• Title/Summary/Keyword: SCR-1

검색결과 349건 처리시간 0.021초

NH3-SCR 반응에서 스팀 처리된 zeolite BEA 촉매의 영향 (Effect of Steam-Treated Zeolite BEA Catalyst in NH3-SCR Reaction)

  • 박지혜;조광희;황라현;백정훈;이광복
    • 청정기술
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    • 제26권2호
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    • pp.145-150
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    • 2020
  • 아산화질소(N2O)는 6대 온실가스 중 하나로 이산화탄소(CO2)의 310배에 해당하는 지구온난화지수(global warming potential, GWP)를 나타내어 N2O를 저감하는 것은 필수적이다. 선택적 촉매환원법(selective catalytic reduction, SCR)은 대기오염 물질의 하나인 NOx의 제거를 위해 암모니아를 환원제로 사용하여 무해한 N2 및 H2O로 전환하는 기술로 높은 탈질효율을 나타낸다. 본 연구에서는 NH3-SCR반응에서 스팀 처리된 Fe-BEA 촉매가 활성에 미치는 영향을 조사하기 위하여 Fe-BEA 촉매는 Fe를 이온교환하기 전, 고정층 반응기로 100 ℃에서 2 h 동안 스팀 처리 되었다. 제조된 촉매의 NH3-SCR반응 테스트는 고정층 반응기로 WHSV = 180 h-1, 370 ~ 400 ℃에서 수행되었다. 100 ℃에서 스팀 처리된 Fe-BEA(100) 촉매가 370 ~ 390℃에서 Fe-BEA 촉매보다 다소 높은 활성을 나타내었다. NH3-SCR 활성에 영향을 주는 원인을 파악하기 위하여 제조된 촉매는 BET, ICP, NH3-TPD, H2-TPR, 27Al MAS NMR을 통하여 특성분석 되었다. H2-TPR결과를 통해 Fe-BEA(100) 촉매가 Fe-BEA 촉매 보다 isolated Fe3+의 환원이 더 많이 일어난 것을 확인하였으며, 스팀 처리는 활성종인 isolated Fe3+의 양을 늘려주어 활성이 증가한 것으로 판단된다.

바나디아 촉매담지 세라믹 캔들필터를 이용한 질소산화물 제거기술 (Removal Technology of NOx Using V2O5/TiO2 Catalyst Impregnated Ceramic Candle Filters)

  • 이동섭;박진식
    • 한국환경과학회지
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    • 제16권9호
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    • pp.1077-1083
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    • 2007
  • [ $V_2O_5/TiO_2$ ] catalyst impregnated ceramic candle filters are in principle, capable of performing shallow-bed dust filtration plus a catalytic reaction, promoted by a catalytic deposited in their inner structure. Pilot-scale $V_2O_5/TiO_2$ catalyst impregnated ceramic candle filters were prepared, characterized and tested for their activity towards the SCR reaction. The effect on NO conversion of operating temperature, gas hourly space velocity, amount of deposited catalyst, pressure drops and long-term experiment (life of catalytic filter) was determined. The following effects of $V_2O_5/TiO_2$ catalyst impregnated ceramic candle filters in SCR reaction are observed: (1) It increases the activity and widens the temperature window for SCR. (2) When the content of $V_2O_5$ catalyst increases further from 3 to 9wt.%, activity of NO increases. (3) NO conversion at first increases with temperature and then decreases at high temperatures (above $400^{\circ} over), possibly due to the occurrence of the ammonia oxidation reaction.

기상 환원제를 사용하는 선택적 환원촉매에서 유동혼합 개선에 관한 연구 (A STUDY ON FLOW MIXING IMPROVEMENT OF SELECTIVE CATALYTIC REDUCTION USING GASEOUS REDUCTANT)

  • 고상철;이범호;조승환;이상헌;홍성태;이대엽
    • 한국전산유체공학회지
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    • 제15권1호
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    • pp.56-63
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    • 2010
  • Since emission regulations for vehicles have become more stringent, SCR technology has drawn a strong attention in order to reduce NOx emissions. Optimal design of a reductant injection nozzle and a multi-hole plate located between the cone and catalyst is critical in that the uniform distribution of reductant is necessary to maximize the NOx conversion efficiency and minimize the slip of reductant in SCR. In this work, an LPG fuel(C3H8 in vapor state) was used as a reductant for LPG vehicles. A Realizable k-$\varepsilon$ model is used for turbulence, and SCR body is defined as porous media with inertia and viscous resistances measured in this work. Effect of the number of nozzle holes on the flow mixing index was analyzed, which revealed that a four hole nozzle shows the best performance in terms of uniformity of flow. An installment of a multi-hole plate at the entrance of catalyst was evaluated with flow mixing index, uniformity of flow, and pressure drop. A multi-hole plate with gradual hole diameter change in three steps showed the best uniformity of flow within the conditions suggested in this work.

