• Title/Summary/Keyword: SWEEP

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Preparation and Characterization of Electrodeposited Cadmium and Lead thin Films from a Diluted Chloride Solution

  • Sulaymon, Abbas Hamid;Mohammed, Sawsan A.M.;Abbar, Ali Hussein
    • Journal of Electrochemical Science and Technology
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    • v.5 no.4
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    • pp.115-127
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    • 2014
  • Cd-Pb thin films were electrodeposited from a diluted chloride solution using stainless steel rotating disc electrode. The linear sweep voltammograms of the single metallic ions show that electrodeposition of these ions was mass transfer control due to the plateau observed for different rotations at concentration (50 and 200 ppm). The voltammograms of binary system elucidate that electrodeposition process always start at cathodic potential located between the potential of individual metals. Currents transients measurements, anodic linear sweep voltammetry (ALSV) and atomic force microscopy (AFM) were used to characterize the electrocryatalization process and morphology of thin films. ALSV profiles show a differentiation for the dissolution process of individual metals and binary system. Two peaks of dissolution Cd-Pb film were observed for the binary system with different metal ion concentration ratios. The model of Scharifker and Hills was used to analyze the current transients and it revealed that Cd-Pb electrocrystalization processes at low concentration is governed by three-dimensional progressive nucleation controlled by diffusion, while at higher concentration starts as a progressive nucleation then switch to instantaneous nucleation process. AFM images reveal that Cd-Pb film electrodeposited at low concentration is more roughness than Cd-Pb film electrodeposited at high concentrated solution.

Methodological Consideration on the Prediction of Electrochemical Mechanical Polishing Process Parameters by Monitoring of Electrochemical Characteristics of Copper Surface

  • Seo, Yong-Jin
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.346-351
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    • 2020
  • The removal characteristics of copper (Cu) from electrochemical surface by voltage-activated reaction were reviewed to assess the applicability of electrochemical-mechanical polishing (ECMP) process in three types of electrolytes, such as HNO3, KNO3 and NaNO3. Electrochemical surface conditions such as active, passive, transient and trans-passive states were monitored from its current-voltage (I-V) characteristic curves obtained by linear sweep voltammetry (LSV) method. In addition, the oxidation and reduction process of the Cu surface by repetitive input of positive and negative voltages were evaluated from the I-V curve obtained using the cyclic voltammetry (CV) method. Finally, the X-ray diffraction (XRD) patterns and energy dispersive spectroscopy (EDS) analyses were used to observe the structural surface states of a Cu electrode. The electrochemical analyses proposed in this study will help to accurately control the material removal rate (MRR) from the actual ECMP process because they are a good methodology for predicting optimal electrochemical process parameters such as current density, operating voltage, and operating time before performing the ECMP process.

Velocity selective optical pumping spectroscopy (속도군 선택 광펌핑 분광학)

  • Park, Sung-Jong;Cho, Hyuck;Lee, Ho-Seong
    • Korean Journal of Optics and Photonics
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    • v.8 no.5
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    • pp.366-371
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    • 1997
  • We performed the velocity selective optical pumping(VSOP) spectroscopy using the rubidium atomic vapor in the room temperature. This spectroscopic technique removes the Doppler broadening by both optical pumping effect and the selection of atoms with a particular velocity. In this experiment, we used two independent lasers; one was a locked laser whose frequency was fixed and the other was a sweep laser whose frequency was tunable. The two beams were passing through the sample in the same direction unlike the conventional VSOP spectroscopy using two counter-propagating beams. We could make the velocity selective range of atoms much wider with this method than the old one.

