• Title/Summary/Keyword: SOx and NOx

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Effect of Adding Hydrocarbon Gases for Reduction of NOx and SOx Using PPCP (탄화수소 가스 첨가가 PPCP 장치에 의한 NOx 및 SOx 저감에 미치는 영향)

  • 김홍석;강형수;정태용
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.5
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    • pp.73-80
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    • 1999
  • To decrease NOx and SOx using PPCP(Pulse-induced Plasma Chemical Process). This study is tried to obtain the relation and the basic data under the various conditions such the initial concentrations of NOx and SOx. The additional amount of hydrocarbon gases. The concentration of oxygen and input power etc. Especially, this study is focused on the effects of the additional hydrocarbon gases on the decrease of NOx and SOx.

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Effects of NOx and SOx on the Medium pH and microalgal growth in photo-culture system (광배양 시스템에서 NOx 및 SOx의 배지 pH와 미세조류 생장에 미치는 영향)

  • Yoon, Se Young;Hong, Min Eui;Sim, Sang Jun
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.3
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    • pp.255-263
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    • 2013
  • Carbon dioxide reduction technologies using photosynthetic microorganism were suggested to overcome environmental destruction caused by $CO_2$ in flue gases from power plant and other industries. However, there are many toxic constituents in flue gas including CO, NOx, SOx. Continuous and Excessive supply of these noxious gases to cells will leads to inhibition of microalgal growth along with partial cell death. In this study, we tested the noxious effect of SOx and NOx on the pH and microalgal growth under photoautotrophic culture in three microalgae of Neochloris oleoabundans, Chlorella vulgaris and Haematococcus pluvialis. As a result, SOx concentration more than 50 ppm led to the rapid reduction of pH, thereby inhibiting of the growth in Neochloris oleoabundans and Chlorella vulgaris. NOx concentration more the 100 ppm reduced the exponential growth of N. oleoabundans and C. vulgaris. And H. pluvialis exhibited low sensitivity to SOx and NOx. Consequently, the three microalgae of N. oleabundas, C. vulagaris and H. pluvialis showed the normal vegetative growth in 25 ppm of NOx and SOx. Above all, H. pluvialis was useful for the $CO_2$ sequestration of the flue gas including high concentrations of NOx and SOx.

Reaction Characteristics of SOx/NOx Removal Using CuO/γ-Al2O3 Sorbent/Catalyst (CuO/γ-Al2O3 흡수제/촉매를 이용한 SOx/NOx 제거 반응특성)

  • Yoo, Kyung Seun;Kim, Sang Done
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.671-678
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    • 2000
  • Reaction characteristics of simultaneous removal of SOx and NOx have been investigated in a thermogravimetric analyzer and tubular fixed bed reactor using the $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst. Sulfur removal capacity of $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst is largely enhanced above both the temperature of $450^{\circ}C$ and the loading of 6wt% due to the participation of alumina support in a sulfation reaction. The NO reduction efficiency of 8wt% $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst shows the maximum value at $370^{\circ}C$ and then decreases with the increase of reaction temperature due to the oxidation of $NH_3$ gas. The presence of sulfate on the surface of sorbent/catalyst enhances the optimum reaction temperature showing the maximum deNOx efficiency. In the simultaneous removal of SOx and NOx at $250^{\circ}C$. deNOx activity of $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst is rapidly decreased due to the formation of ammonium salts such as $NH_4HSO_4$. In the simultaneous removal reaction of SOx and NOx, the optimum temperature showing the maximum deNOx efficiency increases to $400^{\circ}C$ due to the presence of $SO_2$ gas.

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A Study on the Removal of SOx and NOx Using Catalytic Ceramic Filters (촉매담지 세라믹 필터를 이용한 황산화물과 질소산화물의 제거에 관한 연구)

  • 홍민선;이동섭
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.5
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    • pp.455-464
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    • 1998
  • Removal teals of Soxmox were performed using low density ceramic filters doped with various catalysts. Disc type (50 mmO.Dx10 mmt) low density ceramic filters were doped with three different catalysts such as Cu to remove SOx and NOx, and Mn and Co to remove NOx. The air permeabilities and specific surface areas were 40~50cc/min.cm2.cmH2O and 4.1~8.88 m2/g, respectively. Also, the peak pore sizes of catalyst support were 3~5nm. Tests were focused to search optimum operating temperatures for different catalysts. It was found that as the CuO content increases, SOx removal efficiency was increased. NOx removal efficiencies for Mn, Cu and Co, were 85% at 30$0^{\circ}C$, 90% at 40$0^{\circ}C$ and 90% at 45$0^{\circ}C$, respectively.

