• Title/Summary/Keyword: Salt Contamination

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금속염용액의 분무열분해에 의한 TiC/Co복합분말 제조 (Synthesis of TiC/Co Composite Powder by the Spray Thermal Conversion of Metallic Salt Solution)

  • 이길근;문창민;김병기
    • 한국분말재료학회지
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    • 제10권4호
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    • pp.228-234
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    • 2003
  • In the present study, the focus is on the synthesis of titanium carbide/cobalt composite powder by the spray thermal conversion process using metallic salt solution as the raw materials. Two types of oxide powders of Ti-Co-O system were prepared by the spray drying of two types of metallic salt solutions : titanium chloride-cobalt nitrate and $TiO_2$ powder-cobalt nitrate solutions. These oxide powders were mixed with carbon black, and then these mixtures were carbothermal reduced under a flowing argon atmosphere. The changes in the phase structure and thermal gravity of the mixtures during carbothermal reduction were analysed using XRD and TG-DTA. In the case of using the titanium chloride-cobalt nitrate solution, it could not be obtained TiC/Co composite powder due to contamination of the impurities during the spray drying of the solution. However, in tile case of using the $TiO_2$ powder-cobalt nitrate scullion, TiC-15 wt. %Co composite powder could be synthesized by the spray thermal conversion process. The synthesized TiC-15 wt. %Co composite powder at 120$0^{\circ}C$ for 2 hours has average particle size of 150 nm.

전국 염전에서 생산된 갯벌천일염, 함수 및 해수의 중금속 함량 평가 (Evaluation of Heavy Metal Contents in Mudflat Solar Salt, Salt Water, and Sea Water in the Nationwide Salt Pan)

  • 김학렬;유영주;이인선;고강희;김인철
    • 한국식품영양과학회지
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    • 제41권7호
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    • pp.1014-1019
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    • 2012
  • 전국 염전에서 생산된 갯벌천일염의 수분함량과 함수 및 염전 저수지 해수에 포함된 중금속(수은, 납, 카드뮴, 비소, 구리) 함량을 평가하였으며, 생산지역에 따른 갯벌천일염의 중금속 함량 차이를 비교 분석하였다. 갯벌천일염의 수분함량은 7.357%에서 14.862% 범위였으며, 중금속 함량은 생산지역에 따라 차이가 있었으나, 비소함량은 0.007 ppm에서 0.497 ppm 수준으로 기준치를 초과한 함량은 검출되지 않았으며, 카드뮴은 불검출에서부터 0.101 ppm, 납은 불검출에서부터 0.191 ppm, 수은은 0.006 ppb에서 0.180 ppb 수준으로 기준치를 초과한 시료는 검출되지 않았다. 천일염의 구리함량은 0.039 ppm 수준에서 4.794 ppm 수준의 범위를 나타내었으며, 지역에 따라 다소 높은 수준의 함량이 검출되었다. 염전 저수지 해수에 포함되어 있는 비소함량은 불검출에서 0.474 ppm 수준이었으며, 카드뮴은 불검출에서 0.009 ppm, 납은 0.005 ppm에서 0.038 ppm, 수은은 불검출에서 0.018 ppb, 구리함량은 0.267 ppm 수준에서 3.184 ppm 수준의 범위였다. 전국 염전 함수에 대한 비소함량은 0.012 ppm에서 0.914 ppm, 카드뮴은 불검출에서 0.021 ppm, 납은 0.010 ppm에서 0.094 ppm 수준의 범위였으며, 수은은 불검출에서 0.0221 ppb, 구리함량은 0.372 ppm 수준에서 3.275 ppm 수준을 나타내었으며, 모든 시료에서 기준치를 초과한 함량은 검출되지 않았다. 이상과 같은 결과로부터 전국 염전에서 생산된 천일염, 함수 및 해수에 포함된 중금속 함량은 안전한 수준인 것으로 판단되지만 염전 결정지 바닥재로 사용하고 있는 PVC의 잠재적인 위해성을 감안한다면 이에 대한 지속적인 관리가 절실히 요청된다.

