• 제목/요약/키워드: Reverse rate coefficients

검색결과 15건 처리시간 0.02초

Expansion of the equilibrium constants for the temperature range of 300K to 20,000K

  • Kim, Jae Gang
    • International Journal of Aeronautical and Space Sciences
    • /
    • 제17권4호
    • /
    • pp.455-466
    • /
    • 2016
  • Chemical-kinetic parameters of the equilibrium constants to evaluate the reverse rate coefficients in the shock layer of a blunt body and the expanding flows are derived for the temperature range from 300 K to 20,000 K. The expanded equilibrium constants for the chemical reactions of the dissociation, ionization, associative ionization, and neutral and charge exchange reactions of the atmospheric species and carbon materials are proposed in the present work. In evaluating the equilibrium constants, the inter-nuclear potential energies of the molecular species are calculated by the analytical potential function of the Hulburt-Hirschfelder model, and the parameters of the analytical model are determined from the semi-classically calculated RKR potentials. The electronic states and energies of the atoms are calculated by the electronic energy grouping model, and the rovibrational states and energies of each electronic states of the molecules are evaluated by the WKB method. The expanded equilibrium constants for 31 types of the reactions are provided for the best curve-fit functions, and the recombination reaction rate coefficients evaluated from the present equilibrium constants are compared with existing measured values.

Scaling predictions in seawater reverse osmosis desalination

  • Hchaichi, Houda;Siwar, Saanoun;Elfil, Hamza;Hannachi, Ahmed
    • Membrane and Water Treatment
    • /
    • 제5권3호
    • /
    • pp.221-233
    • /
    • 2014
  • Simulations were conducted to predict supersaturation along Reverse Osmosis (RO) modules for seawater desalination. The modeling approach is based on the use of conservation principles and chemical equilibria equations along RO modules. Full Pitzer ion interactive forces model for concentrated solutions was implement to calculate activity coefficients. An average rejection rate for all ionic species was considered. Supersaturation has been used to assess scaling. Supersaturations with respect to all calcium carbonate forms and calcium sulfate were calculated up to 50% recovery rate in seawater RO desalination. The results for four different seawater qualities are shown. The predictions were in a good agreement with the experimental results.

축류압축기 익렬에서의 역류 유동 특성에 대한 수치적 연구 (Numerical Study on Reverse Flow Charcteristics in an Axial Compressor Cascade)

  • 손창현
    • 대한기계학회논문집B
    • /
    • 제24권5호
    • /
    • pp.615-622
    • /
    • 2000
  • Numerical simulation is performed with Denton's code to get pressure loss coefficients in wide range of reverse flow incidence(from -90 degree to +85 degree) for an axial compressor cascade. As a results, it is found that the pressure loss coefficient is increased with incidence and there exist critical incidence which corresponds to the maximum pressure loss coefficient. Pressure loss coefficient with bigger incidence than its critical value is decreased. The effect of increasing incidence in a cascade extremely reduce the mass flow rate by the large flow separation region. Consequently this effect reduce the portion of dynamic pressure in the total pressure loss and beyond the critical incidence the pressure loss coefficient decrease.

INFLUENCE OF HALL CURRENT AND HEAT SOURCE ON MHD FLOW OF A ROTATING FLUID IN A PARALLEL POROUS PLATE CHANNEL

  • VENKATESWARLU, M.;UPENDER REDDY, G.;VENKATA LAKSHMI, D.
    • Journal of the Korean Society for Industrial and Applied Mathematics
    • /
    • 제22권4호
    • /
    • pp.217-239
    • /
    • 2018
  • This paper examined the MHD and thermal behavior of unsteady mixed convection flow of a rotating fluid in a porous parallel plate channel in the presence of Hall current and heat source. The exact solutions of the concentration, energy and momentum equations are obtained. The influence of each governing parameter on non dimensional velocity, temperature, concentration, skin friction coefficient, rate of heat transfer and rate of mass transfer at the porous parallel plate channel surfaces is discussed. During the course of numerical computation, it is observed that as Hall current parameter and Soret number at the porous channel surfaces increases, the primary and secondary velocity profiles are increases while the primary and secondary skin friction coefficients are increases at the cold wall and decreases at the heated wall. In particular, it is noticed that a reverse trend in case of heat source parameter.

