DOI QR코드

DOI QR Code

Removal Technology of NOx Using V2O5/TiO2 Catalyst Impregnated Ceramic Candle Filters

바나디아 촉매담지 세라믹 캔들필터를 이용한 질소산화물 제거기술

  • Lee, Dong-Sub (Department of Health & Environmental, Kyungwoon University) ;
  • Park, Jin-Sick (Department of Health & Environmental, Kyungwoon University)
  • Published : 2007.09.30

Abstract

[ $V_2O_5/TiO_2$ ] catalyst impregnated ceramic candle filters are in principle, capable of performing shallow-bed dust filtration plus a catalytic reaction, promoted by a catalytic deposited in their inner structure. Pilot-scale $V_2O_5/TiO_2$ catalyst impregnated ceramic candle filters were prepared, characterized and tested for their activity towards the SCR reaction. The effect on NO conversion of operating temperature, gas hourly space velocity, amount of deposited catalyst, pressure drops and long-term experiment (life of catalytic filter) was determined. The following effects of $V_2O_5/TiO_2$ catalyst impregnated ceramic candle filters in SCR reaction are observed: (1) It increases the activity and widens the temperature window for SCR. (2) When the content of $V_2O_5$ catalyst increases further from 3 to 9wt.%, activity of NO increases. (3) NO conversion at first increases with temperature and then decreases at high temperatures (above $400^{\circ} over), possibly due to the occurrence of the ammonia oxidation reaction.

Keywords

References

  1. Saracco G., 1999, Coupling catalysts and hightemperature resistance filters, High Temperature Gas Cleaning, Edited by Achim D. et al., Institut filr Mechanische Verfahrenstechnik und Mechanik der Universitat Karlsruhe, Germany, 627-640
  2. Ronald M. H., Farrauto R. J, 1995, Catalytic air pollution control - commercial technology, Van Nostrand Reinhold Publishers, New York, 1115
  3. Hums E., Joisten M., Mulller R., Sigling R., Spielmann H., 1996, Innovative lines of SCR catalysis : NOx reduction for stationary diesel engine exhaust gas and dioxin abatement for waste incineration facilities, Catalysis Today, 27, 29-34 https://doi.org/10.1016/0920-5861(95)00205-7
  4. Forzatti P., Nova I., Beretta A., 2000, Catalytic properties in deNOx and $SO_{2}$-$SO_{3}$ reactions, Catalysis Today, 56, 431-441 https://doi.org/10.1016/S0920-5861(99)00302-8
  5. Nakajima F., Hamada I., 1996, The stateof- the-art technology of NOx control, Catalysis Today, 29, 109-115 https://doi.org/10.1016/0920-5861(95)00288-X
  6. Zhu Z., Liu Z., Liu S., Niu H., 1999, A novelcarbon-supported vanadium oxide catalysts for NO reduction with NIh at low temperature, Applied Catalysis B: Environmental, 23, L229-L233
  7. Liu Z., Tabora J., Davis R. J, 1994, Relationships between microstructure and surface acidity of Ti-Si mixed oxide catalysts, J Catalysis, 149,1, 117-126 https://doi.org/10.1006/jcat.1994.1277
  8. Topsoe N. Y., Dumesic J A, Topsoe H., 1995, Vanadia/titania catalysts for selective catalytic reduction of nitric oxide by ammonia II. studies of active sites and formulation of catalytic cycles, J catalysis, 151, 241-252 https://doi.org/10.1006/jcat.1995.1025
  9. Handy B. E., Baiker A, Martin M. S., Wokaun A, 1992, Vanadia supported on $TiO_{2}$-$SiO_{2}$ mixed oxide gels : structure of the dispersed phase and activity for the selective catalytic reduction of NO with $NH_3$, J Catalysis, 133, 1-20 https://doi.org/10.1016/0021-9517(92)90182-H
  10. Shikada T., Fujumoto K., Kunugi T., Tominaga H., 1983, Reduction of nitric oxide with ammonia on silica-supported vanadium oxide catalysts, J Chern. Tech. biotechnol., 33A, 446-454
  11. Bosch H., Janssen F., Kerkhof F., Oldenziel J, Ommen J, Ross J., 1986, The activity of supported vanadium oxide catalysts for the selectivity reduction of NO with ammonia, Applied Catalysis, 25, 239-248 https://doi.org/10.1016/S0166-9834(00)81242-7
  12. Blanco J, Bahamonde A, Alvarez E., Avila P., 1998, Two-bed catalytic system for NOx/SOx removal, Catalysis Today, 42, 85-92 https://doi.org/10.1016/S0920-5861(98)00079-0
  13. Blanco J., Avila P., Suarez S., Martin J A, Knapp C., 2000, Alumina- and titiania-based monolithic catalysts for low temperature selective catalytic reduction of nitrogen oxides, Applied Catalysis B: Environmental, 28, 235-244 https://doi.org/10.1016/S0926-3373(00)00180-6
  14. Stefan B., Hammer T., 2000, Selective catalytic reduction of nitrogen oxides by combining a non-thermal plasma and a $V_{2}O_{2}$-$WO_{3}$-$TiO_{2}$ catalyst, Applied Catalysis B: Environmental, 28, 101-111 https://doi.org/10.1016/S0926-3373(00)00166-1
  15. Inomata M., Miyamoto A, Murakami Y, 1981, Determination of the number of V=O species on the surface of vanadium oxide catalyst 2. $V_{2}O_{2}$/$TiO_{2}$ catalysts, J. Phys. Chem., 85, 2372-2377 https://doi.org/10.1021/j150616a016