염진해 오손도 자동측정장치 (Automatic Measuring Apparatus for Salt and Dust Contamination)

  • 최남호;구경완;이명섭;한상옥;정재기;조성배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.187-190
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    • 1999
  • To reduce the maintenance expence, and the possibility of electric outage and accident, accurate measurement should be carried. But the classical method has some problems in the aspect of man power, reliability, and expence. In this paper, we propose a new type apparatus, which could detect the degree of contamination on insulators on outdoor insulation system, such as transmission and distribution line insulator and bushing. The new type apparatus consists of Pelltier module, electrode system, and measuring part. At first leakage current detecting method was considered, then with the fault(oxidation of electrode) of that method we should propose a another method. We carried various test to prove the possiblity and reliability of the propoused apparatus. And we get some useful result with laboratory test.

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국내 해안지역의 오손특성 분석 (Analysis of Salt Contamination in the domestic coast area)

  • 김동명;김병숙;이남우;최선규
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 A
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    • pp.504-505
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    • 2006
  • We installed the measurement equipment which measure the equivalent Salt Deposit Density(ESDD) of the domestic coast area in the selected 112 place and investigated the influence of the wind which blow at the point of 500m from coast installing a wind vane, wind gauge for realtime measurement. During september${\sim}$december, 2005, ESDD which passively measured at the point of 50m from coast is maximum C grade in the Homigot of Pohang, B grade in the Gochang and A grade in the remaining point. Also ESDD which is measured in the east coast, west coast respectively is the more the distance being far from the coast to inland, the more ESDD rapidly decreasing but each area of the south coast is difficult to identify the decreased tendency because of very low measurements.

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해안지방의 염분 누적오손 특성 (Analysis of Cumulative Salt Contamination in the Coast Area)

  • 권태호;김동명;조성현
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 제39회 하계학술대회
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    • pp.2067-2068
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    • 2008
  • 해안지방의 염분 누적오손 특성을 분석하기 위하여 등가염분부착밀도(ESDD : Equivalent Salt Deposit Density) 측정장치를 국내 112 곳을 선정하여 설치하였다. 해안에서 500m 지점에 풍향, 풍속계를 설치하고, 실시간으로 측정하여 바람에 의한 영향을 분석하였다. 2005년 10월부터 2007년 9월까지 측정한 결과 고창은 해안에서 50m 떨어진 지점에서 최대 D 등급, 2,000m 지점은 B등급까지 오손되었으며, 포항 호미곳은 D등급까지 오손되었다. 분석결과 동해안의 오손특성은 타 지역보다 해안에 가까울수록 부착밀도가 급격히 증가하였으나, 서해안보다는 오손정도가 낮고 남해안보다는 높게 나타났다.

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용해성물질과 비용해성물질로 인공 오손된 송전용 애자의 누설전류 특성 (Characteristics of Leakage Current on Transmission Insulators Contaminated Artificially with Soluble and Nonsoluble Materials)

  • 최인혁;최장현;이동일;김찬영
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제53권9호
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    • pp.464-469
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    • 2004
  • The leakage current of transmission insulators contaminated with salt, clay, and kaolin was examined in the Gochang's Long Periods Testing Center. The Insulators were artificially contaminated and estimated with the method of equivalent salt deposit density(ESDD). The artificially contaminated insulators were installed with the same condition as in the real transmission power line and applied with 154 (kV). The leakage current of the artificially contaminated insulators was measured with environment conditions, such as temperature and humidity by the a automatic leakage current detecting system. The leakage current of heavily contaminated insulator was abruptly increased above 72[%] of humidity, even though the leakage current was similar between the contaminated and non-contaminated insulators below 72[%] of humidity. Also, it was found that the humidity was much more important than the temperature in the leakage current of transmission insulators. The leakage current of contaminated insulator was decreased when it was plenty of rainfall, resulting from natural washing.

