• Resources Recycling
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• v.20 no.1
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• pp.28-36
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• 2011

More than 50% of refractory materials generated from high-temperature melting furnace was not carbonized and could be recycled by adopting proper separation process. In the present work, the separation of refractory materials has studied by adopting color sorting technology to promote the recycling of waste refractory. Purity of the refractory materials was obtained with at 97.2%, color temperature of sorter light source 6,500K, which gives less interference of surrounding light source. Purity and separation efficiency were improved as size is setting bigger and lower conveyer belt speed. It is revealed that optimum conditions were color temperature 6,500K, conveyer belt speed 1,000 mm/sec, particle size -20 mm, etc. To improve purity and separation efficiency on below 10mm size, the resolution of should be fixed camera and it narrow recognition range. As a result of the study, color sorting technology could be used for separation of waste refractory materials and will contribute to promote the waste recycling.

• Membrane Journal
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• v.15 no.2
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• pp.147-156
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• 2005

It is well-known that polyethersulfone (PES) has high $CO_2$ selectivity over $N_2\;(or\;CH_4)$ and excellent pressure resistance of $CO_2$ plasticization among muy commercialized engineering plastics[1-4]. Asymmetric PES hollow fiber membranes for flue gas separation were developed by dry-wet spinning technique. The dope solution consists of PES, NMP and acetone. Water and water/NMP mixtures are used in outer and inner coagulants, respectively. Gas permeation rate (i.e., permeance) and $CO_2/N_2$ selectivity were measured with pure gas, respectively and the micro-structure of hollow fiber membranes was characterized by scanning electron microscopy. The effects of polymer concentration, ratio of NMP to acetone, length of air gap, evaporation condition and silicone coating were investigated on the $CO_2/N_2$ separation properties of the hollow fibers. Optimized PES hollow fiber membranes exhibited high permeance of $25\~50$ GPU and $CO_2/N_2$ selectivity of $30\~40$ at room temperature and have the apparent skin layer thickness of about $0.1\;{\mu}m$. The developed PES hollow fiber membranes, would be a good candidate suitable for the flue gas separation process.

• Membrane Journal
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• v.16 no.4
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• pp.268-275
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• 2006

Novel SILEMs were prepared by multi-stage phase separation process combined by the low temperature phase separation (LTPS) and the high temperature phase separation (HTPS) using room temperature ionic liquids (RTILs) which have a high ionic conductivity. PVDF and imidazolium series ionic liquids were used as membrane material and electrolyte, respectively. To study the ion conducting properties, the SILEMs were tested using LCR meter at temperature controlled from 30 to $130^{\circ}C$. Under humid conditions, with increasing temperature from 30 to $100^{\circ}C$, the ion conductivity of the cast $Nafion^{(R)}$ membrane increased linearly, but then started to decrease after $100^{\circ}C$. However, in the case of the SILEMs, with increasing operating temperature, the ion conductivity increased. Also, the ion conductivity behaviors of the SILEMs were almost same, regardless of humidity. The ion conductivity of the SILEMs was $2.7{\times}10^{-3}S/cm$ and increased almost linearly up to $2.2{\times}10^{-2}S/cm$ with increasing temperature to $130^{\circ}C$. The effects of an inorganic filler on the physical properties of the SILEMs were studied using the $SiO_2$. The addition of $SiO_2$ could improve the mechanical strength of the SILEMs, though the ionic conductivity was decreased slightly.

• Korean Chemical Engineering Research
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• v.48 no.2
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• pp.232-243
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• 2010

Gas hydrates are crystalline solids composed of water and gas molecules. Water molecules are linked through hydrogen bonding and create cavities(host lattice) that can capture a large variety of guest molecules under appropriate conditions, generally high pressure and low temperature. Recently, many researchers try to apply gas hydrates to industrial processes to capture greenhouse gases due to the facts that the process is eco-friendly and target gas molecules can be preferentially captured. In this paper, we introduced recent studies on $CO_2$ and $CO_2-N_2$ mixture hydrates to evaluate the feasibility of industrial application of gas hydrate technology to $CO_2$ capture process. Specifically, we put emphasis on the technical feasibility of $CO_2$ separation in steel industry using gas hydrate formation principles.

• Membrane Journal
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• v.28 no.3
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• pp.187-195
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• 2018

In this work, the morphology of polyvinylidene-co-hexafluoropropylene (PVDF-co-HFP) membranes were systemically investigated using phase inversion technique, to target membrane contactor applications. As the presence of macrovoids degrade the mechanical integrity of the membranes and jeopardize the long-term stability of membrane contactor processes (e.g. wetting), a wide range of dope compositions and casting conditions was studied to eliminate the undesired macrovoids. The type of solvent had significant effect on the membrane morphology, and the observed morphology were correlated to the physical properties of the solvent and solvent-polymer interactions. In addition, to fabricate macrovoid-free structure, the effects of different coagulation temperatures, inclusion of additives, and addition of nonsolvents were investigated. Due to the slow crystallization rate of P(VDF-co-HFP) polymer, it was found that obtaining porous membrane without macrovoids is difficult using only nonsolvent-induced phase separation method (NIPS). However, combined other phase inversion methods such as evaporation-induced phase separation (EIPS) and vapor-induced phase separation (VIPS), the desired membrane morphology can be obtained without any macrovoids.

• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1368-1370
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• 2010

• Bulletin of Food Technology
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• v.22 no.1
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• pp.110-116
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• 2009

• Polymer Science and Technology
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• v.2 no.5
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• pp.355-362
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• 1991

• Applied Chemistry for Engineering
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• v.31 no.5
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• pp.453-466
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• 2020

As the demand for eco-friendly energy increases to overcome the energy shortage and environmental pollution crisis, hydrogen economy has been proposed as a potential solution. Accordingly, an economical and efficient hydrogen production is considered to be an essential industrial process. Research on applying hydrogen separation membranes for H₂/CO₂ separation to the production of highly concentrated hydrogen by purifying H₂ and capturing CO₂ simultaneously from synthetic gas produced by gasification is in progress nowadays. In high temperature environments, the membrane separation process using glassy polymeric membrane with H₂ selectivity has the potential for CO₂ capture performance, and is an energy and cost effective system since polybenzimicazole (PBI)-based separators show excellent chemical and mechanical stability under high-temperature operation conditions. Thus, the development of high-performance PBI hydrogen separators has been rapidly progressing in recent years. This overview focuses on the recent developments of PBI-based membranes including structure modified, cross-linked, blended and carbonized membranes for applications to the industrial hydrogen separation process.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.3
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• pp.212-219
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• 2015

This study focuses evaluating the efficiency and performance evaluation of composite type sheet-membrane waterproofing method that utilizes a separation behavior inducement system designed to resolve the chronic problems of disintegration and damage of overlap areas of waterproofing layers. As the result of the test, the tensile strength value was at 13.8N/mm and elongation rate at 587% for the separation behavior inducement type specimen, and the compared specimens had 14.2N/mm for tensile strength and 335% for elongation rate. For the separation behavior adhesion method specimen, when tensile stress or displacement occurred, the Zero-Span tension occurrence did not follow, which resulted in that the bottom sheet layer and the top membrane layer did not simultaneously becoming damaged. When undergoing the top and bottom layers were separated through separation behavior due to lack of flexibility, the bottom layer began to damage at the primary stage, and with the allowed boundary the upper membrane layer began to display flexibility and showed continuous displaced resulting in secondary phase damaging.