• Bulletin of the Korean Chemical Society
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• 제15권10호
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• pp.857-860
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• 1994

We have calculated the ${\pi}$-electron density, atom self-polarizability, and free valence on each atom of N-(2-chlorobenzyl)-pyridinium, N-(benzyl)-2-chloropyridinium, and N-(2-chlorobenzyl)-2-chloropyridinium salts using a simple Huckel method in order to discuss their intramolecular photocyclization reaction in a qualitative method. Our calculation qualitatively predicts that photocyclization occurs through forming radicals as a reaction intermediate by breaking a C-Cl bond after photoexcitation into a triplet state via intersystem crossing from an initially excited singlet state. We noticed that this C-Cl bond breaking is aided by ${\pi}$-complex formation between a chlorine atom and the ${\pi}$ -electrons of the neighboring ring in the triplet state and a stronger ${\pi}$-complex bond makes C-Cl bond breaking, i.e., radical formation, much easier. A chlorine atom will form a stronger ${\pi}$ -complex bond to a benzyl ring of N-(benzyl)-2-chloropyridinium than a pyridinium ring of N-(2-chlorobenzyl)-pyridinium because the former can donate its ${\pi}$-electron more easily than the latter. The chlorine at position 15 of N-(2-chlorobenzyl)-2-chloropyridinium salt in the excited state also provides its ${\pi}$-electron to the benzyl ring. So this ${\pi}$-electron can increase the bond strength of the $\pi-complex.$ Therefore, the strength of ${\pi}$-complex follows the order of N-(2-chlorobenzyl)-2-chloropyridinium, N-(benzyl)-2-chloropyridinium, and N-(2-chlorobenzyl)-pyridinium salts and thus the radical formation rate. This provides us with an intramolecular photocyclization reaction rate of the same order as given above.

• Journal of the Optical Society of Korea
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• 제7권3호
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• pp.156-159
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• 2003

Permanent structure of photoinduced singlemode waveguide in optical fluoride glasses was demonstrated using the self-channeled plasma filament excited by a femtosecond (110 fs) Ti:sapphire laser ($λ_p$ = 800 nm). The photoinduced refractive index modification in ZBLAN glasses reached a length of approximately 10 - 15 mm from the input surface of the optical glass with the diameters ranging from 5 to 8 ${\mu}{\textrm}{m}$ at input intensities more than l.0 ${\times}$ $10^{12}$ W/$\textrm{cm}^2$. The graded refractive index profiles were fabricated to be a symmetric form from the center of an optical fluoride glass and a maximum value of refractive index change (ㅿn) was measured to be l.3${\times}$$10^{-2}$. The beam profile of the output beam transmitted through the modified region showed that the photoinduced refractive index modification produced a permanent structure of singlemode waveguide.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집C
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• pp.202-206
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• 2001

Machine tool chatter is the self-excited vibration generated by chip thickness variation and severely degrades the quality of machined surface. The incidence of chatter is greatly affected by the dynamic characteristics of machine tool structure. Therefore, the cutting dynamics in the parallel machine tool is to be carefully studied considering the dynamic characteristics of parallel mechanism. In this paper, the vibration model of parallel machine tool is derived, in which the legs of the parallel mechanism are considered as spring-damper systems. The chatter stability charts for various machining parameters are examined with the example of the cubic parallel mechanism that is specially designed for machine tool use.

• Journal of Advanced Marine Engineering and Technology
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• 제10권4호
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• pp.31-40
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• 1986

With the tendency toward high speed and high pressure in centrifugal pumps, the problem of sub-synchronous vibration has arisen, caused by the hydraulic forces of the working fluid, such as wearring, balance piston, impeller, etc.. These forces can drastically alter the rotor critical speeds and stability characteristics, and can be acted significant destabilizing forces. For preventing such self-excited vibration, the desing of the rotor system needs, which would secure the stability of the machine. In this paper, a procedure is presented for dynamic modeling of rotor-bearing-seal-impeller systems which consist of rigid disks, distributed parameter finite rotor elements and discrete bearings, seals and impellers. A finite element model including the effects of rotatory inertia and gyroscopic moments is developed using the consistent matrix approach. The technique of dynamic matrix reduction is applied to the shaft matrices to reduce them to a set of matrices of dynamic of significantly fewer degrees of freedom. The representation of bearing, seal and impeller elements is in term of linearized stiffness and damping matrices by reasonably small perturbations from equilibrium. The stability behavior of a typical double suction centrifugal pump is presented. Results show the influence of clearance and flow conditions on running speeds and stability characteristics.

