• Corrosion Science and Technology
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• 제18권3호
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• pp.78-85
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• 2019

The International Maritime Organization (IMO) will administer a new 0.5% global sulfur cap on fuel content from 1 January 2020, lowering from the present 3.5% limit. Seawater $SO_x$ (sulfur oxide) scrubbing is especially spray scrubbing and a promising alternative to complying with the IMO regulation. However, the ionization of $SO_2$ (sulfur dioxide) and the $H_2SO_4$ (sulfuric acid) formed from $SO_3$ (sulfur trioxide) is proposed to accelerate corrosion of the internal seawater pipe. Apparently, the corrosion of the scrubber seawater piping system occurs in a severe and frequent manner. Hence, in this study, electrochemical measurement and weight loss of carbon steel (used as seawater pipe in most of the ships) in diluted sulfuric acid solution were investigated to determine corrosion rate, corrosion current density, corrosion potential, electrochemical behavior, and impressed-current density. Accordingly, the corrosion rate of carbon steel sheet in various diluted sulfuric acid solutions was observed to be greater than that in natural seawater, thus suggesting the fundamental data to deal with corrosion problems in scrubber seawater pipe.

• Corrosion Science and Technology
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• 제17권4호
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• pp.176-182
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• 2018

Corrosion of the Cu alloy with 10wt% Ni in stagnant seawater with residual free chlorine was investigated. Despite that fact that Cu alloys are widely used for seawater applications due to their stubborn resistance to chloride attack, not much is known as to how the residual free chlorine in seawater affects corrosion of Cu and its alloys. In this work, immersion tests were conducted in the presence of different levels of chlorine for 90-10 Cu-Ni samples, one of the most frequently used Cu alloys for seawater application, mostly in shipbuilding. The results revealed no evidence for accelerated corrosion of the Cu-Ni alloy even in the presence of 5 ppm residual chlorine in seawater, signifying that the Cu-Ni alloy can be more tolerant to residual chlorine that has been commonly cited by the shipbuilding industry. However, comparison of polarization behavior of the alloy samples in the presence of different electrolytes with different concentrations of residual chlorine suggests that higher concentration of chlorine could increase the corrosion rate of the Cu-Ni alloy. Furthermore, it is suggested that microorganisms in the seawater could increase the corrosion rate of the Cu-Ni alloy by encouraging exfoliation of the corrosion product off the metal surface.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2006년도 전기학술대회논문집
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• pp.283-284
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• 2006

The ship performs heat exchange using seawater to keep main engine and auxiliary machinery at optimum temperature. In heat exchanger, refrigerant located outside of copper tube is cooled by seawater flowing through inside of copper tube. On the other hand, seawater erosion and corrosion nay occasionally cause the corrosion of the copper tube in A/C(Air Conditioner) condenser. This corrosion of copper tube makes seawater and refrigerant mixed, seriously damaging A/C system. In this study, accordingly, the exact ive mechanism of the corrosion on the condenser entailing serious problems occasional is investigated through the electrochemical polarization experiments on the condenser's component materials. According to the experiments, the corrosive procedures on the copper tube was verified by the fact that passive film of the copper tube surface which is destroyed by the pressure of sucked seawater, is damaged by the corrosive ingredients in the seawater.

• Corrosion Science and Technology
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• 제3권2호
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• pp.47-53
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• 2004

The conditions to simulate the atmospheric corrosion behavior in the laboratory were investigated to clarify atmospheric corrosion mechanism of steel material in coastal area, For airborne sea salt and artificial seawater droplet, the various behaviors were observed by optical microscope, The particle size of the dried airborne sea salt was about $20{\mu}m$, and was about 1/10 compared with the artificial seawater droplet. Though the airborne sea salt represented the same behavior as the thermodynamic water absorption, the behavior of the artificial seawater droplet deviated from the results of the thermodynamic calculation, It is concluded that the water absorption behavior is influenced by the particle size of the dried sea salt. The corrosion behaviors of carbon steels were observed under the deposited condition of airborne sea salt and artificial seawater droplet. The corrosion behaviors showed a different trend, indicating that the corrosion behavior depended on the particle size of the dried sea salt. The corrosion in the actual environrnent progressed greater than that in the chamber. Furthermore, the summer showed the greater corrosion than the spring. It is found that the corrosion behaviors are attributed to the influence of the environmental factors.

• Corrosion Science and Technology
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• 제20권2호
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• pp.85-93
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• 2021

The corrosion damage of materials in marine environment mainly occurs by Cl^- ions due to the breakdown of passive films. Additionally, various characteristics in seawater such as salinity, temperature, immersion time, flow rate, and biological activity also affect corrosion characteristics. In this study, the corrosion characteristics of stainless steels (STS 304 and STS 316L) and anodized aluminum alloys (AA 3003 and AA 6063) were evaluated with seawater temperature parameters. A potentiodynamic polarization experiment was conducted in a potential range of -0.25 V to 2.0 V at open circuit potential (OCP). Corrosion current density and corrosion potential were obtained through the Tafel extrapolation method to analyze changes in corrosion rate due to temperature. Corrosion behavior was evaluated by measuring weight loss before/after the experiment and also observing surface morphology through a scanning electronic microscope (SEM) and 3D microscopy. Weight loss, maximum damage depth and pitting damage increased as seawater temperature increased, and furthermore, the tendency of higher corrosion current density with an increase of temperature attributed to an increase in corrosion rate. There was lower pitting damage and lower corrosion current density for anodized aluminum alloys than for stainless steels as the temperature increased.