인공오손에 따른 배전기자재의 건조 및 습윤 섬락에 관한 연구 (The Study on the Dry and Wet Flashover Voltages of the Artificially Salt Contaminated Distribution Facilities)

  • 김찬영;김동명;권태호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.487-488
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    • 2008
  • The dry and wet flashover characteristics on the contaminated distribution facilities was investigated. The test were carried out on the suspension insulator, line post insulator, lightning arrester, cut off switch, etc. In the dry state, the flashover voltages of facilities contaminated with B, C, D classes are similar to the non-contaminated ones. However, in the wet state, the flashover voltages of facilities contaminated with B, C, D classes are decreased. The flashover voltages of some few facilities show under the standard value. This results indicate that the high humidity may cause the flashover on distribution facilities.

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Salt fog 내에서 옥외용 고분자 절연물의 내오손 성능 변화 (The Change of Contamination Performance of Polymeric Insulators for Outdoor Use)

  • 김정호;문중섭;박용판;김동명;원호상
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.505-508
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    • 1999
  • In this study, weight loss, ESDD, surface conductivity and leakage current were measured at the different saline solutions by salt fog method. The magnitude of leakage current was higher at higher conductivity of 2 S/m saline water, but weight loss ESDD and surface conductivity which are indices of degradation were lower. This is considered that the current includes mainly ohmic component which doesn\`t contribute to surface degradation. In addition, it is shown that FFT could be useful in measuring initial transition from hydrophobic to hydrophilic surface.

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염무-열 반복 열화에 따른 실리콘 고무의 표면열화특성변화 (The change of surface degradation properties of silicone rubber for salt fog)

  • 오태승;이청;박수길;류부형
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.886-889
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    • 2001
  • Silicone rubber is being used for the housing material of outdoor high voltage insulators such as composite insulator, bushing, surge arrestor and cable terminator because of good tracking and erosion resistance, good hydrophobicity and recovery of hydrophobicity and chemical stability. But, the leakge current occurs on surface of the composite polymeric insulation materials when the insulator is used for a long time with severe contaminative condition and it can lead the contamination flashover. So the leakage current is important to estimate the condition of the silicone rubber surface. In this paper, aging characteristics of silicone rubber used for outdoor insulation have been hydrophobicity of silicone rubber in salt fog chamber with average leakage current monitoring for observing the transformation of surface degradation properties of silicone rubber with different ATH(alumina trihydrate, A1$_2$O$_3$$.$3H$_2$O) filler contents. The experimental results show that a higher peak leakage current and to raise a long time for tracking with increasing amount of ATH by the salt fog and heat recycle ageing.

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옥외 애자용 재료의 표면 전기전도 특성 (Electrical Conduction Properties of Surface in Materials for Outdoor Insulator)

  • 박영국;이운석;정수현;장동욱;임기조
    • 한국전기전자재료학회논문지
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    • 제11권10호
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    • pp.758-762
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    • 1998
  • Electrical conduction property of insulator surface is most important factor to assess the insulation performances of outdoor insulating materials. In this paper, contamination performance of the materials to be used for outdoor insulator such as porcelain, EPDM, silicone rubber was discussed by measuring properties of average leakage current and scintillation discharge pulses under salt fog conditions. The fog was applied by nozzle in chamber and fogging fluids were deionized distilled water, 0.5wt% NaCI solution and 2wt% NaCl solution. The average leakage current showed linearly with applied voltage at dry and clean surface condition. The magnitude of leakage current was almost same at different kinds of samples. In case of deionized distilled water fog, the characteristics of leakage current and applied voltage were much different to those in case of dry and clean condition with 2wt% salt fog. In case of slat fog pollution condition, the leakage current was increased above critical voltage. the scintillation discharges were also activated at the level. The leakage current and scintillation discharges were increased with increasing pollution degree. The resistance to pollution properties of silicone rubber appeared excellent among them.

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