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A Study on the Aileron Reversal Characteristics of CUS Composite Aircraft Wings (CUS 복합재료 항공기 날개의 에일러론 역전 특성 연구)

  • Kim, Keun-Taek;Song, Oh-Seop
    • Aerospace Engineering and Technology
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    • v.8 no.2
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    • pp.149-159
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    • 2009
  • This paper deals with an analytical study on the aileron reversal characteristics of anisotropic composite aircraft wings modelled as thin-walled beam and having extension-twist structural couplings caused by Circumferentially Uniform Stiffness (CUS) layup scheme. For a study on the aileron reversal of CUS composite wings, it is essential to consider the following effects such as extension-twist structural coupling, wing aspect ratio, and ratio of span-wise and chord-wise length of aileron to wing, initial angle of attack, and sweep angle, etc. The results on the aileron reversal could have a significant role in more efficient designs of thin-walled composite wing aircraft for which this aeroelastic instability is one of the most critical ones.

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A Study on Power Flow Method of Radial Distribution System using a measured data from FRTU in Distribution Automation System (배전자동화 시스템의 단말장치(FRTU)로부터 취득되는 데이터를 이용한 방사상 배전계통 조류계산 방법에 관한 연구)

  • Kim, Hyung-Seung;Choi, Myeon-Song;Lee, Seung-Jae
    • Proceedings of the KIEE Conference
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    • 2015.07a
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    • pp.286-287
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    • 2015
  • Currently, Studies on improving the reliability of power supply is becoming an important issue because of the increase in demand of the electric power system. Therefore necessity of automation in distribution system is increasing day by day. However, a measured voltage data from FRTU of distribution automation system is incorrect because of installation space limits. Therefore there is a need of system analysis method by considering the characteristics of the distribution system. For a distribution system, applying the power flow method of transmission system has some problems, as distribution is radial system and it has unbalanced load. Therefore power flow by considering the characteristics of the distribution system have been studied. Existing power flow analysis of the distribution system has different methods like direct analysis method, backward/forward sweep method, modified method of newton raphson etc. In this paper, an improved power flow analysis method based on backward/forward sweep method is proposed in order to efficiently operate the distribution automation system. The proposed method of power flow has been verified through the result of case study.

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Genomic Detection using Electrochemical Method (전기화학적 방법에 의한 유전자의 검출)

  • Choi, Yong-Sung;Lee, Kyung-Sup;Park, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.6
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    • pp.560-570
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    • 2005
  • In this paper, a microelectrode away DNA chip was fabricated on glass slide using photolithography technology. Several probe DNAs consisting of mercaptohexyl moiety at their 5' end were immobilized on the gold electrodes by DNA arrayer utilizing the affinity between gold and sulfu. Then target DNAs were hybridized and reacted with Hoechst 33258, which is a DNA minor groove binder and electrochemically active dye. Cyclic voltammetry in 5mA ferricyanide/ferrocyanide solution at 100 mV/s confirmed the immobilization of probe DNA on the gold electrodes. Linear sweep voltammetry or cyclic voltammetry showed a difference between target DNA and control DNA in the anodic peak current values. It was derived from Hoechst 33258 concentrated at the electrode surface through association with formed hybrid. It suggested that this DNA chip could recognize the sequence specific genes. It suggested that multichannel electrochemical DNA microarray is useful to develop a portable device for clinical gene diagnostic system.

Dynamic Model Identification of Quadrotor UAV based on Frequency-Domain Approach (주파수 영역 기반 쿼드로터 무인기 운동 모델 식별)

  • Jung, Sunggoo;Kim, Sung-Yug;Jung, Yeundeuk;Kim, Eung-Tai
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.23 no.4
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    • pp.22-29
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    • 2015
  • Quadrotor is widely used in variable application nowadays. Due to its inherent unstable characteristics, control system to augment the stability is essential for quadrotor operation. To design control system and verify its performance through simulation, accurate dynamic model is required. Quadrotor dynamic model is simply compared with conventional rotorcraft such as helicopter. However, the accurate dynamic model of quadrotor is not easy to develop because of the highly correlated aerodynamic effect of each rotor. In this paper, quadrotor dynamic model is identified from the flight data using frequency domain approach. Flight test of quadrotor is performed in closed loop configuration with stability augmentation system included. Frequency sweep input is applied in each of lateral, longitudinal, yaw and heave axis separately. The bare dynamic model is identified from the flight data of quadrotor responses and thrust measurement through Pulse Width Modulation(PWM) data. The frequency responses of identified model match well with those of flight data, and time responses of identified model for doublet input in each axis are also shown to agree with flight data.

