• Title/Summary/Keyword: Saturated solution

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Photochemical Reaction of Aqueous Ethanol in the Presence of CO (일산화탄소가 포함된 에탄올 수용액의 광화학 반응)

  • Kim, Hui Jeong;Lee, Hyeong Cheol;Park, Hyeong Ryeon
    • Journal of the Korean Chemical Society
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    • v.38 no.4
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    • pp.271-275
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    • 1994
  • The photochemical reaction of aqueous ethanol saturated with argon and carbon monoxide has been investigated using 184.9 nm UV light. The photochemical reaction of $1{\times}10^{-2}$ M aqueous ethanol saturated with argon results in the formation on the acetaldehyde and 2,3-butanediol. The irradiation of the solution saturated with carbon monoxide causes the formation of carbonylation and carboxylation products such as ${\alpha}$-hydroxypropionaldehyde, formaldehyde, glyoxal, formic acid, oxalic acid and glyoxylic acid in addition to above two products. But in the case of concentrated ethanol solutions, the irradiation did not give carbonylation and carboxylation products. The initial quantum yields of the products were determined and probable mechanisms for the reaction were presented on the basis of product analysis.

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Determination of Normal Saturated- and Polycyclic Aromatic Hydrocarbons in the River Water of Bangladesh by Liquid-Liquid Extraction and Gas Chromatography

  • Mottaleb, M.A.;Sarma, D.K.;Sultana, S.;Husain, M.M.;Alam, S.M.M.;Salehuddin, S.M.
    • Bulletin of the Korean Chemical Society
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    • v.24 no.1
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    • pp.99-105
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    • 2003
  • A liquid-liquid extraction followed by evaporative concentration method was used to determine the concentration of normal, or straight chain, saturated hydrocarbons (NSH) $(C_{10}\;to\;C_{24})$ and polycyclic aromatic hydrocarbons (PAH) here defined as: fluorene, anthracene, pyrene, chrysene and perylene, in the Buriganga River water of Bangladesh. Samples were collected from 5 and 25 cm depth of water at the southern, middle and northern parts of the river at Postogolla, Sadarghat and Sowarighat stations. Hydrocarbons were extracted from 450 mL of water into 75 mL n-hexane and then concentrated into 1 or 2 mL solution by evaporation. These solutions were analyzed by gas chromatography. The highest and lowest concentrations were determined as $257\;{\mu}gL^{-1}\;for\;C_{13}\;and \;0.24\;{\mu}g\;L^{-1}\;for\;C_{22}$ at 5 ㎝ depth of water, at the northern part of the Sowarighat and southern part of the Postogolla, respectively. This method could allow the analysis of water for $C_{22}$ as low as $0.24\;{\mu}g\;L^{-1}$.

Measurements of the Diamagnetic Susceptibility of NaCl Aqueous Solution

  • Lee, Seung-Hwan
    • Journal of Navigation and Port Research
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    • v.27 no.6
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    • pp.669-675
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    • 2003
  • Using a SQUID magnetometer, the diamagnetic susceptibility of NaCl aqueous solution was measured with high accuracy in a magnetic field of up to 6 Tat 25$\pm0.05^{\circ}C$. The NaCl concentrations adopted in this experiment were 0 (water), 7.5, 15, 23, 26.2, 26.6 and 100% (crystal) with the concentration error of $\pm$0.04%. Experimental data was compared with the calculated value of susceptibility derived from dependence of the vapor pressure on NaCl concentration As a result, our measured value was almost in accordance with the calculated value. It was found that the diamagnetic susceptibility shows a decrease of approximately 10% within the saturated concentration (26.2%) and that the susceptibility is one of the effective cause for the concentration dependence in the gas-liquid interface deformation of the NaCl solution.

암모니아/물 흡수식 냉동기의 대향류 판형 재생기의 수치모델

  • 지제환;정은수;정시영
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.10
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    • pp.1034-1041
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    • 2001
  • A numerical model which simulates the flow boiling process of the ammonia/water solution within a plate type generator for ammonia/water absorption refrigerators was developed. The ammonia/water solution flows downward under gravity and the ammonia/water vapor generated by flow boiling flows upward. The heating medium flows counter to the ammonia/water solution. The flow pattern within the generator was assumed to be a bubbly flow, and the liquid and vapor phases were assumed to be saturated. It was shown that the boiling of ammonia occurred mainly in the upper part of the generator. The effects of the heating medium inlet temperature, the mass flow rate of the heating medium and the mass flow rate of ammonia/water solution into the generator on the generation of ammonia/water vapor were investigated.

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The Effect of Pressure on Laminar Film Condensation along a Horizontal Plate (수평평판의 층류 막응축에서 압력의 영향)

  • Lee, Euk-Soo;Lee, Sung-Hong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.12
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    • pp.945-953
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    • 2008
  • Laminar film condensation of saturated vapor in forced flow over a flat plate is analysed. The problem is formulated as exact boundary-layer solution and integral approximate solution. From numerical solutions of the governing equations, it is found that the energy transfer by convection and the effect of inertia term in the momentum equation in negligibly small for low pressure but quite important for high pressure. The condensate rate, liquid-vapor interfacial shear stress and local heat transfer are strongly dependent on the reduced pressure $P_r$ and the modified Jacob number Ja/Pr.

