• Title/Summary/Keyword: Rubber Compounding

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High Performance Barrier Technologies for Tire Innerliner (타이어 인너라이너용 고차단화 기술)

  • Kang, Yong-Gu;Lee, Seong-Peal;Han, Min-Hyun
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.102-111
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    • 2011
  • The innerliner for a tire has excellent impermeability, air retention and good flex properties. The innerliner offers a role to improve performance parameter, such as air retention and tire durability that is of praricular importance for commercial tires. In order to improve the gas barrier properties of a innerliner, most of the innerliner rubbers, such as a halogenated butyl rubber(HIIR), brominated poly(isobutylene-co-isoprene)(BIIR), brominated polyisobutylene-co-paramethylstyrene(BIMS) are used as nanocomposites with nano fillers such as silicates, graphite etc. Innerliners based on nanocomposites may allow gauge adjustments and permeability reductions with potential improvement in tire durability. This article discusses potential innerliner permeablity reduction and compounding parameters on the properties of nanocomposite based innerliners.

Studies on the Quality Reinforcement for Pneumatic Tire and Tube (Part 5) Physical Properties for Tire Cord and Butyl Tube (Tire 및 Tube의 품질보강(品質補强)에 관(關)한 연구(硏究) (제5보(第5報)) Tire Cord 및 Butyl Tube의 물성(物性)에 대(對)하여)

  • Kim, Joon-Soo;Lee, Myung-Whan;Yum, Hong-Chan;Lee, Chin-Bum;Park, Chang-Ho;Hong, Chong-Myung;Im, Dong-Ho
    • Elastomers and Composites
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    • v.4 no.1
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    • pp.89-93
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    • 1969
  • 1. Physical properties of various nylon cords in a tire, both of home and foreign products are studied. The experimental data for home nylon cords appeared to be quite satisfactory for use in a tire compared with foreign nylon cords with respect to its tenacity, elongation, shrinkage and contraction. 2. Excellent results have been obtained with 50 phr carbon in butyl-carbon compounding.

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A Study on Dynamic Properties for Filler Compounded NR Vulcanizates (충전제(充塡劑)를 배합(配合)한 NR가황체(加黃體)의 동적(動的) 성질(性質)에 관(關)한 연구(硏究))

  • Chun, Kyung-Soo;Choi, Jae-Woon
    • Elastomers and Composites
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    • v.27 no.4
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    • pp.281-288
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    • 1992
  • The purpose for this study is to examine the vulcanization characteristics, especially the damping, elastic modulus and viscous modulus properties of filler 50phr filled NR compounds and to find out the compounds which can be used as damping materials in industry. For this study, compounds were prepared with filler filled compounding formula. Their vulcanization characteristics, elastic modulus, viscous modulus and damping properties were examined by mean of the rheometrics dynamic spectrometer. The results of this study can be summarized as follows. 1. The elastic modulus values of the maxium under the condition of 1Hz frequency, showed the order as follows, $HAF>Silica>FEF>GPF>SRF>Clay>CaCO_3\;coated>CaCO_3$. 2. The damping values of the maxium under the condition of 1Hz frequency, showed the order as follows $Silica>HAF>FEF>GPF>SRF>Clay>CaCO_3\;coated>CaCO_3$.

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Thermal Conductivity and Mechanical Properties of Magnesium Oxide Reinforced Polyamide-66 Composites

  • Hwang, Seok-Ho
    • Elastomers and Composites
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    • v.50 no.3
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    • pp.205-209
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    • 2015
  • Magnesium oxide (MgO) reinforced polyamide-66 (PA66) composites were prepared through melt-compounding method in order to determine the possibility of using MgO particle as conductive filler in the polymer-based composite. The effects of MgO filler content on the thermal conductivity and mechanical properties for the PA66/MgO composites were investigated. The results showed that the addition of MgO filler to the PA66 matrix led to a large increase in thermal conductivity of the PA66/MgO composites. Tensile strengths of the PA66/MgO composites were slightly decreased as MgO filler loading increased. However, flexural strength and flexural modulus were improved with increasing filler loading. Notched Izod impact strengths were dramatically lowered by the addition of MgO filler.

Analysis of Peroxide Curing Agents in EVA Compounds and Vulcanizates

  • Chae, Eunji;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.55 no.1
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    • pp.6-12
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    • 2020
  • Poly(ethylene-co-vinyl acetate) compounds and vulcanizates containing dicumyl peroxide (DCP) (HD) were prepared, and the curing agent and reaction products were analyzed using gas chromatography/mass spectrometry (GC/MS). Samples containing trially cyanurate (TAC) and DCP (HDT) were also prepared and analyzed. Some raw DCP were decomposed in the injector region of GC to produce acetophenone. DCP was detected in the HD compound but was not observed in the HD vulcanizate, and instead acetophenone and 2-phenyl-2-propanol were detected. Both DCP and TAC were observed in the HDT compound but not in the HDT vulcanizate, where acetophenone and 2-phenyl-2-propanol were detected. Thus, some of the DCP decomposed during the compounding process. The formation mechanism for acetophenone and 2-phenyl-2-propanol during the crosslinking reaction was identified, and differences in the crosslinking reactions of HD and HDT compounds were discussed.