• 소음진동
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• 제4권3호
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• pp.365-375
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• 1994

Periodic longitudinal vibrations of a video and audio tape and the like used for transducing pictures and sounds may be induced by self-excited vibrations which are caused by frictions against the heads and guides, and their eccentricity, noncircularity or irregularity. It is important to analyze the longitudinal vibration of a tape because it causes distortions of a reproduced signal. It is difficult to measure directly the longitudinal vibration. In this paper a method estimating longitudinal vibration using impulse responses in the transverse direction is presented. And, the parameters boundary domain where the transverse and longitudinal vibration can be decoupled is introduced. In the domain where the both vibrations are decoupled, analytic methods using frequency characteristics and transient responses of the transverse vibration, respectively, are presented. The time domain method predicted more exactly the instantaneous phase of the longitudinal vibration than frequency domain method did.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2007년도 추계학술대회논문집
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• pp.1395-1400
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• 2007

Tire flat spot is a deformation which occurs around the contact patch during long-period parking and does hardly recovered even after driving. The deformation makes a tire self-excited and ride comfort gets worse. In this study, it is shown that the flat spot can be evaluated by measuring change in radial run out or force. Its effects on vibration at vehicle floor and steering wheel are also revealed. Finally it is shown that the flat spot is likely to occur if the inflation pressure is low and the tire is suppressed by a heavy load at a high temperature.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2000년도 전력전자학술대회 논문집
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• pp.489-492
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• 2000

A novel low-cost simple and unity-power-factor electronic ballast is presented. The proposed electronic ballast employs a bypassing capacitor and load networks composed of ballast capacitors and small charge pump capacitors as power factor correction circuit combined with the secondary winding of the transformer in the self-excited current-fed push-pull resonant inverter(CF-PPRI) resulting in cost-effectiveness and higher efficiency. By analyzing the principles of power factor correction mathematically optimum design guidelines are presented. Since the lamps are used in power factor correction stage the input power is automatically adjusted according to the number of the lamps.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2007년도 추계학술대회 논문집 전기기기 및 에너지변환시스템부문
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• pp.31-33
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• 2007

Cost reduction requires lowering number of power devices used in the converter driving SRM. This is quite feasible in SRM drive systems than in other drive systems. This paper deals with design, analysis, and simulation of such a novel two phase SRM. A novel two phase SRM has high performance, self-starting capability, high efficiency, and low manufacturing cost. Additionally, the stator back iron does not experience any flux reversal as the flux is in the same direction whether phase A or B is excited leading to a greater reduction in core losses. The magnetic analysis and design considerations of the novel two phase SRM have been obtained by the finite element analysis (FEM). Experimental verification of the machine design is provided to correlate with analysis and simulation studies.

• 조명전기설비학회논문지
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• 제26권8호
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• pp.42-49
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• 2012

Grid-connected photovoltaic generator system requires high performance PCS(Power Conditioning System) according to the standard of 'Distributed Generation Grid-Connected Technology Standards'. This paper presents the MPPT control method which improves output efficiency through fast tracking to the maximum power point of PV and a reduced self-excited vibration. Secondly, in this paper DVR function was applied to PCS to compensate the voltage sag frequently happening for a power system. The proposed PCS control is analyzed and compared to conventional PCS operating characteristic, the various insolation and loads, and voltage sag condition through PSIM tool. It proves the utility.

• 한국자동차공학회논문집
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• 제18권3호
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• pp.127-132
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• 2010

Eigensolutions associated with self-excited vibration of disc brake system can be obtained by complex eigenvalue analysis. The eigenvalue sensitivity to change in contact stiffness can be used to demonstrate stability criteria and eigenvalue veering. Dynamic instability on eigenvalue loci with respect to the variation of contact stiffness is found to be related to mode interaction between two adjacent modes. This modal interaction can be effectively shown by mode shape visualization. This paper presents the methodology to construct the mode shape of disc brake system where a disc and two brake pads are coupled with contact stiffness.