• Title/Summary/Keyword: Secondary position

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Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond (수소 결합에 의한 삼차원의 Copper(II) 거대고리 착물과 2,5-Pyridinedicarboxylate와의 자기조립)

  • Ki-Young Choi;Haiil Ryu;Yong-Son Kim
    • Journal of the Korean Chemical Society
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    • v.47 no.2
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    • pp.104-108
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    • 2003
  • The reaction of $[Cu(L)]Cl_2{\cdot}H_2O(L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,0^{1.18},0^{7.12}]docosane)$ with 2,5-pyridinedicarboxylate(pdc) led to the formation of $[Cu(L)(H_2O)](pdc){\cdot}6H_2O(1)$. The structure was characterized by X-ray crystallography and spectroscopic method. The coordination geometry around the copper atom is a distorted square-pyramid with four secondary amines of the macrocycle occupying the basal sites and a water molecule at the axial position. Intermolecular hydrogen bonds in 1 form a three-dimensional molecular network.

Building Industrial Competitiveness in the Global Production Network: A Case Study on the Cosmetics Industry in Korea (글로벌생산네트워크 상에서의 산업경쟁력 강화 프로세스: 한국화장품산업을 중심으로)

  • Lee, Kyung Jin
    • Journal of the Economic Geographical Society of Korea
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    • v.16 no.4
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    • pp.597-612
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    • 2013
  • The purpose of this paper is to examine the building process of industrial competitiveness of the Korean cosmetics industry in the global production network. For this study, cosmetics industry in Korea is selected as a research subject. Secondary data and the Korea Health Industry Statistics are analyzed to examine the overall changes of the cosmetics firms under the changes of global economy overtime. In-depth interviews of the case firms are also conducted to understand the old and new corporate strategies which locate with the sustainability and competitive advantages under an uncertain environment. As a result of the restructuring processes, the Korea cosmetics industry has upgraded its position as an innovative power in the world cosmetics industry. In addition, during the restructuring processes, cosmetics industry is overwhelmingly concentrated in the Capital Region, reflecting intensification of agglomeration economies.

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Heat-Flux Analysis of Solar Furnace Using the Monte Carlo Ray-Tracing Method (몬테카를로 광선추적법을 이용한 태양로의 열유속 해석)

  • Lee, Hyun-Jin;Kim, Jong-Kyu;Lee, Sang-Nam;Kang, Yong-Heack
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.10
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    • pp.989-996
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    • 2011
  • An understanding of the concentrated solar flux is critical for the analysis and design of solar-energy-utilization systems. The current work focuses on the development of an algorithm that uses the Monte Carlo ray-tracing method with excellent flexibility and expandability; this method considers both solar limb darkening and the surface slope error of reflectors, thereby analyzing the solar flux. A comparison of the modeling results with measurements at the solar furnace in Korea Institute of Energy Research (KIER) show good agreement within a measurement uncertainty of 10%. The model evaluates the concentration performance of the KIER solar furnace with a tracking accuracy of 2 mrad and a maximum attainable concentration ratio of 4400 sun. Flux variations according to measurement position and flux distributions depending on acceptance angles provide detailed information for the design of chemical reactors or secondary concentrators.

Validation of a new three-dimensional imaging system using comparative craniofacial anthropometry

  • Naini, Farhad B.;Akram, Sarah;Kepinska, Julia;Garagiola, Umberto;McDonald, Fraser;Wertheim, David
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.39
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    • pp.23.1-23.8
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    • 2017
  • Background: The aim of this study is to validate a new three-dimensional craniofacial stereophotogrammetry imaging system (3dMDface) through comparison with manual facial surface anthropometry. The null hypothesis was that there is no difference between craniofacial measurements using anthropometry vs. the 3dMDface system. Methods: Facial images using the new 3dMDface system were taken from six randomly selected subjects, sitting in natural head position, on six separate occasions each 1 week apart, repeated twice at each sitting. Exclusion criteria were excess facial hair, facial piercings and undergoing current dentofacial treatment. 3dMDvultus software allowed facial landmarks to be marked and measurements recorded. The same measurements were taken using manual anthropometry, using soluble eyeliner to pinpoint landmarks, and sliding and spreading callipers and measuring tape to measure distances. The setting for the investigation was a dental teaching hospital and regional (secondary and tertiary care) cleft centre. The main outcome measure was comparison of the craniofacial measurements using the two aforementioned techniques. Results: The results showed good agreement between craniofacial measurements using the 3dMDface system compared with manual anthropometry. For all measurements, except chin height and labial fissure width, there was a greater variability with the manual method compared to 3D assessment. Overall, there was a significantly greater variability in manual compared with 3D assessments (p < 0.02). Conclusions: The 3dMDface system is validated for craniofacial measurements.