[ H2 ] Control of Uncertain Systems with Actuator Saturation (구동기포화를 갖는 불확실한 시스템의 H2 제어)

  • Choi, Hyoun-Chul;Hong, Suk-Kyo;Chwa, Dong-Kyoung
    • Journal of Institute of Control, Robotics and Systems
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    • v.13 no.10
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    • pp.1000-1006
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    • 2007
  • This paper presents an LMI-based method to design a saturated state-feedback $H_2$ controller for uncertain systems with actuator saturation. Specifically, the paper proposes a sufficient condition such that the system under norm-bounded uncertainties and actuator saturation is asymptotically stable and the $H_2$-norm of the system has an upper-bound. The resulting condition is further utilized to solve a convex optimization problem specified in the context of $H_2$-norm minimization, whose solution yields a saturated $H_2$ controller. A numerical example is presented to show the effectiveness of the proposed method.

Colorimetric Method of Determining Unsaturated Fatty Acids in Animal Tissues (불포화지방산(不飽和脂肪酸)의 비색정량법(比色定量法))

  • Huh,, Rhin-Sou;Chang, In-Ho
    • Journal of Nutrition and Health
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    • v.15 no.1
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    • pp.9-14
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    • 1982
  • The present paper describes a colorimetric method of determining the free and total unsaturated fatty acids in animal tissues. The procedure is based in three steps on the following principles : First step is that the tissue homogenates are extracted in chilled acetone in order to eliminate the interfering substance, such as phospholipids, sulfatides and proteins. At next step, after centrifugation acetone layer is decanted and evaporated to dryness. Then the extract is shaken with heptane to solve in the solvent. That the characteristic nature of copper salts of unsaturated fatty acids are freely soluble in heptane and those of saturated acids are not is the bases of separating one from another. Thus unsaturated fatty acids can be isolated in heptane as their salts from saturated acids and other lipid mixture by shaking with copper reagent. Finally the yellowish brown color developed by adding color reagent (0.2% sodium diethyldithiocarbamate in n-butanol solution) which reacts with the copper salts of the acids and produces the color is measured colorimetrically.

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Noise Analysis of Sub Quarter Micrometer AlGaN/GaN Microwave Power HEMT

  • Tyagi, Rajesh K.;Ahlawat, Anil;Pandey, Manoj;Pandey, Sujata
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.9 no.3
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    • pp.125-135
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    • 2009
  • An analytical 2-dimensional model to explain the small signal and noise properties of an AlGaN/GaN modulation doped field effect transistor has been developed. The model is based on the solution of two-dimensional Poisson's equation. The developed model explains the influence of Noise in ohmic region (Johnson noise or Thermal noise) as well as in saturated region (spontaneous generation of dipole layers in the saturated region). Small signal parameters are obtained and are used to calculate the different noise parameters. All the results have been compared with the experimental data and show an excellent agreement and the validity of our model.

Nanotribological Behavior of Cu Oxide and Silicon Tip (Cu Oxide와 Silicon Tip 사이의 나노트라이볼러지 작용)

  • Kim, Tae-Gon;Kim, In-Kwon;Park, Jin-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.364-365
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    • 2005
  • This paper report nanotribological behavior between Si tip and Cu wafer surfaces which was treated various concentration of $H_2O_2$. This experimental approach has proven atomic level insight into Cu CMP. It has been used to study interfacial friction and adhesion force between Si tip and Cu wafer surfaces in air by atomic force microscopy (AFM). Adhesion force of Cu surfaces which was pre-cleaned in diluted HF solution was lager than Cu oxide surfaces. Adhesion force of Cu oxide surface was saturated around 7 nN. Slope of normal force vs lateral signal was increased as increasing concentration of $H_2O_2$ and it was saturated around 24. Friction force of Cu oxide was lager than Cu.

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Temperature effect on multi-ionic species diffusion in saturated concrete

  • Damrongwiriyanupap, Nattapong;Li, Linyuan;Limkatanyu, Suchart;Xi, Yunping
    • Computers and Concrete
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    • v.13 no.2
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    • pp.149-171
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    • 2014
  • This study presents the mathematical model for predicting chloride penetration into saturated concrete under non-isothermal condition. The model considers not only diffusion mechanism but also migration process of chloride ions and other chemical species in concrete pore solution such as sodium, potassium, and hydroxyl ions. The coupled multi-ionic transport in concrete is described by the Nernst-Planck equation associated with electro-neutrality condition. The coupling parameter taken into account the effect of temperature on ion diffusion obtained from available test data is proposed and explicitly incorporated in the governing equations. The coupled transport equations are solved using the finite element method. The numerical results are validated with available experimental data and the comparison shows a good agreement.