• Title/Summary/Keyword: Shear thinning index

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Shear Thinning Effects by VII Added Lubricant with In-Situ Optical Viscometer

  • Jang Siyoul
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2003.11a
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    • pp.215-223
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    • 2003
  • Viscosity index improver (VII) is one of the major additives to the modern multigrade lubricants for the viscosity stability against temperature rise. However, it causes shear thinning effects which make the film thickness lessened very delicately at high shear rate $(over\;10^5\;s^{-1})$ of general EHL contact regime. In order to exactly verify the VII's performance of viscosity stability at such high shear rate, it is necessary to make the measurement of EHL film thickness down to $\~100nm$ with fine resolution for the preliminary study of viscosity control. In this work, EHL film thickness of VII added lubricant is measured with the resolution of $\~5nm$, which will give very informative design tool for the synthesis of lubricants regarding the matter of load carrying capacity at high shear rate condition.

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Experimental study on the shear thinning effects of viscosity index improver added lubricant by in-situ optical viscometer

  • Jang, Siyonl
    • Korea-Australia Rheology Journal
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    • v.15 no.3
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    • pp.117-124
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    • 2003
  • Elastohydrodynamic lubrication (EHL) film is measured under the condition of viscosity index improver added to base oil. In-situ optical contact method using the interference principle make the measuring resolution of ~5 nm possible and enables the measuring range all over the contact area of up to ~300 $\mu\textrm{m}$ diameter. What is more important to the developed method by the author is that the measurement of EHL film thickness is possible in the range from 100 nm to 2 $\mu\textrm{m}$, which is the regime of worst contact failures in precision machinery. Viscosity index improver (VII) is one of the major additives to the modem multigrade lubricants for the viscosity stability against temperature rise. However, it causes shear thinning effects which make the film thickness lessened very delicately at high shear rate (over $10^5 s^{-1}$) of general EHL contact regime. In order to exactly verify the VIIs performance of viscosity stability at such high shear rate, it is necessary to make the measurement of EHL film thickness down to ~100 nm with fine resolution for the preliminary study of viscosity control. In this work, EHL film thickness of VII added lubricant is measured with the resolution of ~5 nm, which will give very informative design tool for the synthesis of lubricants regarding the matter of load carrying capacity at high shear rate condition.

A Study on the Rheological Properties of Branched Polycarbonates by Melt Polymerization (용융중합에 의한 분지형 폴리카보네이트의 유변학적 특성 연구)

  • Choi, Su-Jung;Yoon, Kyung-Hwa;Kim, Hee-Seung;Yoo, Seung-Yoon;Kim, Youn-Cheol
    • Polymer(Korea)
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    • v.35 no.4
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    • pp.356-362
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    • 2011
  • The branched polycarbonates (B-PCs) with two different branching agents were synthesized from melt polymerization. The contents of branching agent were in the range of 0.001~0.005 mol%. The chemical structure of the synthesized PC was determined by FTIR, $^1H$ NMR, and $^{13}C$ NMR, spectroscopy. The molecular weight, glass transition and degradation temperatures were determined by GPC, DSC, and TGA. The molecular weight of the phloro type B-PC had a lower value than the other one, and the glass transition temperature increased with molecular weight. Compared with linear PC, the rheological properties of the B-PC indicated an increase of complex viscosity in the low frequency region and shear thinning tendency. Power law index(n) representing shear thinning was calculated by linear regression and the values were in the range of 0.483~0.996. The rheological properties of the B-PCs were measured by a dynamic rheometer.

Study of Cam and Follower Contacts with the Mixed Concepts of EHL and Boundary Lubrication (EHL과 경계 윤활의 혼합 개념에 의한 캠과 종동물의 접촉 현상에 대한 연구)

