The fish species and groups were investigated at the four streams in Goseong from September 2011 to August 2012. During the survey period, 17 species from Goseong stream, 18 species from Maam stream, 20 species from Guman stream, and 15 species from Baedun stream of fish were collected. Four creek downstreams were classified into 2 groups which were categorized by the effects of seawater. Group A is Guman and Maam streams with no estuary barrage, with the exchange of freshwater and seawater. On the other hand, group B is Goseong and Beadun streams which was blocked by the estuary barrage and submerged weir. The former group was mainly consisted of peripheral freshwater fish species such as Tridentiger brevispinis, Gymnogobius castaneus, Mugli cephalus, and Acanthogobius flavimanus. The latter one was composed of primary freshwater fish species such as Zacco koreanus, Squalidus gracilis majimae, and Pseudorasbora parva. These results suggest that estuary barrage and submerged weir in the stream could change the natural flow of seawater and freshwater, resulting in change of fish species and groups.
To assess the adsorption and removal mechanism of dissolved inorganic nutrients in seawater by scattering yellow loess, a laboratory experiment was conducted for the change of nutrient concentration in seawater during the course of time depending on particle size and scattered concentration of the yellow loess. Twenty four hours after the addition of yellow loess in the size range of 0 $\mu$m to 500 $\mu$m in seawater, the removal rate of dissolved inorganic phosphorus (DIP) was increased with increasing amount of yellow loess. There was little difference among the removal rates depending on the size of yellow loess. On average, $26\%$ of dissolved inorganic silicate was reduced for the same period. No greate difference among the removal rate depending on both size and amount of yellow loess was found. Our results suggested that the removal mechanism of DU seemed to be associated with mostly the chemical bond with iron. More than $99\%$ of initial DU concentration was likely to be removed by this mechanism. In the case of inorganic dissolved silicate, the removal mechanism was likely to be attributed to a cation exchange between the yellow loess and seawater.
Proceedings of the Korean Institute of Navigation and Port Research Conference
/
2006.10a
/
pp.157-165
/
2006
In February,2004, at International Maritime Organization (IMO), LONDON, a new international convention 'International Convention fur the Control and Management of Ship's Ballast Water and Sediment 2004' was adopted. It is called 'Ballast Water Management Convention (BWM)'. Ballast water means charged seawater or fresh water in ship's special tanks (ballast tank) to keep safety navigation and ship's maneuverability. However, from 1980, it was point out the serious problem for marine ecosystem and human life that ballast water includes harmful marine species (and small organisms) and these species are also discharged along with ballast water. These species were released with discharged ballast water in water areas, where species are different from discharged ballast water. The problem is that released species increase when released species are more powerful than native species and consequently, marine ecological system is destroyed in released water area. Authors have inspected the validity of the ballast water exchange using pumping-through method that is one of the methods of ballast water management. In this paper, the numerical simulation of the motion and density of the fluid at the time of exchange of the fluid in a 2-dimensional tank using the pumping-through method was carried out by using two different type numerical methods. One method is MPS method that is one of the particle methods. Other one is Finite Different Method (FDM). Authors were compared with result of two numerical method calculations and experiment result and reported some knowledge from these results.
Electrodialysis (ED) is essential in separating ions through an ion exchange membrane. The disposal of brine generated from seawater desalination is a primary environmental concern, and its recycling through membrane separation technology is highly efficient. Alkali is produced by several chemical industries such as leather, electroplating, dyeing, and smelting, etc. A high concentration of alkali in the waste needs treatment before releasing into the environment as it is highly corrosive and has a chemical oxygen demand (COD) value. The concentration of calcium and magnesium is almost double in brine and is the perfect candidate for carbon dioxide adsorption, a major environmental pollutant. Sodium hydroxide is essential for the metal carbonation process which, is easily produced by the bipolar membrane electrodialysis process. Various strategies are available for its recovery, like reverse osmosis (RO), nanofiltration (NF), ultrafiltration (UF), and ED. This review discusses the ED process by ion exchange membrane for alkali recovery are discussed.
