• Analytical Science and Technology
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• v.22 no.6
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• pp.471-479
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• 2009

This study was performed to improve the analytical methods and re-establish the regulatory standard of PCBs-containing solid wastes for sufficient management in which has been concerned internationally. To do this, the sampling, pre-treatment and quantification methods which were used in USA and Japan were discussed. It was thought properly that new standard of PCBs-containing solid wastes was established through correlation with PCBs concentration of transformer oil. The surface wipe sampling was selected in the nonporous materials and cutting sampling in the porous materials. In the absence of transformer oils, electrical equipment is PCB-contaminated if it has PCBs at ${\geq}0.4{\mu}g/100cm^2$ as measured by a wipe test of a nonporous surface and if it has at 0.04 mg/L as measured by cutting test of a porous material. Also, new analytical methods for PCBs containing solid waste were proposed.

• Journal of Environmental Health Sciences
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• v.42 no.2
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• pp.102-111
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• 2016

Objectives: This study was conducted to evaluate the use of polyurethane foam disk passive air samplers (PUF PAS) for better measurement of atmospheric polychlorinared dibenzo-p-dioxins/furans (PCDD/Fs) concentrations compared to PUF PAS combined with high volume air samplers (HVS). Methods: Air samples were collected by a low volume air sampler (LVS) and PUF PAS. A total of two pairs were continuously collected for six months, but the PUF was replaced every two months. Results: A good correlation was shown ($R^2=0.8595$, p<0.0001) between atmospheric PCDD/Fs concentration measured by the LVS and PUF PAS. The average air sampling rate ($1.5m^3/day-sampler$) of all PCDD/Fs congeners showed a middle of the means which were measured using a HVS by other researchers in different cities. In addition, the air sampling rates of the LVS for each congener made less difference than did those of the HVS. Conclusion: It was found that measurements using the LVS were less influenced by atmospheric peak PCDD/Fs concentrations. However, trace POPs such as PCDD/Fs may involve relatively large analytical errors in measurement, and as a result the air sampling rate of the respective PCDD/Fs isomer is also likely to involve errors. The method of using a regression straight line between the concentrations obtained from the LVS and those from the PUF PAS was judged higher than the method using the air sampling rate, since the former compensated for the experimental errors in the process of evaluation of atmospheric PCDD/F concentrations using the PUF PAS.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.5 no.2
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• pp.212-225
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• 1995

This study was performed in a diatomite factory located at Pohang City, Kyeongsangbuk-Do. The major objectives were to evaluate sampling and analytical methods of diatomaceous earth dust. Concentrations of total and respirable diatomaceous earth dust were measured. Size distribution of dust was analyzed by a personal cascade impactor and the particle size analyzer which is an application of multiple diffraction method. Also crystalline silica in respirable and total dust samples was analyzed quantitatively by X-ray diffraction and Fourie Transform Infrared Spectroscopy(FTIR). The results were as follows: The airborne total and respirable dust concentrations, particle size distribution, and cristalline silica(quartz) concentrations showed approximately a log-normal distribution. The means of totaldust concentrations at flour maufacturing, fire brick grinding and packaging processes exceeded the Korean and American Conference of Governmental Industrial Hygienists standards, $10mg/m^3$. The size distribution of diatomaceous earth dust was log-normal and identified as the rspirable particle mass and thoracic particle mass. The crystalline silica in respirable and total dust samples was identified to quartz and contained about 10 % in those samples. Finally, it is necessary to study the applicability of multiple diffraction for particle size distribution to compare the ACGIH's size selective sampling with other materials containing crystalline silica. Also, advanced quantitative study to X-ray diffraction and FTIR methods shoud be carried out 10 verify general and specific characteristics for respirable crystalline silica.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.4 no.2
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• pp.208-223
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• 1994