$\mu\textrm{p}$-based Electronic Control System for Automobiles Part1. Electronic Engine Control System (자동차의 마이크로프로셋서를 이용한 전자식 제어시스템에 대한 연구 제1편 : 전자식 엔진 제어시스템)

  • Chae, Suk;Kim, Young-Lip;Liu, Joon;Kim, Kwang-Rak;Bien, Zeungnam
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.17 no.5
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    • pp.15-21
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    • 1980
  • An engine control system in which the conventional mechanical ignition system is studied. The contact point of the breaker is replaced by the contactless magnetic pick up sensor from which the information of the speed and the position of the crankshaft is extracted , and further an electronic High Energy Ignitim System Is designed, implemented and tested . The High Energy Igniticwl System increases the secondary spark voltage of the ignition coil from the conventional 10000~15000 volts to the 30000~40000 volts resulting in improving the combustion efficiency. Also, instead of the conventional advimce mechanism forigniliontiming control, a microprocessorbased timinng mechanisn is installed to determine the ignition timing data in response to the engine rpm and the intake manifold vacuum.

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Evaluation of dose distribution from 12C ion in radiation therapy by FLUKA code

  • Soltani-Nabipour, Jamshid;Khorshidi, Abdollah;Shojai, Faezeh;Khorami, Khazar
    • Nuclear Engineering and Technology
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    • v.52 no.10
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    • pp.2410-2414
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    • 2020
  • Heavy ions have a high potential for destroying deep tumors that carry the highest dose at the peak of Bragg. The peak caused by a single-energy carbon beam is too narrow, which requires special measures for improvement. Here, carbon-12 (12C) ion with different energies has been used as a source for calculating the dose distribution in the water phantom, soft tissue and bone by the code of Monte Carlobased FLUKA code. By increasing the energy of the initial beam, the amount of absorbed dose at Bragg peak in all three targets decreased, but the trend for this reduction was less severe in bone. While the maximum absorbed dose per bone-mass unit in energy of 200 MeV/u was about 30% less than the maximum absorbed dose per unit mass of water or soft tissue, it was merely 2.4% less than soft tissue in 400 MeV/u. The simulation result showed a good agreement with experimental data at GSI Darmstadt facility of biophysics group by 0.15 cm average accuracy in Bragg peak positioning. From 200 to 400 MeV/u incident energy, the Bragg peak location increased about 18 cm in soft tissue. Correspondingly, the bone and soft tissue revealed a reduction dose ratio by 2.9 and 1.9. Induced neutrons did not contribute more than 1.8% to the total energy deposited in the water phantom. Also during 12C ion bombardment, secondary fragments showed 76% and 24% of primary 200 and 400 MeV/u, respectively, were present at the Bragg-peak position. The combined treatment of carbon ions with neutron or electron beams may be more effective in local dose delivery and also treating malignant tumors.

Identification of ginseng root using quantitative X-ray microtomography

  • Ye, Linlin;Xue, Yanling;Wang, Yudan;Qi, Juncheng;Xiao, Tiqiao
    • Journal of Ginseng Research
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    • v.41 no.3
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    • pp.290-297
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    • 2017
  • Background: The use of X-ray phase-contrast microtomography for the investigation of Chinese medicinal materials is advantageous for its nondestructive, in situ, and three-dimensional quantitative imaging properties. Methods: The X-ray phase-contrast microtomography quantitative imaging method was used to investigate the microstructure of ginseng, and the phase-retrieval method is also employed to process the experimental data. Four different ginseng samples were collected and investigated; these were classified according to their species, production area, and sample growth pattern. Results: The quantitative internal characteristic microstructures of ginseng were extracted successfully. The size and position distributions of the calcium oxalate cluster crystals (COCCs), important secondary metabolites that accumulate in ginseng, are revealed by the three-dimensional quantitative imaging method. The volume and amount of the COCCs in different species of the ginseng are obtained by a quantitative analysis of the three-dimensional microstructures, which shows obvious difference among the four species of ginseng. Conclusion: This study is the first to provide evidence of the distribution characteristics of COCCs to identify four types of ginseng, with regard to species authentication and age identification, by X-ray phase-contrast microtomography quantitative imaging. This method is also expected to reveal important relationships between COCCs and the occurrence of the effective medicinal components of ginseng.