500 PS급 선박 SCR 반응기에서 디퓨저 각도와 면적비에 따른 유동균일도 수치해석 (Numerical Analysis on Flow Uniformity According to Area Ratio and Diffuser Angle in an SCR Reactor of a 500 PS-Class Ship)

  • 성홍석;박인성;장현;박창대;김현규;정경열;서정세
    • 한국생산제조학회지
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    • 제24권4호
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    • pp.394-399
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    • 2015
  • Because flow uniformity affects the life cycle and performance of the catalyst, it is an important design factor for selective catalytic reduction (SCR) systems. We examined how the diffuser angle and the area ratio of the inlet of the SCR reactor to the front of the catalyst affect flow uniformity. For the numerical analysis, we used STAR-CCM+, a common CFD software program. Analysis results showed that the larger the area ratio was, the less the flow uniformity was, and that the longer the diffuser length was, the greater the flow uniformity was. When the area ratio was greater than 1:5, the flow uniformity appeared very similar at the front of the catalyst. As a result, the spread time of the exhaust gas increased and the flow velocity decreased.

SOME PROPERTIES OF STRONG CHAIN TRANSITIVE MAPS

  • Barzanouni, Ali
    • 대한수학회논문집
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    • 제34권3호
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    • pp.951-965
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    • 2019
  • Let $f:X{\rightarrow}X$ be a continuous map on a compact metric space (X, d) and for an arbitrary $x{\in}X$, $${\mathcal{SC}}_d(x,f):=\{y{\mid}x{\text{ can be strong }}d-{\text{chain to }}y\}$$. We give an example to show that ${\mathcal{SC}}_d(x,f)$ is dependent on the metric d on X but it is a closed and f-invariant set. We prove that if ${\mathcal{SC}}_d(x,f){\supseteq}{\Omega}(f)$ or f has the asymptotic-average shadowing property, then ${\mathcal{SC}}_d(x,f)=X$. Also, we show that if f has the shadowing property, then ${\lim}\;{\sup}_{n{\in}{\mathbb{N}}}\{f^n\}={\mathcal{SC}}_d(f)$ where ${\mathcal{SC}}_d(f)=\{(x,y){\mid}y{\in}{\mathcal{SC}}_d(x,f)\}$. For each $n{\in}{\mathbb{N}}$, we give an example in which ${\mathcal{SCR}}_d(f^n){\neq}{\mathcal{SCR}}_d(f)$. In spite of it, we prove that if $f^{-1}:(X,d){\rightarrow}(X,d)$ is an equicontinuous map, then ${\mathcal{SCR}}_d(f^n)={\mathcal{SCR}}_d(f)$ for all $n{\in}{\mathbb{N}}$.

New Thyristor Based ESD Protection Devices with High Holding Voltages for On-Chip ESD Protection Circuits

  • Hwang, Suen-Ki;Cheong, Ha-Young
    • 한국정보전자통신기술학회논문지
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    • 제12권2호
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    • pp.150-154
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    • 2019
  • In the design of semiconductor integrated circuits, ESD is one of the important issues related to product quality improvement and reliability. In particular, as the process progresses and the thickness of the gate oxide film decreases, ESD is recognized as an important problem of integrated circuit design. Many ESD protection circuits have been studied to solve such ESD problems. In addition, the proposed device can modify the existing SCR structure without adding external circuit to effectively protect the gate oxide of the internal circuit by low trigger voltage, and prevent the undesired latch-up phenomenon in the steady state with high holding voltage. In this paper, SCR-based novel ESD(Electro-Static Discharge) device with the high holding voltage has been proposed. The proposed device has the lower triggering voltage without an external trigger circuitry and the high holding voltage to prevent latch-up phenomenon during the normal condition. Using TCAD simulation results, not only the design factors that influence the holding voltage, but also comparison of conventional ESD protection device(ggNMOS, SCR), are explained. The proposed device was fabricated using 0.35um BCD process and was measured electrical characteristic and robustness. In the result, the proposed device has triggering voltage of 13.1V and holding voltage of 11.4V and HBM 5kV, MM 250V ESD robustness.