The purpose of this study was to evaluate the efficiency of diffusive(or passive) sampler in measuring airbone organic solvents. Diffusive samplers are generally simple in construction and do not require power for operation. The efficiency of the diffusive samplers has not sufficiently been investigated in Korea. Three types of samplers were studied in this study. The sampling and analytical results by passive samplers were compared with results by charcoal tube method recommended by NIOSH(National Institute for Occupational Safty and Health). The following characteristics are identified and studied as critical to the performance passive monitors; recovery, reverse diffusion, storage stability, accuracy and precision, face velocity and humidity, n-Hexane, TCE(trichloroethylene) and toluene were used as test vapors. A dynamic vapor exposure system consisting of organic vapor generator and sampling chamber for evaluating diffusive samplers are made. The results of the study are summarized as follows. 1. NIOSH recommands that the overall accuracy of a sampling method in the range of 0.5 to 2.0 times the occupational health standard should be ${\pm}25$ percent for 95 percent confidence level. Among three types of diffusive samplers, sampler A has permeation membrane and samplers Band C have diffusive areas, samplers A and B met the criterion that overall accuracy for 95% confidence level of the samplers were within ${\pm}25$ percent of the reference value. Sampler C had overall accuracy ${\pm}9.6%$ and ${\pm}11.8%$ in hexane and TCE, respectively. The concentration of toluene was overestimated in sampler C with overall accuracy of ${\pm}43.9%$. 2. The desorption efficiencies of diffusive samplers were 96-107%. 3. There was no significant sampe loss during four weeks of storage both with and without refrigeration. 4. There was no significant reverse diffusion, when the samplers were exposure to clean air for 2 hours after sampling for 2 hours at the level of 2 TLY. 5. In case of 8 hours sampling, relative differences(RD) of concentrations between charcoal tube method and diffusive method were 15-39%, 13-46%, and 4-35% for sampler A, B and C, respectively. The performance was poor in 8 hours sampling for multiple substance monitors. 6. At high velocity(100 cm/sec), samplers B and C overestimated the concentrations of organic vapors, and sampler A with permeation membrance gave better results. 7. At 80% relative humidity, samplers showed no siginificant effect. Low humidity also did not affect the diffusive samplers.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.354-357
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• 2004

The addition of oxygenates to diesel fuel can significantly reduce particulate emissions. Dibutyl maleate (DBM) and tripropylene glycol methyl ether (TGME) have been identified as possible additives based on their physicochemical characteristics and performance in engine test. However, their potential environmental impacts are unknown. therefore, practical considerations in the selection of an oxygenate additives should include cost, availability, compatibility with engines and fuel, and, particularly, its overall environmental impact. This study was investigated to determine optimal condition for the analysis of potential diesel oxygenates using SPME technique with GC-FID. Four fibers were compared and CAR/PDMS fiber was found to be the most sensitive when used direct-sampling. An absorption time of 30min and a desorption time of 5min provided to be the most sensitivity. The effects of experimental parameters such as the addition of salts, agitation, absorption time, compositon on the analysis were investigated. Analytical parameter such as linearity was also evaluated.

• 제어로봇시스템학회:학술대회논문집
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• 1998.10a
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• pp.58-63
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• 1998

B.Widrow established fundamental relations between the least-mean-square (LMS) algorithm and the digital Fourier transform［1］. By extending these relations, we proposed the short time spectra analysis system using the LMS algorithm［2]. In that paper, we used the normal LMS algorithm on the thought of dealing with only real analytical signal. This algorithm minimizes the real mean-square by recursively altering the complex weight vector at each sampling instant. But, the short time spectra analysis sometimes deals with the complex signal that is outputted from complex analog filter. So, in order to optimize and develop this methods, furthermore it is necessary to derive an algorithm for the complex analytical signal. In this paper, we first discuss the new adaptive system for the spectra analysis using the complex LMS algorithm and then derive convergence condition, time constant of coefficient adjustment and frequency resolution by extending the discussion. Finally, the effectiveness of the proposed method is experimentally demonstrated by applying it to the measurement of transfer performance on complex analog filter.