  • 장시열
    • Tribology and Lubricants
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    • v.15 no.4
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    • pp.343-353
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    • 1999
  • The role of viscosity index improver's(Ⅶ) additives for modem engine lubrication is complex. Under the condition of atmosphere or low shear rate, the characteristics of Ⅶ added lubricant is verified and quoted frequently for mathematical model of lubricant behavior. However, recent research shows that added lubricant has the characteristics of shear thinning at high shear rate condition although it performs well enough over the whole range of working temperature. At high shear rate, they show significant decrease of apparent viscosity irrespective of temperature. Many experimental researches verify that Ⅶ added lubricant shows boundary film layer formation on the solid surface as well as shear thinning effect by its polymeric molecular characteristics. The intend of our research is to verify the effects of Ⅶ from the viewpoint of continuum mechanics, because conventional Reynolds'equation with only pressure-viscosity relation cannot fully predict the lubricant behavior under the Ⅶ added condition. In these aspects, Reynolds'equation of Newtonian fluid model lacks the reflection of real fluid behavior and there is no way to explain the non-linear characteristics of Ⅶ added lubricant. In this research, we mathematically modeled the Ⅶ added lubricant behaviors which are the characteristics of non-Newtonian fluid behavior at high shear rate and boundary film formation on the solid surface. The consideration of elastic deformation in the contact region is also included in our computation and finally the converged film pressure and the film thickness with elastic deformation are obtained. The results are compared with those of Newtonian fluid model.

Studies on the Flow Properties of Semi-Solid Dosage Forms (I) : Steady Shear Flow Behavior of Toothpastes (반고형제제의 유동특성에 관한 연구 (제1보) : 치약의 정상전단 유동거동)

  • Kim, Jeong-Hwa;Song, Ki-Won;Lee, Jang-Oo;Lee, Chi-Ho
    • Journal of Pharmaceutical Investigation
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    • v.25 no.3
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    • pp.213-221
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    • 1995
  • The steady shear flow properties of six kinds of commercial toothpastes were measured using a concentric cylinder type rheometer. In this paper, the shear rate and temperature dependencies of their flow behavior were investigated and the validity of the Casson and Herschel-Bulkley models was examined. Further, the flow properties over a wide temperature range were quantitatively evaluated by calculating the various material parameters. Main results obtained from this study can be summarized as follows: (1) Toothpastes are plastic fluids with a yield stress and their flow behavior shows shear-thinning characteristics. (2) With increasing temperature, the degree of shear-thinning becomes weaker and the Newtonian flow behavior occurs at a lower shear rate range. (3) The Herschel-Bulkley model is more effective than the Casson model in predicting their flow behavior. (4) As the temperature increases, the yield stress, plastic viscosity and consistency index become smaller, on the contrary, the flow behavior index becomes larger.

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Useful Guide to Solve Herschel-Bulkley Model in a Flow Mode Damper (유동 모드 댐퍼에서의 Herschel-Bulkley 모델의 유용한 해법)

  • 이덕영;박성태
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2003.11a
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    • pp.784-787
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    • 2003
  • Electrorheological(ER) and magnetorheological(MR) fluid-based dampers are typically analyzed using Bingham-plastic shear model under quasi-steady fully developed flow conditions. A Herschel-Bulkley constitutive shear flow relationship is that the linear shear stress vs. strain rate behavior of Bingham model is replaced by a shear stress that is assumed to be proportional to a power law of shear rate. This power is called the flow behavior index. Depending on the value of the flow behavior index number, varying degrees of post-yield shear thickening or thinning behavior can be analyzed. But it is not practical to analyze the damping force in a flow mode damper using Herschel-Bulkley model because it is needed to solve a polynomial equation. A useful guide is suggested to analyze the damping force in a damper using the Herschel-Bulkley model.

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THE RELATIVE IMPORTANCE OF NON-NEWTONIAN CHARACTERISTICS OF BLOOD IN THE HEMODYNAMICS OF THE CAROTID BIFURCATION (경동맥 혈류유동에서의 혈액의 비뉴우토니안 특성의 상대적 중요성 해석)

  • Lee, S.W.;Steinman, D.A.
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03a
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    • pp.181-185
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    • 2008
  • In this study, we attempted to quantify the relative importance of assumptions regarding blood rheology. Three patient-specific carotid bifurcation geometries and time-varying flow rates were obtained using magnetic resonance imaging. For each subject, CFD simulations were carried out assuming two different non-Newtonian rheology models Carreau and Ballyk models) and rescaled Newtonian viscosities based on characteristic shear rates to account for the shear-thinning property of blood. The sensitivity of WSS and oscillatory shear index (OSI) were contextualized with respect to the reproducibility of the reconstructed geometry and to assumptions regarding the inlet boundary conditions. We conclude that the assumption of Newtonian fluid is reasonable for studies aimed at quantifying the distribution of WSS-based extrema in an image-based CFD model of carotid bifurcation.

