• Journal of Korean Society for Atmospheric Environment
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• v.14 no.4
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• pp.273-280
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• 1998

The investigation on the removal of 502 gas fro.In flue gas which causes serious air pollution was made by using a semi dry flue gas desulfurization method. Experiments were carried out as a function of process variables which would affect SO2 removal efficiency. Process variables inclilded SO2 inlet concentration, inlet temperature of simulated flue gas, sorbent weight fraction, and volume flow rate of sorbent slurry. In this study, used sorbent was Ca(OH), and simulated flue gas was prepared by mixing pure SO2 gas with air. Experimental conditions were varied at 140~18$0^{\circ}C$ of inlet temperature of the simulated flue gas, 500~2000ppm of inlet SO2 concentration, 0.4~1.0% of sorbent concentration, and 10~25 mL/min of flow rate of sorbent slurry. Among process variables, inlet concentration of SO2 was found to be the most significant factor to affect SO2 removal efficiency. The concentration of Ca(OH2) had a lower effect on SO2 removal than SO2 inlet concentration removal amount was 0.108, 0.141, 0.153 g SO2/g Ca(OH)2 respectively- As 200 mmol of HNO3 was added into slurry to improve removal efficiency, initial pH was maintained and solubility of slurry increased, so that removal efficiency elevated. Adding over 200 mmol of HNO3 into slurry caused removal efficiency lower. Therefore it could be concluded the optimum was 200 mmol of HNO3 input.

• 보존과학연구
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• s.17
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• pp.65-99
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• 1996

We exanmined the each effect of $NO_2$ and $SO_2$gas, the maincomponets of air pollutants, on the deterioration of 6 organic materials with Gasexposure cabinet. The organic materials were used 2 kind of papers(Korean paper, Oldbook paper) and 4 kind of textiles (Cotton, Silk, Hemp, ramie) in gas exposure experiments. In order to know how to change of physical conditions, the materials were exposed to 2000, 1000 ppm. h of $SO_2$dose, to 100 ppm. h of $NO_2$ dose at 65% RH. The color difference, tensile strength, elongation coeffient, mass reduction and fabric status of each materials were discussed the following below.1. The color difference of cotton and hemp was larger than that of silk and ramie in the presence of $SO_2$ gas. and the color difference of korean paper was less than that of the textile materials in the presence of $SO_2$ gas.2. The tensile strength of cotton fell suddenly at 100ppm.h of $SO_2$ dose and even became 56% of the unexposed cotton.3. The weight of 6 materials began to decrease in the presence of $SO_2$ gas.4. The tensile strength and elongation of the materials tended to decrease at 12.5ppm.h of $NO_2$ especially silk was the strongest tendency to decrease.5. Cotton, hemp and ramie were influenced by $SO_2$ gas more than by $NO_2$, but silk were influenced by $NO_2$ more thang by $SO_2$ at 10ppm.h of each noxious gas.

• Journal of the Korean Society of Marine Environment & Safety
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• v.21 no.2
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• pp.188-193
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• 2015

It has been generally recognized that $N_2O$(Nitrous Oxide) emission from marine diesel engines has a close correlation with $SO_2$(Sulfur Dioxide) emission, and diversity of fuel elements using ships affects characteristics of the $N_2O$ emission. According to recent reports, in case of existence of an enough large NO(Nitric Oxide) generated as fuel combustion, effect of the $SO_2$ emission in exhaust gas on the $N_2O$ formation is more vast than effect of the NO. Therefore, $N_2O$ formation due to the $SO_2$ element operates on a important factor in EGR(Exhaust Gas Recirculation) systems for NOx reduction. An aim of this experimental study is to investigate that intake gas of the diesel engine with increasing of $SO_2$ flow rate affects $N_2O$ emission in exhaust gas. A test engine using this experiment was a 4-stroke direct injection diesel engine with maximum output of 12 kW at 2600rpm, and operating condition was set up at a 75% load. A standard $SO_2$ gas with 0.499%($m^3/m^3$) was used for changing of $SO_2$ concentration in intake gas. In conclusion, the diesel fuel included out sulfur elements did mot emit the $SO_2$ emission, and the $SO_2$ emission in exhaust gas according as increment of the $SO_2$ standard gas had almost the same ratio compared with $SO_2$ rate in mixture inlet gas. Furthermore, the $N_2O$ element in exhaust gas was formed as $SO_2$ mixture in intake gas because increment of $SO_2$ flow rate in intake gas increased $N_2O$ emission. Hence, diesel fuels included sulfur compounds were combined into $SO_2$ in combustion, and $N_2O$ in exhaust gas should be generated to react with NO and $SO_2$ which exist in a combustion chamber.

• Food Science and Preservation
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• v.15 no.6
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• pp.791-795
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• 2008

In order to establish the method to prepare and use the sulfur dioxide gas generating agent in low temperature storage of grape fruits, the $SO_2$ generation capacity from various sulfite compounds was investigated, and the method to regulate $SO_2$ gas generation and to detect the gas was developed. The conidial germination and mycelium growth of Botrytis cinerea which causes gray mold disease during grape fruit storage was completely inhibited at the $SO_2$ gas concentration of 400 ppm and 3200 ppm, respectively. Sodium hydrosulfite generated the most amount of $SO_2$ gas among the investigated 5 different sulfite or bisulfite compounds. By adjusting the number of pinholes on packaging film of the compound or by adding pH adjusting agent, e.g. citric acid or phosphates, it was possible to regulate the amount and duration of $SO_2$ gas generation from the compound. Because malachite green was quantitatively discolored by $SO_2$ gas, the solution or impregnated paper with the compound could be practically utilized as a indicator detecting $SO_2$ gas. Finally, when Muscat Bailey A grape was stored at low temperature with $SO_2$ gas generating agent, the disease incidence was reduced after storage.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.E
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• pp.17-28
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• 1999