Moon, Deok-Soo;Kim, Kwang Soo;Gi, Ho;Choi, Mi Yeon;Jung, Hyun Ji;Kim, Hyun Ju
Journal of the Korean Society for Marine Environment & Energy
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v.16
no.4
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pp.227-238
/
2013
The purpose of this study is to develop a process technology to produce high hardness drinking water which meet drinking water standard, remaining useful minerals like magnesium and calcium in the seawater desalination process while removing the sulfate ions and chloride ions. Seawater have been separated the concentrated seawater and desalted seawater by passing on Reverse Osmosis membrane (RO). Using Nano-filtration membrane (NF), We were prepared primary mineral concentrated water that sodium chloride were not removed. By the operation of electro-dialysis (ED) having ion exchange membrane, we were prepared concentrated mineral water (Mineral enriched desalted water) which the sodium chloride is removed. We have produced the high hardness water to meet the drinking water quality standards by diluting the mineral enriched desalted water with deionized water by RO. Reverse osmosis membranes (RO) can separate dissolved material and freshwater from seawater (deep seawater). The desalination water throughout the second reverse osmosis membrane was completely removed dissolved substances, which dissolved components was removed more than 99.9%, its the hardness concentration was 1 mg/L or less and its chloride concentration was 2.3 mg/L. Since the nano-filtration membrane pore size is $10^{-9}$ m, 50% of magnesium ions and calcium ions can not pass through the nano-filtration membrane, while more than 95% of sodium ions and chloride ions can pass through NF membrane. Nano-filtration membrane could be separated salt components like sodium ion and chloride ions and hardness ingredients like magnesium ions and calcium ions, but their separation was not perfect. Electric dialysis membrane system can be separated single charged ions (like sodium and chloride ions) and double charged ions (like magnesium and calcium ions) depending on its electrical conductivity. Above electrical conductivity 20mS/cm, hardness components (like magnesium and calcium ions) did not removed, on the other hand salt ingredients like sodium and chloride ions was removed continuously. Thus, we were able to concentrate hardness components (like magnesium and calcium ions) using nano-filtration membrane, also could be separated salts ingredients from the hardness concentration water using electrical dialysis membrane system. Finally, we were able to produce a highly concentrated mineral water removed chloride ions, which hardness concentration was 12,600 mg/L and chloride concentration was 2,446 mg/L. By diluting 10 times these high mineral water with secondary RO (Reverse Osmosis) desalination water, we could produce high mineral water suitable for drinking water standards, which chloride concentration was 244 mg/L at the same time hardness concentration 1,260 mg/L. Using the linked process with reverse osmosis (RO)/nano filteration (NF)/electric dialysis (ED), it could be concentrated hardness components like magnesium ions and calcium ions while at the same time removing salt ingredients like chloride ions and sodium ion without heating seawater. Thus, using only membrane as RO, NF and ED without heating seawater, it was possible to produce drinking water containing high hardness suitable for drinking water standard while reducing the energy required to evaporation.
The distribution of physicochemical environmental factors and microbiological factors was studied at 6 sampling sites in Kyeongge Bay of Yellow Sea from October 1989 to October 1990. The total bacterial number, saprophytic bacterial number, petroleum-degrading bacterial number, bacterial biomass, and bacterial secondary production were measured in the range of 0.09~1.24*10$^{7}$ cells/ml, 7~60000 CFUs/ml, 0~240 cells/ml, 14.16~301 .$\mu$g-C/l, and 0.13~11.82 mg-C/m$^{3}$/hr, respectively. The turnover times of $^{3}$H-glucose and $^{3}$H-acetate were in range of 6.5~6984 and 41~24897 hours, respectively. The spatial distribution of heterotrophic bacterial communities were hightly affected by influx of organic pollutants from the coastal area and the seawater exchange with offshore.
Kim, Hyun-Ji;Hamm, Se-Yeong;Kim, Nam-Hoon;Cheong, Jae-Yeol;Lee, Jeong-Hwan;Jang, Sung
Economic and Environmental Geology
/
v.42
no.6
/
pp.575-589
/
2009
Groundwater has been extracted for irrigation in Sacheon-Hadong area, which is close to the South Sea. We analyzed chemical components of groundwater to examine the effects of seawater intrusion and agricultural activities in the study area. Most groundwater samples displayed the Na/Cl concentration ratios similar to that of seawater (0.55) with an increasing tendency of electrical conductivity ($227-7,910\;{\mu}S/cm$) towards the coast. In addition, statistical interpretation of the cumulative frequency curves of Cl and $HCO_3$ showed that 30.1% of the groundwater samples were highly affected by seawater intrusion. Groundwaters in the study area mostly belonged to the Ca-Cl and Na-Cl type, demonstrating that they were highly influenced by seawater intrusion and cation exchange. The result of oxygen-hydrogen isotope analysis demonstrated slightly higher $\delta^{18}O$ ((-8.53)-(-6.13)‰) and ${\delta}D$ ((-58.7)-(-43.7)‰) comparing to mean oxygen-hydrogen isotope ratios in Korea. As a result of nitrogen isotope analysis, the $\delta^{15}N-NO_3$ values ((-0.5)-(19.1)‰) indicate two major sources of nitrate pollution (organic nitrogen in soil and animal and human wastes) and mixed source of the two. However, denitrification may partly contribute as a source of nitrogen. According to factor analysis, four factors were identified among which factor 1 with an eigenvalue of 6.21 reflected the influence of seawater intrusion. Cluster analysis indicated the classification of groundwater into fresh, saline, and mixed ones.