• Journal of the Korea Institute of Military Science and Technology
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• v.21 no.3
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• pp.370-378
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• 2018

The mission data in missile systems should be quickly and reliably transmitted from a mission transmission device to a guidance control unit. The MIL-STD-1553B is one of the reliable communication standards, but its bit rate is generally limited to 1Mbps due to the intrinsic properties of its electrical design. Therefore, the bus controller needs to be optimized to efficiently transmit the mission data on the inevitably limited bit rate. This paper proposes an analytical approach based on sampling-based optimization methods to maximize the data throughput without data loss. The proposed approach was evaluated in the simulations with the data transmission model for the MIL-STD-1553B communication system. The results of the proposed methods were applied to a real-time system and showed that the proposed method was successfully performed.

• Analytical Science and Technology
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• v.24 no.3
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• pp.200-211
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• 2011

In this study, 13 compounds including four volatile fatty acids (VFA) and nine volatile organic compounds (VOC) were analyzed by cryogenic trapping-thermal desorption technique. In order to evaluate the analytical method for VFA, calibration experiments were performed using five different sorbent materials. When the calibration results are compared between different sorbents, sampling tube filled with Carbopack X showed the highest response factor (RF) for both VFA and VOC. To validate this new analytical method for VFA using cryogenic trapping-thermal desorption technique, this method was compared with alkali absorption method recommended by the odor prevention law of the Korea Ministry of Environment (KMOE). For this purpose, unknown samples were analyzed by two different methods, i.e., cryogenic trapping-thermal desorption (TD) and alkali absorption with solid phase microextraction (SPME). When the results of two different methods were compared, ratios of concentrations determined by the two analytical methods (TD/SPME) was found as 0.46 (valeric acid) ~ 0.71 (isovaleric acid). Therefore, additional study is required to properly establish and find stable analytical conditions for VFA analysis. Furthermore, comparison between two different methods should be made with more reliable calibration approaches.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.4
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• pp.357-366
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• 2010

The purpose of this study is to evaluate a method for the measurement of N,N-Dimethylformamide (DMF) and to apply the method to the ambient air samples. For the determination of DMF together with other general VOCs (e.g., benzene, toluene, and xylenes), adsorption sampling and thermal desorption with GC/MS was used in this study. The sampling and analytical approaches tested in this study showed a good repeatability and linearity with lower detection limits of less than 0.35 ppb. Field measurements were carried out at three industrial sites (Daegu-Seongseo, Siwha and Banwall industrial complexes) and one residential site in Daegu city during a period from October 2006 to November 2008. DMF was detected in 71.8% of the total samples from the Seongseo industrial complex, well known for textile industry. In contrast, DMF was detected in only 20.4% and 12.9% of all the samples from the other two sites in Banwall and Siwha industrial complexes, respectively. This implies that sources of DMF should be strongly associated with textile industry. The mean concentration of DMF also appeared to be the highest in Seongseo site (5.95 ppb), followed by a residential site in Daegu (3.28 ppb), Banwall (0.88 ppb) and Siwha (0.55 ppb). In this study, we demonstrated the environmental significance of DMF in urban ambient air. To our knowledge, the DMF measurement introduced in this paper is the first case of an official report in Korea.

• Computational Structural Engineering
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• v.9 no.4
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• pp.107-115
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• 1996

Displacement response is one of the important parameter to determine vibration characteristics of bridge structure. Reliable estimate of displacement response is obtained economically from integration of measured acceleration data in frequency domain. Proper sampling rate of frequency in discretization process of measured acceleration is proposed. Comparison of integrated and directly measured displacement response from laboratory experiment for a cantilever beam shows good agreement each other. Mode shape obtained from estimated displacement response also closely match with analytical result, thus the developed method is proved to be effective in practical use.