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A Study on the Technical Strategy in the IMO Air Pollution Prevention (IMO의 대기오염규제에 따른 기술적 대응전략에 관한 연구)

  • 김종헌
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.2 no.S1
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    • pp.77-85
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    • 1996
  • As conservation of global environment has becoming a major outstanding issue of the world, the International Maritime Organization(IMO) has been legislation a convention for prevention of air pollution from ships. By the new convention, use of air pollutants such SOx, NOx, Freon and Halin Gas shall be restricted. In this regards, analysing these requirements of the convention is required as the cinvention will also be applied in restriction of descharging exhaust gases from ships by estsblishing a requirement of Sox and NOx discharged. The purpose of this study is as follows; 1) Introdcuing of the backgrounds of legislating the convention for prevention of air pollution from ships and major contents of the convention and a countermeasuures in the convention by Korea 2) Reviewing by analyzing the influence in domestic industries concernd by restriction of SOx, NOx in exhaust gases and sulpher content of fuel oil 3) Preparing a countermeasure in the convention properly.

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A Study on the Technical Strategy on the IMO Air Pollution Prevention (IMO의 대기오염규제에 따른 기술적 대응전략에 관한 연구)

  • Kim, Jong Heon
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.2
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    • pp.69-69
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    • 1996
  • As conservation of global environment has becoming a major outstanding issue of the world, the International Maritime Organization(IMO) has been legislation a convention for prevention of air pollution from ships. By the new convention, use of air pollutants such as SOx, NOx, Freon and Halon Gas shall be restricted. In this regards, analysing these requirements of the convention is required as the convention will also be applied on restriction of discharging exhaust gases from ships by establishing a requirement of SOx and NOx discharged. The purposed of this study is as follows ; 1) Introducing of the backgrounds of legislating the convention for prevention of air pollution from ships and major contents of the convention and a countermeasures on the convention by Korea. 2) Reviewing by analyzing the influence on domestic industies concerned by restriction of SOx, NOx in exhaust gases and sulphur content of fuel oil. 3) Preparing a countermeasure on the convention properly.

Simultaneous Removal Characteristics of NOx, SOx from Combustion Gases using Plasma Chemical Reaction (플라즈마 화학반응에 의한 연소가스 중 NOx. SOx 동시제거 특성)

  • 박재윤;고용술;이재동;손성도;박상현;고희석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.406-409
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    • 1999
  • Experimental Investigations were carried out to remove NOx, SOx simultaneously from simulated flue gas[NO(0.02%)-SO$_2$(0.08%)-$CO_2$-Air-$N_2$] by using a plasma chemical reaction. Ammonia gas(14.81%) balanced by argon was diluted by all and was Introduced to mall simulated flue gas duct through NH$_3$ Injection system which is in downstream of reactor. The NH$_3$ molecular ratio(MR) was determined based on (NH3) to [NO+S0$_2$]. MR is 1, 1.5, 2.5. The NOx removal rate significantly increased with increasing NaOH bubble quantity. The SO$_2$ removal rate was not significantly effected by applied voltage, however it fairly Increased with increasing NH$_3$ molecule ratio. By-product aerosol particle was observed by XRD(X-ray diffraction) after sampling, The NOx, SOx removal rates, when H2O vapour bubbled by dry all was injected to plasma reactor, were better than those of other cases. When aqueous NaOH solution(20%) bubbled by 2.5( ι /min) of $N_2$ and 0.5 ( ι /min) NH$_3$(MR=1.5) were injected to simulated flue gas, The NOx. SOx removal rate was 95 ~ 100[%]

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Preparation of Porous Ceramic Bead using Mine Tailings and Its Applications to Catalytic Converter (광미(鑛尾)를 활용(活用)한 다공성 세라믹 비드 제조(製造) 및 촉매(觸媒) 변환기(變換機)로의 응용(應用))

