2\textrm{O}_3$ 40wt% mixed) was about 30wt% in the clay Kaolin chamotte binder. 3) Variation of apparent porosity and compressive strength of sintered SiC-binder mixture fired at $1350^{\circ}C$ were due to the sinterbility of clay.

• 한국전기전자재료학회논문지
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• 제25권1호
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• pp.33-36
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• 2012

In this study, the thickness effects of $Al_2O_3$ layer on the sensing properties of $SiO_2/Al_2O_3$ (OA) stacked membrane were investigated using electrolyte-insulator-semiconductor (EIS) structure for high quality pH sensor. The $Al_2O_3$ layers with a respective thickness of 5 nm, 15 nm, 23 nm, 50 nm, and 100 nm were deposited on the 5-nm-thick $SiO_2$ layers. The electrical characteristics and sensing properties of each OA membranes were investigated using metal-insulator-semiconductor (MIS) and EIS devices, respectively. As a result, the OA stacked membrane with 23-nm-thick $Al_2O_3$ layer shows the excellent characteristics as a sensing membrane of EIS sensor, which can enhance the signal to noise ratio.

• 한국세라믹학회지
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• 제28권12호
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• pp.961-968
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• 1991

The nature and composition of the surfaces of silicon nitride and β-Sialon powders were investigated using high voltage and high resolution transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). β-Sialon powder was produced from Hadong kaolin by the carbothermic reduction and simultaneous nitridation. XPS showed that Al was contained in the surface of β-Sialon powder besides Si, N and O components, which is different from that of silicon nitride. It was supposed that Al in the surface of β-Sialon was bonded with oxygen from the oxygen-nitrogen ratio and the measurement of Al 2p binding energies. After both silicon nitride and β-Sialon powders were oxidized at 800℃ for 24h in air, nitrogen didn't exist in the surfaces and the depth of the oxide layer increased. The measurement of Si 2p binding energies showed that the chemical shifts occurred from Si3N2O and/or Si2N2O to SiO2 phase.

• 한국주조공학회지
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• 제30권1호
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• pp.22-28
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• 2010

Metal foam is a porous or cellular structure material and representative property is a very high porosity. Foamed materials have very special properties such as sound, vibration, energy and impact absorption capacity. Especially this properties are widely used for safety demands of architecture, auto and aircraft industry. But metal foam need to increased its compression strength and hardness. This study were researched about Al-Si alloy foams with variation amount of Si contents for their fabrication and properties such as porosity, cell structure, microstructure and mechanical properties. The result are that the range of pore size is 2~4 $mm{\phi}$, the high porosity are 88%, high yield strength is 1.8MPa, the strain ratio is 60~70% and vickers hardness is 33.1~50.6.

• 한국주조공학회지
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• 제17권4호
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• pp.365-370
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• 1997

The effects of changes in microstructure of Si phase on the thermal expansion coefficients(CTEs) and tensile properties of the hypereutectic Al-Si foundry alloy(A390) were investigated experimentally. Specimens were prepared by various fabrication processes, such as a permanent mold casting, a squeeze casting and a spray casting process, and subsequently hot-extruded. CTEs of the spray-cast specimen were found to be about 10% lower than those of the permanent mold-cast specimen, and the CTEs of the hypereutectic Al-Si alloy(A390) were changed proportionally with the size of Si phase. Ultimate tensile strength of the spray-cast and hot-extruded specimen was dramatically improved about 100% with improved elongation, compared to that of permanent mold-cast specimen. These improvements are mainly attributed to the reduction in size and aspect ratio of the brittle Si phase, and the elimination of the microvoids/porosities formed during casting.

• 전기전자학회논문지
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• 제22권4호
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• pp.1230-1233
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• 2018

에어로졸 데포지션 (aerosol deposition)공정을 통해 $Al_2O_3$막을 4H-SiC 상에 50 nm 두께로 제조하였고, 후열처리 공정에 따른 전기적 특성을 분석하였다. 그 결과 $N_2$분위기 열처리 시 $Al_2O_3$와 SiC 계면의 고정전하량이 감소하였으나 산소공공 생성에 의한 누설전류의 증가를 확인하였다. 본 결과로부터 계면특성 향상과 누설전류의 감소를 위해서는 적절한 $N_2$와 $O_2$가스의 혼합이 중요함을 확인하였다.

• 한국세라믹학회지
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• 제37권3호
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• pp.247-255
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• 2000

Silicon carbide with sialon was prepared by hot pressing and transient liquid-phase sintering, and the effects of sintering atmosphere and starting phases on their microstructural characteristics were investigated. The sintered SiC with Sialon composition(Y2O3, AlN, Si3N4) in argon atmosphere had high sintered density and large aspect ratio. But sintered specimens in nitrogen atmosphere showed low aspect ratio and small grian size, becuase of the retardation of phase transformation and grain growth. Addition of Y-Sialon powder to SiC also retarded the phase transformation to ${\alpha}$-SiC from ${\beta}$-SiC and densification. The SiC specimen prepared from the starting ${\beta}$-SiC powder with Sialon composition(Y2O3, AlN, Si3N4) showed the highest fracture toughness about 6.0 MPa$.$m1/2.

• 한국표면공학회지
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• 제49권6호
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• pp.580-586
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• 2016

Cr-Si-Al-N coating with different Si content were deposited by hybrid physical vapor deposition (PVD) method consisting of unbalanced magnetron (UBM) sputtering and arc ion plating (AIP). The deposition temperature was $300^{\circ}C$, and the gas ratio of $Ar/N_2$ were 9:1. The CrSi alloy and aluminum targets used for arc ion plating and sputtering process, respectively. Si content of the CrSi alloy targets were varied with 1 at%, 5 at%, and 10 at%. The phase analysis, composition and microstructural analysis performed using x-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) including energy dispersive spectroscopy (EDS), respectively. All of the coatings grown with textured CrN phase (200) plane. The thickness of the Cr-Si-Al-N films were measured about $2{\mu}m$. The friction coefficient and removal rate of films were measured by a ball-on-disk test under 20N load. The friction coefficient of all samples were 0.6 ~ 0.8. Among all of the samples, the removal rate of CrSiAlN (10 at% Si) film shows the lowest values, $4.827{\times}10^{-12}mm^3/Nm$. As increasing of Si contents of the CrSiAlN coatings, the hardness and elastic modulus of CrSiAlN coatings were increased. The morphology and composition of wear track of the films was examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy, respectively. The surface energy of the films were obtained by measuring of contact angle of water drop. Among all of the samples, the CrSiAlN (10 at% Si) films shows the highest value of the surface energy, 41 N/m.

• 한국세라믹학회지
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• 제31권9호
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• pp.1069-1075
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• 1994

When ceramics are used as the parts of an engine and a machine, the tribological properties are very important. For the preparation of the resistance material for wear applications by the method of Reaction-Bonded Sintering, metal silicon and carbon black are mixed up into SiC powder, and Al2O3 and Fe2O3 are put as an additive. As the general properties, the bending strength and water absortion are measured in the normal temperature and the phase changies are investigated with XRD. The property of the resistance for wear applications is measured with the amount of friction and wear, friction coefficient and maximum asperties. And, the surface of wear is observed with SEM. With the results of this study, the optimal mol ratio of Si : C and the suitable quantity of the mixture of SiC are 7 : 3 and 40 wt%, respectively. In the case of the addition of Al2O3 (2 wt%), the resistance for friction and wear applications is prominent. The bending strength showed the highest peak when Al2O3 (4 wt%) and Fe2O3 (4 wt%) were added. The properties of friction and wear were related with the propagation velocity of crack rather than the bending strength.