To evaluate the change for water quality after the water gate operation in Shiwha lake, in situ survey were conducted on september in 2000 and January, march, jane in 2001. Chemical characteristics and eutrophication level was estimated from the survey data. The water quality of the Shihwa lake was greatly affected by pollutant load from rainfall, and formation of stratification in summer and winter was increased to effect on nutrient release from sediment. Especially, high concentration of chlorophyll-a was occurred in autumn, due to increased nutrient, high water temperature and low salinity after rainfall runoff. The mean concentration of DIN, DIP were 0.346mg/L, 0.0217mg/L in surface water and 0.826mg/L, 0.0415mg/L in bottom water, respectively, which were over III grade of seawater standard. Also high percentage of ammonia nitrogen to DIN in bottom water for autumn and winter was affected by released nutrient from sediment. Correlation analysis of chlorophyll-a versus TSS was shown that organic matter was affected by autochthonous organic matter stem from the algae, these factor showed reverse correlation about salinity. Closely correlations among to the water quality constituent in continuity survey was appeared. The results of eutrophication index estimation showed the high potentiality of red tide occurrence in Shiwha lake, particularity in summer or fall. Overall water quality was greatly improve to compared with measuring data during 1997~1998 at the beginning water gate operation, which reported by KORDI. Therefore, to improve of water quality in Shiwha lake, we need to establish of management plan about nutrient release from sediment, rainfall runoff, maximum of seawater exchange.
Real-time monitoring for environmental factors (temperature, salinity, chlorophyll-a, etc.) and fugacity of carbon dioxide ($fCO_2$) was conducted at an oyster Crassostrea gigas farm in Goseong Bay, south coast of Korea during 2-4th of November, 2011. Surface temperature and salinity were ranged from $17.9-18.7^{\circ}C$ and 32.7-33.8, respectively, with daily and inter-daily variations due to tidal currents. Surface $fCO_2$ showed a range of $390-510{\mu}atm$ and was higher than air $CO_2$ during the study period. Surface temperature, salinity and $fCO_2$ are showed significant correlations with chl.-a and nutrients, respectively. It means when chl.-a value is high in surface water of the oyster farm, active biological production consume $CO_2$ and nutrients from environments and produce oxygen, suggesting a tight feedback between biological processes and environmental reaction. Thus, factors affecting the surface $fCO_2$ were evaluated using a simple mass balance. Temperature and biological productions by phytoplankton are the main factors for $CO_2$ drawdown from afternoon to early night, while biological respiration increases seawater $CO_2$ at night. Air-sea exchange fraction acts as a $CO_2$ decreasing gear during the study period and is much effective when the wind speed is higher than $2-3m\;s^{-1}$. Future studies about organic carbon and biological production/respiration are required for evaluating the roles of oyster farms on carbon sink and coastal carbon cycle.
This study was performed to investigate the formation and mass production of resting eggs by freshwater rotifer, Brachionus calyciflorus as influenced by different aeration supplements and exchange intervals of culture water in 15-L culture vessels and 500 L culture tanks. The maximum densities and mixis rates of the rotifers were not different between experimental group exposed to air or oxygen supplements. However, the fertilization rate and formation of resting eggs of the rotifers in the air-supplemented group were significantly higher than those in the oxygen supplemented group. In the experiment concerning exchange interval of culture water, the maximum density of the rotifers and formation of resting eggs in the batch culture were significantly higher than those in the semi-continuous culture with exchange of water every day. The formation of resting eggs per Chlorella dry weight was highest in the semi-continuous culture with exchange of water every day. The resting eggs of rotifers were produced at a density of $51.8{\sim}57.9{\times}10^6$ eggs in 500-L culture tanks. In this study, the batch culture with air is an effective method for mass production of resting eggs by the freshwater rotifer, B. calyciflorus, and the efficiency of mass production of resting eggs by this rotifer was similar to that of the seawater rotifers, B. plicatilis and B. rotundiformis.
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