Study of WMA Additive's Compaction Characteristics in Terms of Temperature Change by Using DSR (DSR을 이용한 온도변화에 따른 중온화 첨가제의 다짐특성 연구)

  • Hwang, Sung-Do;Lee, Sang Jae;Cho, Dong-Woo;Rhee, Suk Keun
    • International Journal of Highway Engineering
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    • v.15 no.4
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    • pp.11-20
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    • 2013
  • PURPOSES : This study is to develop a method to evaluate the compaction effects of asphalt binders using WMA additives and compare their compaction effects on two types of WMA additives, two types of testing temperatures, and three types of asphalt film thicknesses. METHODS : This study is based on laboratory experiments and rheological analysis of the experimental results. Testing materials are aggregate disks, asphalt, and WMA additives. The main testing method is the stress sweep test by using dynamic shear rheometer (DSR). In addition, the testing parameters obtained from the stress sweep results to evaluate lubrication effects are complex modulus and LVE-Limit. RESULTS : At both the first compaction condition ($110^{\circ}C$, 0.3mm) and second compaction condition ($80^{\circ}C$, 0.2mm) assumed, LEADCAP showed better compaction effects than Sasobit. CONCLUSIONS : The temperature $30^{\circ}C$ lower than general compaction temperatures can provide a better sensitivity for the evaluation of compaction effects. If a testing temperature and film thickness are grouped for the proper compaction conditions in the testing results, the compaction performance of each WMA additive can be more clearly discriminated in the grouped testing results matched with the grouped conditions.

A Study on the Bed Change in Reservoirs (저수지 하상변동에 관한 연구)

  • Lee, Gwan-Su;Lee, Yeong-Seok;Jeong, Byeong-Geon
    • Journal of Korea Water Resources Association
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    • v.30 no.4
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    • pp.401-409
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    • 1997
  • This study aims to predict the bed elevation change of river and reservoir by compound water model, two-dimensional jet model and one-dimensional density current model, assuming that the river has a single channel and the reservoir has multiple channels. In numerical model, discharge and water level changes is obtained by flow continuity equation and flow momentum equation through double-sweep method, and then applied to sediment continuity equation to predict the scour and deposit of channel bed. The span ranged from the Bosung Dam to Mundueok Bridge at the upstream of Juam Dam, which is approximately 31km long (13km of river and 18km of reservoir), is taken as survey area.

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INVESTIGATION ON EFFECTS OF ENLARGED PIPE RUPTURE SIZE AND AIR PENETRATION TIMING IN REAL-SCALE EXPERIMENT OF SIPHON BREAKER

  • Kang, Soon Ho;Lee, Kwon-Yeong;Lee, Gi Cheol;Kim, Seong Hoon;Chi, Dae Young;Seo, Kyoungwoo;Yoon, Juhyeon;Kim, Moo Hwan;Park, Hyun Sun
    • Nuclear Engineering and Technology
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    • v.46 no.6
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    • pp.817-824
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    • 2014
  • To ensure the safety of research reactors, the water level must be maintained above the required height. When a pipe ruptures, the siphon phenomenon causes continuous loss of coolant until the hydraulic head is removed. To protect the reactor core from this kind of accident, a siphon breaker has been suggested as a passive safety device. This study mainly focused on two variables: the size of the pipe rupture and the timing of air entrainment. In this study, the size of the pipe rupture was increased to the guillotine break case. There was a region in which a larger pipe rupture did not need a larger siphon breaker, and the water flow rate was related to the size of the pipe rupture and affected the residual water quantity. The timing of air entrainment was predicted to influence residual water level. However, the residual water level was not affected by the timing of air entrainment. The experimental cases, which showed the characteristic of partical sweep-out mode in the separation of siphon breaking phenomenon [2], showed almost same trend of physical properties.