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THE RELATIVE IMPORTANCE OF NON-NEWTONIAN CHARACTERISTICS OF BLOOD IN THE HEMODYNAMICS OF THE CAROTID BIFURCATION (경동맥 혈류유동에서의 혈액의 비뉴우토니안 특성의 상대적 중요성 해석)

  • Lee, S.W.;Steinman, D.A.
    • 한국전산유체공학회:학술대회논문집
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    • 2008.10a
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    • pp.181-185
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    • 2008
  • In this study, we attempted to quantify the relative importance of assumptions regarding blood rheology. Three patient-specific carotid bifurcation geometries and time-varying flow rates were obtained using magnetic resonance imaging. For each subject, CFD simulations were carried out assuming two different non-Newtonian rheology models (Carreau and Ballyk models) and rescaled Newtonian viscosities based on characteristic shear rates to account for the shear-thinning property of blood. The sensitivity of WSS and oscillatory shear index (OSI) were contextualized with respect to the reproducibility of the reconstructed geometry and to assumptions regarding the inlet boundary conditions. We conclude that the assumption of Newtonian fluid is reasonable for studies aimed at quantifying the distribution of WSS-based extrema in an image-based CFD model of carotid bifurcation.

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Computational design of mould sprue for injection moulding thermoplastics

  • Lakkannan, Muralidhar;Mohan Kumar, G.C.;Kadoli, Ravikiran
    • Journal of Computational Design and Engineering
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    • v.3 no.1
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    • pp.37-52
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    • 2016
  • To injection mould polymers, designing mould is a key task involving several critical decisions with direct implications to yield quality, productivity and frugality. One prominent decision among them is specifying sprue-bush conduit expansion as it significantly influences overall injection moulding; abstruseness anguish in its design criteria deceives direct determination. Intuitively designers decide it wisely and then exasperate by optimising or manipulating processing parameters. To overwhelm that anomaly this research aims at proposing an ideal design criteria holistically for all polymeric materials also tend as a functional assessment metric towards perfection i.e., criteria to specify sprue conduit size before mould development. Accordingly, a priori analytical criterion was deduced quantitatively as expansion ratio from ubiquitous empirical relationships specifically a.k.a an exclusive expansion angle imperatively configured for injectant properties. Its computational intelligence advantage was leveraged to augment functionality of perfectly injecting into an impression gap, while synchronising both injector capacity and desired moulding features. For comprehensiveness, it was continuously sensitised over infinite scale as an explicit factor dependent on in-situ spatio-temporal injectant state perplexity with discrete slope and altitude for each polymeric character. In which congregant ranges of apparent viscosity and shear thinning index were conceived to characteristically assort most thermoplastics. Thereon results accorded aggressive conduit expansion widening for viscous incrust, while a very aggressive narrowing for shear thinning encrust; among them apparent viscosity had relative dominance. This important rationale would certainly form a priori design basis as well diagnose filling issues causing several defects. Like this the proposed generic design criteria, being simple would immensely benefit mould designers besides serve as an inexpensive preventive cliché to moulders. Its adaption ease to practice manifests a hope of injection moulding extremely alluring polymers. Therefore, we concluded that appreciating injectant's polymeric character to design exclusive sprue bush offers a definite a priori advantage.

Rheological Models for Describing Fine-laden Debris Flows: Grain-size Effect (세립토 위주의 토석류에 관한 유변학적 모델: 입자크기 효과)

  • Jeong, Sueng-Won
    • Journal of the Korean Geotechnical Society
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    • v.27 no.6
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    • pp.49-61
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    • 2011
  • This paper presents the applicability of rheological models for describing fine-laden debris flows and analyzes the flow characteristics as a function of grain size. Two types of soil samples were used: (1) clayey soils - Mediterranean Sea clays and (2) silty soils - iron ore tailings from Newfoundland, Canada. Clayey soil samples show a typical shear thinning behavior but silty soil samples exhibit the transition from shear thinning to the Bingham fluid as shear rate is increased. It may be due to the fact that the determination of yield stress and plastic viscosity is strongly dependent upon interstructrual interaction and strength evolution between soil particles. So grain size effect produces different flow curves. For modeling debris flows that are mainly composed of fine-grained sediments (<0.075 mm), we need the yield stress and plastic viscosity to mimic the flow patterns like shape of deposition, thickness, length of debris flow, and so on. These values correlate with the liquidity index. Thus one can estimate the debris flow mobility if one can measure the physical properties.