3상 유도 전동기 벡터제어 구동시스템의 구현 (Implementation of Vector Control system for $3\phi$ Induction Motor)

  • 홍순일
    • 조명전기설비학회논문지
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    • 제12권1호
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    • pp.45-50
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    • 1998
  • 최근, 유도전동기 회전속도 제어용 구동 전원으로 인버터와 싸이크로컨버터가 널리 사용되고 있다. 싸이크로컨버터에 의한 전동기 구동은 일정 주파수의 교류전원에서 직접 주파수가 다른 교류로 변환함으로 하드웨어 구성이 인버터 보다 간단하다. 본 연구의 목적은 싸이크로컨버터에 의한 유도전동기 벡터제어 시스템의 제어방법 및 하드웨어 설계를 행하는 것이다. 본 연구에서는 교류 전동기 슬립 주파수형 벡터제어 알고리즘을 도출하고 이 원리에 기초하여 싸이크로컨버터를 이용한 벡터제어 시스템을 구성하였다. 싸이크로컨버터는 1차 입력전류 진폭 $li_1l$ 과 각주파수 $\omega_1$을 지령값으로 진폭변조 제어신호를 발생하여 SCR의 게이터를 트리거한다. 본 벡터제어 시스템은 교류 전동기를 구동한 결과 자속이 일정하게 유지되면서 정회전에서 역회전까지 연속적으로 양호한 운전을 할 수 있었다.

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SCR를 이용한 유도전동기의 속도제어에 관한 연구 (Speed Control of tne Induction Motor Using SCR (Trial Manufacturing of Solid-state Frequency Converter))

  • 원종수
    • 전기의세계
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    • 제19권4호
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    • pp.1-11
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    • 1970
  • It is well known that solid-state devices like inverter and converter made by transistor and other semi-conductors are widely used for the purpose of motor speed control in industrial fields. This paper is devoted primarily to a study of Trial Manufacturing of Solid-state Frequency Converter by means of single-phase bridge-type SCR inverter. The principle of the trial product belongs to AC-DC-AC conversion system. The voltage to be impressed to the motor in case of speed control by frequency conversion method is necessary to be proportional to frequency. It also requires the frequency and voltage are independent to hte load variation. In order to meet above requests required to motor speed control., the trial product introduced the open loop system in the frequency setting and closed loop system in the voltage setting. The trial product showed the favorable performance characteristics in speed control of singlephase fractional horsepower motor from 45HZ through 80HZ.

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회전접촉자를 사용한 SCR 주파수 변환기에 관한 연구 (A Study on the SCR Frequency Converter With a Rotating Distributor)

  • 정연택
    • 전기의세계
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    • 제24권1호
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    • pp.43-53
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    • 1975
  • This paper describes a converter, which combines SCR bridge type rectifier circuit with a rotating distributor. This type of converter produces an adjustable low frequency output of three phase or single phase, from three phase or single phase power source. Output-waveforms of this converter are multi-pulse in three phase output, and square wave in single phase output. Problems about the operation of static switches, a commutation and output-waveforms are investigated, and experimental results verify that frequency can be adjusted satisfactorily from zero to 20 (Hz) and the expected output-waveforms are obtained without sparking on the distributor under various loading conditions. This converter can be utilized to low speed control of A.C. motors, and other lowfrequency loads.

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저 전압 트리거형 ESD 보호회로를 탑재한 저 전압 Step-down DC-DC Converter 설계 (The Design of low voltage step-down DC-DC Converter with ESD protection device of low voltage triggering characteristics)

  • 육승범;이재현;구용서
    • 전기전자학회논문지
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    • 제10권2호통권19호
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    • pp.149-155
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    • 2006
  • In this study, the design of low voltage DC-DC converter with low triggering ESD (Electro-Static Discharge) protection circuit was investigated. The purpose of this paper is design optimization for low voltage(2.5V to 5.5V input range) DC-DC converter using CMOS switch. In CMOS switch environment, a dominant loss component is not switching loss but conduction loss at 1.2MHz switching frequency. In this study a constant frequency PWM converter with synchronous rectifier is used. And zener Triggered SCR device to protect the ESD phenomenon was designed. This structure reduces the trigger voltage by making the zener junction between the lateral PNP and base of lateral NPN in SCR structure. The triggering voltage was simulated to 8V.

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