저질토로부터의 인의 용출거동 예측 및 제어기술 개발 - I. 저질토로부터의 인의 용출거동 예측 (Prediction of Phosphorus Transport from Sediment and Development of Phophorus Control Technology - I. Prediction of Phosphorus Transport from Sediment)

  • 이정엽;강선홍
    • 상하수도학회지
    • /
    • 제13권2호
    • /
    • pp.89-94
    • /
    • 1999
  • In this study small glass columns with 2.5cm inner diameter and 24.5cm length were used as many as the sample numbers to study the effects of initial pH, temperature, dissolved oxygen concentration, and sediment depth on the release of phosphorus from lake sediment. No phosphorus release occurred at $10^{\circ}C$ with all pHs, and release rate at $25^{\circ}C$ was higher than that at $35^{\circ}C$ with pH 4 and reverse trends were observed at pH 7 and 10. Under all conditions, DO concentrations were decreased and equilibrium was obtained after 4-8 days when phosphorus release started and the Do concentrations were less than 1 mg/l. Sediment depth had little effect on phosphorus release rate. It was found that relation between released SRP(Soluble Reactive Phosphorus) concentration and time was zero order reaction and reaction rate coefficients were obtained. The amount of phosphorus release from lake sediment can be predicted by considering these k values.

  • PDF

역상 고속액체크로마토그라피를 이용한 홍삼 사포닌의 정량 (Determination of Ginseng Saponins by Reversed-Phase High Performance Liquid Chromatography)

  • 김천석;김세봉
    • 한국약용작물학회지
    • /
    • 제9권1호
    • /
    • pp.21-25
    • /
    • 2001
  • 인삼의 주종 사포닌인 7종 사포닌($Rb_1,\;Rb_2,\;Rc,\;Rd,\;Re,\;Rf\;and\;Rg_1$)을 고속액체크로마토그라피로 분석하는 일반적인 방법인 순상 column에서 $Rg_1$, Re 및 Rf가 명확히 분리되지 않는 문제점을 개선하기위하여 본 연구를 수행하였다. 고속액체크로마토그라피를 이웅하여 역상 ${\mu}{\beta}ondapak$ ODS컬럼으로 인삼중 주종 사포닌인 7종 ginsenosides $Rg_{1},\;Re,\;Rf,\;Rb_{1},\;RC,\;Rb_{2}$ 및 Rd를 양호하게 분리하였다. 이때 분석 조건으로 이동상 용매 조성은 (A) $H_{2}O$, (B) methyl cyanaide을 (A) 90/(B) 10에서 (A) 0/(B) 100으로 기울기 용리를 이용하였으며, 기울기 용리 제어장치를 사용하여 용리시켰다. 용매 흐름속도는 1.5ml/min, 검출기는 UV detector(203nm)이었다. 이 방법은 분리능과 재현성 및 회수율이 양호하므로, 앞으로 인삼중 ginsenosides 분석에 응용될 수 있을 것으로 사료된다.

  • PDF

선박용 글로브 밸브의 유동특성에 관한 연구 (A Study on the Flow Characteristics inside a Glove Valve for Ships)

  • 배기화;박재현;강상모
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제32권1호
    • /
    • pp.110-118
    • /
    • 2008
  • It is essential for the valid design of a marine flow-control valve to exactly know its flow characteristics. The present study has numerically investigated the flow characteristics inside a marine throttle-type globe valve using a kind of commercial CFD code, CFX10.0, with an adoption of the SST (Shear-Stress Transport) turbulence model. To validate the numerical approach, the flow coefficients are compared with the experimental ones. Results show that the globe valve is effective in the control of flow rate according to the opening ratio in case of the forward-direction flow, whereas it is effective in the flow shutoff in case of the reverse-direction flow. Around the inlet of the valve, a recirculation region is formed due to the blunt body shape, the turbulence intensity becomes strengthened and then an abrupt pressure loss occurs.

역상 고속 액체크로마토그래피를 이용한 인삼 사포닌의 분석 (Determination of Ginseng Saponins by Reversed-Phase High Performance Liquid Chromatography)

  • 정승일;김천석;이노운;최강주;이용구;김일광
    • 분석과학
    • /
    • 제11권6호
    • /
    • pp.436-439
    • /
    • 1998
  • 인삼 사포닌을 역상 고속 액체크로마토그래피 방법을 이용하여 여러 종류의 컬럼으로 분석하였다. 최적 조건은 Novapak $C_{18}$ ODS 역상 칼럼($3.9mm{\times}150mm$, $5{\mu}m$), $CH_3CN/H_2O$ 이성분 이동상 용액과 기울기 제어장치, 그리고 1.5 mL/min의 용매 흐름속도였으며, UV 검출기(203 nm)를 사용하였다. 인삼의 주성분인 ginsenoside $Rb_1$, $Rb_2$, Rc, Rd, Re, Rf 그리고 $Rg_1$ 7종을 50분 안에 양호하게 분리하였다. 각 성분에 대한 검량선은 직선성이 좋았으며, 회귀계수는 0.98~0.99이었다.