• 한국표면공학회지
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• 제50권4호
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• pp.259-265
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• 2017

5000 series aluminium alloys and austenitic stainless steels have excellent corrosion resistance and sufficient strength, which are widely used as materials for marine equipment and their parts in the marine environment. The corrosion characteristics of materials are important factors for selecting the appropriate material due to fluid component changes in the estuarine and coastal areas where seawater and fresh water are mixed. Therefore, for 5083 Al alloy, STS304 and STS316L widely used in the marine environment, anodic polarization experiments were performed to compare the corrosion damage characteristics of each material by three kinds of solutions of 100 % tap water, 50 % tap water+50 % natural seawater and 100 % natural seawater. As a result of the anodic polarization experiments, aluminum alloy (5083) caused locally corrosion on the surface in the tap water, and corrosion damage occurred all over the surface when the seawater was included. Stainless steels (STS304 and STS316L) presented almost no corrosion damage in tap water, but they grew pitting corrosion damage with increasing seawater concentration. STS316L showed better corrosion resistance than STS304.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1993년도 가을 학술발표회 논문집
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• pp.85-90
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• 1993

This study was performed for the purpose of obtaining the fundamental data to establish the criterion of concrete deterioration and presuming steel corrosion of concrete structures under the environment of seawater. It was exposed in seawater for 1 year that steel was embedded in the concrete specimen. The diffusion coefficients of concrete, corrosion potential and steel corrosion were considered. The results show that corrosion potential is reduced according to steel corrosion and corrosion area ratio is correlative with diffusion coefficients of concrete.

• Corrosion Science and Technology
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• 제23권4호
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• pp.255-265
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• 2024

Duplex stainless steels (UNS S32205, UNS S32750) are used in various environments. The potentiodynamic polarization tests were conducted at 30 ℃ in order to study the electrochemical corrosion behaviors of duplex stainless steels under different seawater concentrations (fresh water, seawater, mixed water). The results of Tafel analysis in seawater showed that UNS S32205 and UNS S32750 had the highest corrosion current densities at 6.12 × 10^-4 mA/cm² and 5.41 × 10^-4 mA/cm², respectively. The pitting potentials of UNS S32205 and UNS S32750 were comparable to or higher than the oxygen evolution potential in fresh water, mixed water, and seawater. The maximum damage depths and surface damage ratio caused by pitting corrosion increased with chloride concentration. The synergy effect of molybdenum and nitrogen enhances the concentration of Mo, Ni, and Cr at the interface of the metal-electrolyte. In particular, in the case of nitrogen, NH₃ and NH₄⁺ are formed to compensate for the pH drop in the pitting region, thereby strengthening the repassivation of the film. The excellent corrosion resistance of UNS S32750 is attributed to the strengthening effect of the chromium oxide film due to the presence of molybdenum and nitrogen.

• 한국표면공학회지
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• 제57권4호
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• pp.325-330
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• 2024

When seawater is used in electrochemical devices, issues arise such as the adsorption of chloride ions blocking the active sites for Oxygen reduction reactions (ORR) in seawater batteries, and the occurrence of Chlorine evolution reactions (ClER) in seawater electrolysis due to chloride anions (Cl^-) competing with OH^- for catalytic active sites, potentially slowing down Oxygen evolution reactions (OER). Consequently, the performance of components used in seawater battery and seawater electrolysis may deteriorate. Therefore, conventional alloys are often used by coating or plating methods to minimize corrosion, albeit at the cost of reducing electrical conductivity. This study thus designed a corrosion-resistant layer by doping carbon with Nitrogen (N) and Sulfur (S) to maintain electrical conductivity while preventing corrosion. Optimal N,S doping ratios were developed, with corrosion experiments confirming that N,S (10:90) carbon exhibited the best corrosion resistance performance.

• Corrosion Science and Technology
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• 제20권5호
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• pp.281-288
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• 2021

Due to advancement of the industry, operation of a device in a harsh environment is increasing. Especially, the marine environment contains Cl^- ions which causes localized corrosion such as pitting and crevice corrosion of stainless steel and various metals. In this study, electrochemical corrosion behaviors of austenitic stainless steel (STS 316L) and nickel alloy (Inconel 600) with different seawater concentrations (fresh water, seawater, mixed water) were investigated. The STS 316L and Inconel 600 were etched in 10% oxalic acid and composed of an austenitic phase. Results of Tafel analysis in seawater showed that STS 316L and Inconel 600 presented the highest corrosion current densities of 7.75 × 10^-4 mA/cm² and 1.11 × 10^-4 mA/cm² and the most negative pitting potentials of 0.94 V and 1.06 V, respectively. The maximum damage depths and surface damage ratio by pitting corrosion increased with chloride concentration. The STS 316L had higher PREN than Inconel 600. However, the surface damage and weight loss of Inconel 600 were superior to STS 316L. It was difficult to compare the pitting resistance of STS 316L based on Fe and Inconel 600 based on Ni with PREN simply.