Gas-liquid contact tests above a perforated-plate were conducted with air and water at flooding gas-flow conditions in order to study two-phase flow characteristics in a limestone-gypsum SO2 absorber. Gas layers were in the form of air pockets and confined to the limited areas around each duct pipe, while the remaining tary area were in the wet condition. The liquid above the tray was always in the flooded and even fluidized conditions at gas flows over the range studied, although vigorous bubbly or churn-turbulent two-phase regime was only observed in the immediate vicinity of the gas hole exit at low gas loads. The froth zone was extremely active to provide intimate contact between gas and liquid so that the necessary mass transfer operation can take place, which is the primary purpose of high-performance SO2 absorbers. Howefer, the absorber $\Delta$P was 250mmH2O for the initial water level at 150mm, which is an important issue to be resolved for economical operation of the SO2 absorber. It was seen in the liquid level-and gas flow-transient tests that changes in the absorber liquid inventory were much more pronounced for intimate gas-liquid contact than changes in the gas flow. Based on the 4- and 8-duct pipe test results, grouping the duct pipes near the center of the test tray seemed to promote better recirulation of liquid from gas-liquid contact zone back to the reaction tank so that the absorbed SO2 can be neutralized.

• Korean Chemical Engineering Research
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• v.46 no.3
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• pp.521-528
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• 2008

The micro-porous asymmetric PVDF hollow fiber membranes for gas-liquid contactor were prepared by the dry-jet wet phase inversion process and the characteristics of hollow fiber membranes were evaluated by the gas permeation method and scanning electron microscope. The chemical absorbent for removal of $SO_2$ gas was sodium hydroxide at bench scale hollow fiber membrane contactor. The experiments were performed in a counter-current mode of operation with gas in the shell side and liquid in the fiber lumen of the module to examine the effect of various operating variables such as concentration of absorbent, gas flow rate, L/G ratio and concentration of inlet $SO_2$ gas on the $SO_2$ removal efficiency using PVDF hollow fiber membrane contactor. Membrane mass transfer coefficient($k_m$) was calculated by mathematical modeling. The volumetric overall mass transfer coefficient increased with increasing the concentration of absorbent and L/G ratio. The increase of the absorbent concentration and L/G ratio not only provides more sufficient alkalinity but also decreases liquid phase resistance. The volumetric overall mass transfer coefficient increased with increasing gas flow rate due to decreasing the gas phase resistance.

• Journal of Preventive Medicine and Public Health
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• v.7 no.2
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• pp.373-375
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• 1974

The concentration of Carton momoxide(CO) and Sulful dioxide($SO_2$) by burning time of coal, and its time of fading out in atmosphere after effluence from stove were measured with Kitagawa gas detector, January, 1974. Gas for measurement was sampled by gas syringe at the point distanced 60cm. from first junction of garvanized pipe of stove. CO concentration was directly proportional to the burning temperature of coal but $SO_2$ was generally constant durning burning time or also in proportion to burning temperature. CO gas of effluent mixed with air(relative humidity, 40%) was maintained for long period relatively, but $SO_2$ gas was early faded out within short time. The period decreasing to allowable limit was about 4 days in former and about 30 minutes in later, respectiively.

• Journal of Environmental Health Sciences
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• v.11 no.1
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• pp.9-14
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• 1985

This experiment was carried out to study on the effect of SO$_2$ gas to chemical composition of tobacco leaves during flue-curing. The results were as follows: SO$_2$ gas in briquet was the major factor to damage with tobacco leaves. The damage only occured in a presence of moisture in tobacco leaves, it did not occured after color fix'lng stage which is a little leaf moisture. The danger of damage to tobacco leaves lies in 10ppm of SO$_2$ gas concentration. Follow with the SO$_2$ gas concentration increased, sugar and nitrogen contents became higher, polyphenol contents were loss, and the quality of tobacco leaves declined.

• Journal of the Korean Society of Safety
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• v.14 no.1
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• pp.73-77
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• 1999

In this study, $SO_2$ and $NO_2$ reduction have been investigated by using coil type plasma reactor. The experiments have been carried out changing discharge power, gas flow rate frequency and electrode style to obtain the decomposition rate. Decomposition rates of $SO_2$ and $NO_2$ were obtained 20~98% at gas flow rate 100ml/min~1,000ml/min and discharge power 5~25w respectively. The energy efficiency is very good at the high frequency power. The decomposition rate of $SO_2$ for 5kHz power supply is only 90%, but for 10kHz power supply is very high, more than 98% for 15w. The decomposition rate is increasing according to the residence time or the power consumption of the discharge. About 15W discharge power for 17$cm^2$ reactor is necessary to obtain the decomposition rate of $SO_2$ and $NO_2$ of more than 85% or 98%. From these experiments, the consumption power of the decomposition rate of 98% in 300ppm $NO_2$ gas in nitrogen gas proved to be 18W and 300ppm $SO_2$ gas to be 15w.

• Journal of Korean Society for Atmospheric Environment
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• v.2 no.2
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• pp.1-8
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• 1986

To obtain the guidance of plants sensitivity or resistance to $SO_2$ gas, 16 species, 25 varieties of plants were exposed to 0, 0.2, 0.4, 0.7 and 1.5 ppm of $SO_2$ gas in controlled environmental chamber and the visible injury on the plants was observed. Plant sensitivity and/or resistance rankings at each guidance appeared different, based on first injured time, injury degree, and injury index. Only 10 varieties of plant are equal in the ranking at different base. It is concluded that recommended guidance for sensitivity and resistance of plants to $SO_2$ gas are the first injured time and the injury degree, respectively.