  • PDF

치조열 환자의 장골이식술 후 예후 평가 (A Prognosis Evaluation after Iliac Bone Graft in Cleft Alveolus Patients)

  • 홍진호;소병수;백진아;신효근
    • 대한구순구개열학회지
    • /
    • 제4권2호
    • /
    • pp.69-78
    • /
    • 2001
  • Alveolar cleft exists in 75% of cleft patients, In alveolar cleft patients, alar base is widening, palatal fistular formation, maxillary growth disturbance & tooth loss of adjacent area is raised, Alveolar bone grafting, especially iliac bone grafting, is a general treatment method. As operation timing, bone grafting is classified with primary, early secondary, secondary, & late secondary, Here we report cleft width, marginal bone height, bone resorption rate, grafted shape & bone densities after secondary iliac bone grafting was done in the Dept. of oral and maxillofacial surgery of chonbuk national university hospital. We compared cleft width to bone resorption rate and grafted shape. Also, alveolar bone densities of grafted and contralateral site was compared with Emago 3 package? (Oral Diagonostic System, The Netherlands), The data obtained were analyzed using Spearman's rho coefficients and sign test with SPSS for window, The results were obtained as follows. 1. As alveolar cleft width is increase, bone resorption rate is, too. This relation showed significant difference(P<.01). 2, In proximal & distal area, alvolar cleft width and bone graft contour after bone grafting had a reverse proportional difference. It was not significant difference(P>.05). 3. After 3 month, in bone density results by using Emago 3 package? with periapical standard view, occlusal view & panoramic view, differences between grafted bone and alveolar bone of contralateral site didn't show a significant difference(P>.05). Thus, differences of bone densities in the alveolar bones didn't exist.

  • PDF

닭의 스트레스 연관 표지인자들의 발현도와 생산능력 간의 상관 분석 (The Relationship of the Expressions of Stress-related Markers and Their Production Performances in Korean Domestic Chicken Breed)

  • 박지애;조은정;최은식;홍영호;최연호;손시환
    • 한국가금학회지
    • /
    • 제43권3호
    • /
    • pp.177-189
    • /
    • 2016
  • 본 연구는 닭의 개체 별 스트레스 연관 표지의 발현도와 이들의 생산능력 간의 연관성을 살펴보기 위한 것으로 토종종계 25계통을 대상으로 텔로미어 함량, 열 스트레스 단백질(HSPs) 유전자 발현율 및 DNA 손상율을 분석하고, 동일 개체들의 생존율, 성장능력 및 산란능력을 조사하여 이들 간의 상관관계를 분석 고찰하였다. 분석 결과, 생산능력 및 스트레스 표지 값들 간에 계통별로 유의한 차이가 나타났는데, 대체적으로 고체중 순계들의 스트레스 지표가 상대적으로 높았으며, 저체중 교잡계들의 스트레스 지표가 낮게 나타났다. 텔로미어 함량과 생산능력 간의 상관성은 20주령 이후부터 유의한 상관관계를 보였는데, 성장능력과는 약한 부(-)의 상관 양상을, 산란능력 및 생존율과는 약한 정(+)의 상관관계를 나타내었다. HSPs 유전자 발현율과 생산능력과의 상관에서 생존율 및 산란지수와는 저도 및 중도의 부의 상관을 보였고, 체중과는 약한 정의 상관관계를 나타내었다. DNA 손상율 분석 또한 체중과는 약한 정의 상관을, 산란지수 및 생존율과는 중도 및 저도의 부의 상관관계를 나타내었다. 이는 체중이 증가할수록 HSPs 유전자 발현율, DNA 손상율 및 텔로미어 감축량이 증가함을 의미하고, 반면 산란능력 및 생존율이 높을수록 HSPs 유전자 발현율과 DNA 손상율은 낮아지고, 텔로미어 함량은 상대적으로 높다는 것을 시사한다. 스트레스 표지 인자들 간의 상호 관계에서 모든 표지 값 간에 유의한 상관관계가 나타났는데, HSPs 발현값과 텔로미어 함량과는 부의 상관을, DNA 손상율과는 정의 상관을 보이고, 텔로미어 함량과 DNA 손상율과는 높은 부의 상관을 나타내었다. 이상의 스트레스 표지 값과 생산능력 간의 상관분석 결과에 따라 닭에 있어 HSPs 및 DNA 손상율의 증가는 텔로미어 감축을 촉진하고, 이에 따라 개체의 항병성 및 강건성을 저하시켜 산란능력과 생존율에 나쁜 영향을 미치는 것으로 판단된다.