  • Seo, Junhyung;Kim, Seongmin;Han, Yosep;Kim, Yodeuk;Lee, Junhan;Park, Jaikoo
    • Resources Recycling
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    • v.22 no.4
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    • pp.38-45
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    • 2013
  • The porous ceramic beads using mine tailing were prepared and applied to catalytic converter for NOx/SOx removal. Catalytic support was used synthesized mesoporous silica (SBA-15) which coated on surface. Internal structure for porous ceramic beads was composed of three-dimensional network structure and porosity was about 80%. In addition, the specific surface area for mesoporous silica(SBA-15) coated on converter was significantly increased 55 $m^2/g$ compared with 0.8 $m^2/g$ before coating. NOx/SOx removal experiment was performed using $V_2O_5$ and $V_2O_5$/CuO converter. NOx conversion ratio for $V_2O_5$/CuO converter was approximately increased 10% compared to $V_2O_5$ converter. In addition, catalytic converter of $V_2O_5$/CuO was shown to remove 95% of NOx and 90% of SOx at reaction temperature of $350^{\circ}C$, space velocity of 10000 $h^{-1}$ and $O_2$ concentrations of 5%, respectively.

Dispersion of Air Pollutants from Ship Based Sources in Incheon Port (인천항의 선박오염원에서 배출된 대기오염물질의 확산)

  • Kim, Kwang-Ho;Kwon, Byung Hyuk;Kim, Min-Seong;Lee, Don-Chool
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.5
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    • pp.488-496
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    • 2017
  • Emissions of pollutants from ship-based sources are controlled by the International Maritime Organization (IMO). Since pollutants emitted from ship may be dispersed to the land, controlling emissions from ships is necessary for efficient air quality management in Incheon, where exposure to ship-based pollution is frequent. It has been noted that the ratios of air pollutant emissions from coastal areas to inland areas are about 14% for NOx and 10% for SOx. The air quality of coastal urban areas is influenced by the number of ships present and the dispersion pattern of the pollutants released depending on the local circulation system. In this study, the dispersion of pollutants from ship-based sources was analyzed using the numerical California Puff Model (CALPUFF) based on a meteorological field established using the Weather Research and Forecasting Model (WRF). Air pollutant dispersion modeling around coastal urban regions such as Incheon should consider point and line sources emitted from both anchored and running ships, respectively. The total average NOx emissions from 82-84 ships were 6.2 g/s and 6.8 g/s, entering and leaving, respectively. The total average SOx emissions from 82-84 ships, entering and leaving, were 3.6 g/s and 5.1 g/s, respectively. The total average emissions for NOx and SOx from anchored ships were 0.77 g/s and 1.93 g/s, respectively. Due to the influence of breezes from over land, the transport of pollutants from Incheon Port to inland areas was suppressed, and the concentration of NOx and SOx inland were temporarily reduced. NOx and SOx were diffused inland by the sea breeze, and the concentration of NOx and SOx gradually increased inland. The concentration of pollutants in the area adjacent to Incheon Port was more influenced by anchored ship in the port than sea breezes. We expect this study to be useful for setting emission standards and devising air quality policies in coastal urban regions.

A Circulating Fluidized Bed Scrubbing Technology for Dry Removal of the SOx and NOx of Coal Combustion Gases (석탄연소가스내의 SOx/NOx 동시처리를 위한 순환유동식 건식세정기술)

  • 이상권;조경민
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.69-74
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    • 1999
  • 각종 산업체의 공정에서 혹은 석탄 혹은 석유를 사용하는 화력발전설비에서 다량 발생되는 질소산화물(NOx), 황산화물(SOx)의 배출규제가 점점 강화되어 감에 따라 배출량 절감이 절실히 요구된다. 기존의 배기가스 정화장치는 처리대상에 따라 다양한 방법들이 사용되는데 황산화물의 경우 습식, 반건식, 건식세정법에 의해, 질소산화물은 선택적 촉매환원법(Selective Catalytic Reduction)과 선택적 무촉매환원법(Selective Non Catalytic Reduction)이 널리 이용되고 있다.(중략)

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