Glu-56 in Htrl is Critical for Phototaxis Signaling in Halobacterium salinarum

  • Choi, Ah-Reum;Kim, So-Young;Yoon, Sa-Ryong;Jung, Kwang-Hwan
    • Animal cells and systems
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    • v.9 no.3
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    • pp.139-144
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    • 2005
  • The attractant (orange light) or repellent (white light) signal is transmitted from SRI (Sensory Rhodopsin I) via protein-protein interaction with its transducer Htrl (Halobacterial Transducer for Sensory Rhodopsin I) which in turn controls a cytoplasmic phospho-transfer pathway that modulates flagella motor switching in Halobacterium salinarum. Some mutations in both SRI and Htrl showed an unusual mutant phenotype called inverted signaling, in which the cell produces a repellent response to normally attractant light. Twelve mutations at the Glutamate 56 (E56) position in the second transmembrane helix of Htrl were introduced by site-specific random mutagenesis. Almost all E56 mutants showed orange-light inverted responses in pH and temperature-dependent manners except E56D and E56Y. Except for these two mutants, all mutants accelerated the $S_{373}$ decay compared to wild-type at $18^{\circ}C$. This supported that there is an interaction between SRI and the second transmembrane of Htrl. Also a structural model of Htrl based on the Tar crystal structure and the secondary structure prediction program proposed the E56 residue to be in the middle of the proton channel. The most important observation is that the E56 mutant provides the evidence that this residue is very sensitive for signal relay, which can be explained by the open and closed conformations of the channel (A and R conformations) in SRI, as was postulated by the unified conformational shuttling model for transport and signaling.

Job Satisfaction and Marital Satisfaction among married Employers (유배우 근로자의 직업만족도와 결혼만족도)

  • Park, Eun-Ok
    • Research in Community and Public Health Nursing
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    • v.12 no.3
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    • pp.661-669
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    • 2001
  • Purpose: This study was carried out to investigate the difference in job satisfaction and marital satisfaction by gender and to explore the influences of demographic status. employment characteristics. and job satisfaction/marital satisfaction on each type of satisfaction. Method: Social statistics survey data collected by National Statistical Office in 1998 were used for the secondary analysis in the study. Job satisfaction was measured by questionnaires, which consisted of 12 items such as task, promotion, placement, wage, benefits, future in the work, working environment, human relationship. and working hours. And marital satisfaction was collected by questionnaires which consisted of 7 items, including satisfaction with general family life, relationship with their own parent and parent-in-law, relationship with brothers and sisters, relationship with their children, and economic living status. These are measured by 5-point Likert scale. Result: The results show that more than 60% of women were working as part-time employees. Their education levels were lower than men. Men were satisfied significantly more in their jobs than women. Men also had higher marital satisfaction. The employment status had the most important factor on the job satisfaction. and the marital satisfaction was the second important factor among women and men. As for the age, while older men showed higher job satisfaction, younger women showed higher job satisfaction, 28.04% of the variance in the job satisfaction for men and 33.86% for women were accounted for by the following variables: the younger age. the higher education. job satisfaction, and the higher marital satisfaction, 22.15% of the variance in the marital satisfaction for men and 21.19% for women were accounted for by these variables. Conclusion: The results of this study showed that there were differences in job satisfaction and marital satisfaction between genders, and that job satisfaction and marital satisfaction influenced each other. Employment status was the most predictive factor on the job satisfaction. Married women had an unstable employment status such as part-time position. The stability of employment could be considered as a strategy for enhancing job satisfaction for both sexes. The reason that women had lower marital satisfaction than men will have to be further investigated.

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Analyses on Fine Structure and Electronic Structure of Cr-doped Li4Ti5O12 by Using X-ray Absorption Spectroscopy and First Principle Calculation (X-선 흡수실험 및 제일원리계산을 통한 Cr-doped Li4Ti5O12의 미세구조 및 전자구조 해석)

  • Song, Han-Nah;Kim, Hyung-Sun;Cho, Byung-Won;Kim, Yong-Tae
    • Journal of the Korean Electrochemical Society
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    • v.14 no.1
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    • pp.33-37
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    • 2011
  • $Li_4Ti_5O_{12}$ has been considered a potential material for high power lithium batteries. Since $Li_4Ti_5O_{12}$ is however an insulator having a broad band gap, various methods have been employed to improve the conductivity. In this study, we have investigated the change of fine structure and electronic structure by Cr doping using X-ray absorption spectroscopy and First Principle Calculation. Doping with Cr, we could obtain an enhanced electronic conductivity by locating the Fermi level at the center position of Cr d-band and identify the change of XANES pre-edge and white line peak due to the increase of electron density of Ti d-band.