Properties of Blackdown and Tracking in silicone Rubber (실리콘 고무의 절연파괴 및 트렉킹 특성)

  • Lee, Sung-Ill;Kim, Gui-Yeul;Lee, Won-Jae;Jang, K.U.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.591-593
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    • 2003
  • Silicone composites for high voltage insulator(HVI SC) were prepared by adding aluminum trihydrate(ATH) treated by surface treatment agent to base silicone compound at the ratio of 100:20, 100:40, 100:60, 100:80, and 100:100, respectively. And also, ATH was treated by various surface treatment agents, such as stearic acid, acryl silane vinyl silane under compounding process. electrical properties were investigated for the various contents of ATH and solace-treatment agents we mlas ured volume resistivity, breakdown and tracking resistance were for HVISC containing ATH treated by viuyl silane.

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A Fabrication and Antifogging Performance of Random Polypropylene Film Containing Monoglycerides as Antifogging Agent

  • Jo, Wan;Park, Jin Hwan;Hwang, Seok-Ho
    • Elastomers and Composites
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    • v.56 no.4
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    • pp.217-222
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    • 2021
  • In this study, random polypropylene (rPP) was compounded with two of monoglycerides, namely, glyceryl monolaurate (GML) and glyceryl monostearate (GMS), as antifogging agents to improve its antifogging performance. rPP film samples were prepared by a film-casting method using a three-roll casting machine after melt blending through a twin screw extruder. With an increase in the monoglyceride content, the melt flow index for rPP films with GML and GMS increased, and their yield strength decreased. The incorporation of GMS in rPP was proven to be more effective in improving its physical properties than was rPP with GML. When GML and GMS were separately added to the rPP film at contents of more than 1 phr and more than 5 phr, respectively, the film exhibited antifogging performance.

Study on Property Change with a Fire Retardant Content in the Manufacture of Polymer Composites for Cable Sheath

  • Li, Xiang Xu;Lee, Sang Bong;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.54 no.2
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    • pp.118-122
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    • 2019
  • Four different polymer compounds were manufactured to make cable sheaths for the shipping industry. Two kinds of ethylene vinyl acetate (EVA) as the main matrix polymers and EVA-grafted maleic anhydride (EVA-g-MAH) as the coupling agent were selected for compounding with fire retardant, crosslinking agent, filler, plasticizer, and other additives. The properties of the four compounded materials were investigated with different contents of the fire retardant, silanecoated magnesium dihydroxide (S-MDH). In the rheology evaluation, the $t_{60}$ and ${\Delta}T$ values increased with increasing S-MDH contents. On the other hand, the tensile strength decreased with increasing S-MDH content due to a relative decrease in binder polymers. With increasing S-MDH content, fire resistance increased, but cold resistance showed no obvious enhancement due to the polar effect of vinyl acetate in EVA.

Mechanical Properties of NBR Rubber Composites Filled with Reinforced Fiber and Ceramics (강화섬유와 세라믹이 충진된 NBR 고무 복합체의 기계적 물성 특성)

  • Kwon, Byeong-Jin;Kim, Young-Min;Lee, Danbi;Park, Soo-Yong;Jung, Jinwoong;Chung, Ildoo
    • Journal of Adhesion and Interface
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    • v.22 no.4
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    • pp.118-127
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    • 2021
  • In this study, the mechanical properties of vulcanized rubber were evaluated through compounding by controlling filler content to improve the mechanical properties of NBR rubber. Aramid and glass fibers with excellent heat resistance were used as fillers, and ceramics were additionally used in anticipation of a complementary effect, and as for the ceramic materials, needle-shaped and plate-shaped ceramics were used. Each filler was used in an amount of 5.0, 10.0, 15.0, and 20.0 phr in order to investigate the basic properties according to the amount of filler. To confirm the complementary effect through ceramic application, each 10.0 phr fiber and ceramic were mixed with 1:1 ratio to evaluate mechanical properties. As a result, it was confirmed that the decreasing ratio of tensile strength after heat aging was small in the order of aramid fiber, acicular ceramic, glass fiber, and plate ceramic in the case of applying the filler alone. In addition, the mechanical characteristics of vulcanized rubber using composite filler based on fibers and ceramics were evaluated, and it was confirmed that the composite filler had a complementary effect on thermal aging.

Physical and Chemical Characteristics of Multi-walled Carbon Nanotube (MWCNT) with Acid-treatment and Coupling Agent on the Properties of Styrene Butadiene Rubber (SBR) (SBR에 산 처리된 MWCNT 및 커플링제 적용 시 발현되는 물리.화학적 특성 연구)

  • Song, Sung-Ho;Jeong, Ho-Kyun;Kang, Yong-Gu;Cho, Choon-Tack
    • Polymer(Korea)
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    • v.34 no.2
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    • pp.108-115
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    • 2010
  • The effects of acid-treated MWCNT and coupling agent on properties of MWCNT/SBR are investigated in this work. The MWCNTs oxidized using sulfuric and nitric acids were analyzed by the Raman scattering and Fourier transformed infrared spectroscopy(FT-IR). The FT-IR results indicate the presence of -COOH groups in the treated samples, and Raman spectroscopy of the acidtreated MWCNTs further corroborates the formation of surface defect due to the introduction of carboxyl groups. And the nanocomposites reinforced with MWCNTs were characterized extensively using the scanning electron microscopy(SEM), electrical conductivity, thermal conductivity, and tensile properties measurements. The results showed that nanocomposites onto acid-treated MWCNTs enhanced mechanical properties compared to those containing MWCNTs without acid treatment. These findings confirmed the improved interfacial interactions between MWCNTs and SBR arising from the coupling agents. But the electrical and thermal conductivity of nanocomposites decreased due to the chopping and formation of surface defects of MWCNTs.